Highly porous CuO/MnO2 catalyst prepared by gas release-assisted technology and its enhancement of formaldehyde removal efficiency

Research on Chemical Intermediates - A porous CuO/MnO2 catalyst was synthesized by a gas release-assisted method. Due to the participation of gases (H2O, NH3, CO2) released from ammonia and...     

多孔有机盐单晶的合成及各向异性质子导电性能

以cis,cis-1,3,5-三氨基环己烷·3HBr和均苯四甲酸在室温下通过离子键构筑了具有规整形貌和大尺寸的晶态多孔有机盐CPOS-10, 其具有较好的热稳定性和永久多孔性. 得益于规整形貌及大尺寸单晶, 首次实现了对多孔有机盐单晶各向异性质子导电性能的研究, 并结合晶体结构探索了各向异性质子导电的机理. 结果表明, 水分子浓度对CPOS-10质子电导率的大小具有重要作用, 骨架内水分子浓度高的晶面更易于与极性基团构成氢键网络, 促进质子传导, 利用此网络的质子传导具有更高的质子电导率. 因此, 骨架内水分子的不均匀分布是导致单晶各向异性质子导电的主要原因. 对CPOS-10单晶各向异性质子导电性能的探索可为研究多孔有机盐的质子导电机理提供重要的依据.     

BV estimates of Lax-Friedrichs' scheme for a class of nonlinear hyperbolic conservation laws

We give uniform BV estimates and -stability of Lax-Friedrichs' scheme for a class of systems of strictly hyperbolic conservation laws whose integral curves of the eigenvector fields are straight lines, i.e., Temple class, under the assumption of small total variation. This implies that the approximate solutions generated via the Lax-Friedrichs' scheme converge to the solution given by the method of vanishing viscosity or the Godunov scheme, and then the Glimm scheme or the wave front tracking method.

     

红外双波段双层谐衍射光学系统设计

将谐衍射透镜应用在传统红外单波段佩茨瓦尔(Petzval)物镜上,设计得到工作波段处于3.4~4.2μm和8~11μm的红外双波段单层谐衍射光学系统。但单层谐衍射元件的衍射效率只在设计波长处衍射效率最高,随着波长相对设计中心波长向两侧偏离,主衍射级次的衍射效率逐渐下降。为提高含单层谐衍射元件光学系统的衍射效率,基于双层衍射元件衍射效率表达式研究了双层谐衍射元件的结构优化,给出了优化方法。设计出佩茨瓦尔型红外双波段双层谐衍射光学系统,其在3.4~4.2μm和8~11μm两个工作波段的衍射效率均达到90%以上,相比含有单层谐衍射面的光学系统衍射效率有了很大提升,提高了像面衬比度,完善了系统成像质量。     

Electronic charge distributions and correlations in highT c superconducting compounds

Calculations on negatively charged planar Cu _n O _m clusters are reported. Starting from a self-consistent field calculation within a good Gaussian-type orbital basis set, correlations are included by using the Local Ansatz. A charge analysis reveals that the Cu 3d occupation is 9.5, in close agreement with Local Spin Density calculations. The electrons in the formal ((CuO₂)^2–) _n entities are delocalized between Cu and O sites and strongly correlated. Our findings do not agree with the assumption of localized Cu²⁺ spins which lead to thet-J model. Spin correlations indicate strong short-range antiferromagnetic order even when additional electrons are removed. For them, there is no difference between O and Cu sites.     

考虑中间主应力效应的损伤钢管混凝土构件承载力分析

混凝土三参数统一强度理论在Haigh-Westgaard空间的偏平面上的边界线为十二边形,通过调整中间主应力的影响系数消除角点的奇异性,根据相关流动准则推导基于标量损伤的弹塑性本构方程,考虑了混凝土材料的随动强化效应,结合塑性损伤理论给出了应力计算的数值方法,编制了相应的Fortran语言程序,并将其用于钢管混凝土构件承载能力的计算,计算结果验证了所用模型的预测能力。     

拉曼光谱子空间重合识别修正液中氯代烃

利用拉曼光谱子空间重合对修正液中氯代烃成分进行识别分析。通过计算混合卤代烃组分与标准样品数据库拉曼光谱之间的子间空夹角,依据夹角变化排列筛选出含有最少标准样品数目的子空间,该子空间所含的标准样品组成为待定性混合氯代烃组成,从而实现对混合氯代烃组分的定性分析。将该方法用于修正液中氯代烃的成分定性分析,准确率达100%。该方法操作简单,检测时间短,准确率高,适用于多组分混合体系中的物质定性分析。     

Resistance characterizations of equiarboreal graphs

A weighted (unweighted) graph $G$ is called equiarboreal if the sum of weights (the number) of spanning trees containing a given edge in $G$ is independent of the choice of edge. In this paper, we give some resistance characterizations of equiarboreal weighted and unweighted graphs, and obtain the necessary and sufficient conditions for $k$-subdivision graphs, iterated double graphs, line graphs of regular graphs and duals of planar graphs to be equiarboreal. Applying these results, we obtain new infinite families of equiarboreal graphs, including iterated double graphs of 1-walk-regular graphs, line graphs of triangle-free 2-walk-regular graphs, and duals of equiarboreal planar graphs.