Highly sensitive and stable SERS probes of alternately deposited Ag and Au layers on 3D SiO_2 nanogrids for detection of trace mercury ions

The hazard of Hg ion pollution triggers the motivation to explore a fast, sensitive, and reliable detection method.Here, we design and fabricate novel 36-nm-thick Ag–Au composite layers alternately deposited on three-dimensional(3D)periodic SiO_2 nanogrids as surface-enhanced Raman scattering(SERS) probes. The SERS effects of the probes depend mainly on the positions and intensities of their localized surface plasmon resonance(LSPR) peaks, which is confirmed by the absorption spectra from finite-difference time-domain(FDTD) calculations. By optimizing the structure and material to maximize the intrinsic electric field enhancement based on the design method of 3D periodic SERS probes proposed,high performance of the Ag–Au/SiO_2 nanogrid probes is achieved with the stability further enhanced by annealing. The optimized probes show the outstanding stability with only 4.0% SERS intensity change during 10-day storage, the excellent detection uniformity of 5.78%(RSD), the detection limit of 5.0×10~(-12) M(1 ppt), and superior selectivity for Hg ions. The present study renders it possible to realize the rapid and reliable detection of trace heavy metal ions by developing highperformance 3D periodic structure SERS probes by designing novel 3D structure and optimizing plasmonic material.     

QUASILINEAR-ADDITIVE PROPERTIES AND APPLICATIONS

In this article, the authors study some basic properties of the so-called quasilinear- additive functions, and some applications to the special functions of quasiconformal analysis are specified.     

判别原子外层轨道能级高低与划分能级组的量子值规则

周期表中所有元素基态原子的电子构型,是由光谱实验数据确定的,而通过量子化学的理论计算,完全导出这些结果,则是理论化学的重要课题之一。迄今为止,已建立了多种理论模型,其中较合理的是多多重项理论方法。但由于理论方法的复杂性,造成了在一般教学中推广使用的困难,又有不少化学家提出一些图解法和经验规则。在一般教科书     

在线氧化分光光度法测定铁的价态

1 引言 铁的价态影响着铁在生态系统中的迁移性、生物可利用性以及毒性.本研究基于Fe3+与钛铁试剂在酸性条件下生成蓝紫色络合物的反应原理,建立了顺序注射在线氧化测定铁的价态的光度分析方法.     

二维直角平面内固定圆形夹杂对稳态入射反平面剪切波的散射

利用复变函数法、多极坐标及傅立叶级数展开技术求解了二维直角平面内固定圆形夹杂对稳态入射反平面剪切（shearing horizontal, SH）波的散射问题。首先构造出介质内不存在夹杂时的入射波场和反射波场,然后建立介质内存在夹杂时由夹杂边界产生的能够自动满足直角边应力自由条件的散射波解，从而利用叠加原理写出介质内的总波场。利用夹杂边界处位移条件和傅立叶级数展开方法列出求解散射波中未知系数的无穷代数方程组，在满足计算精度的前提下通过有限项截断，得到相应有限代数方程组的解，最后通过算例具体讨论了二维直角平面水平边界点的位移幅度比和相位随量纲一波数、入射波入射角及夹杂位置的不同而变化的情况，结果表明了算法的有效实用性。     

局部上同调模的Artin性质

In this paper,let (R,m)be a Noetherian local ring,I(?)R an ideal, M and N be two finitely generated modules.Firstly,we study the properties of H_I~t(M),t=f-depth(I,M) and discuss the relationship between the Artinianness of H_I~i(M,N) and the Artinianness of H_I~i(N).Then,we get that H_I~d(M,N)is I-cofinite,if(R,m)is a d-dimensional Gorenstein local ring.     

新型饱和烷基类自由基捕捉剂的合成及ESR研究

设计合成了新的饱和烷基类线型硝酮捕捉剂N-（亚乙基）-t-丁胺-N-氧化物(EBN)和N-（亚乙基）-1-二乙氧基磷酰基-1-甲基乙基胺N-氧化物(EPN),并运用ESR、MS、IR、UV等一系列手段对其结构进行了表征,同时对Fenton体系中产生的羟基及不同类型的氧中心、碳中心和硫中心自由基的捕获能力进行了系统的研究. 结果表明,这两种捕捉剂合成方法比较简单,产率较高,对羟基等自由基有比较强的捕捉能力. 期望本文的工作能为自由基捕捉剂的研究提供一个新的思路.     

Thermal transport property of Ge34 and d-Ge investigated by molecular dynamics and the Slack’s equation

In this study,we evaluate the values of lattice thermal conductivity κ L of type II Ge clathrate (Ge 34) and diamond phase Ge crystal (d-Ge) with the equilibrium molecular dynamics (EMD) method and the Slack's equation.The key parameters of the Slack's equation are derived from the thermodynamic properties obtained from the lattice dynamics (LD) calculations.The empirical Tersoff's potential is used in both EMD and LD simulations.The thermal conductivities of d-Ge calculated by both methods are in accordance with the experimental values.The predictions of the Slack's equation are consistent with the EMD results above 250 K for both Ge34 and d-Ge.In a temperature range of 200-1000 K,the κ L value of d-Ge is about several times larger than that of Ge 34.     

TiO2/石墨烯纳米复合材料制备及其光催化性能研究

以TiCl3和氧化石墨(GO)为原料,采用简便的原位液相法制备了TiO2/石墨烯(RGO)纳米复合材料.利用XRD、SEM、XPS和UV-Vis光谱表征了其微观结构及性能,实验考察了复合材料光催化还原CO2性能,探究了其光催化反应机理.研究表明,TiO2/石墨烯纳米复合材料具有显著的光催化还原活性,光催化反应产物选择性高,反应6.0h甲醇的累积产量为3.43 mmol/L,石墨烯的协同效应提高了TiO2半导体的光催化活性和反应效率.     

Z箍缩动态黑腔形成过程MULTI程序一维数值模拟

Z箍缩动态黑腔能够高效地将Z箍缩丝阵等离子体动能转换为黑腔辐射能,为驱动惯性约束靶丸聚变提供高品质的X射线辐射场.利用一维双温多群辐射磁流体力学程序MULTI-IFE,研究了"聚龙一号"装置驱动电流条件下的Z箍缩动态黑腔形成基本物理过程.数值模拟结果表明,在动态黑腔形成过程中,辐射热波的传播速度比冲击波的传播速度更快,比冲击波更早到达泡沫中心,使中心区域的泡沫在冲击波到达前就已具有较高的辐射温度.对于"聚龙一号"装置动态黑腔实验0180发次采用的负载参数,辐射热波和冲击波在泡沫中的传播速度分别约为36.1 cm/μs和17.6 cm/μs,黑腔辐射温度在黑腔形成初期约80 eV,在冲击波到达泡沫中心前可达100 eV以上,丝阵等离子体外表面发射的X射线能量集中在1000 eV以下.本文给出了程序采用的计算模型、美国"土星"装置丝阵内爆计算结果和"聚龙一号"装置动态黑腔实验0180发次模拟结果.