排序方式: 共有74条查询结果,搜索用时 250 毫秒
1.
Hao Zhang Hui Huang Zihan Lin Xingguang Su 《Analytical and bioanalytical chemistry》2014,406(27):6925-6932
Graphene is a two-dimensional carbon nanomaterial one atom thick. Interactions between graphene oxide (GO) and ssDNA containing different numbers of bases have been proved to be remarkably different. In this paper we propose a novel approach for turn-on fluorescence sensing determination of glucose. Hydrogen peroxide (H2O2) is produced by glucose oxidase-catalysed oxidation of glucose. In the presence of ferrous iron (Fe2+) the hydroxyl radical (?OH) is generated from H2O2 by the Fenton reaction. This attacks FAM-labelled long ssDNA causing irreversible cleavage, as a result of the oxidative effect of ?OH, producing an FAM-linked DNA fragment. Because of the weak interaction between GO and short FAM-linked DNA fragments, restoration of DNA fluorescence can be achieved by addition of glucose. Due to the excellent fluorescence quenching efficiency of GO and the specific catalysis of glucose oxidase, the sensitivity and selectivity of this method for GO-DNA sensing are extremely high. The linear range is from 0.5 to 10 μmol L?1 and the detection limit for glucose is 0.1 μmol L?1. The method has been successfully used for analysis of glucose in human serum. Figure
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Yujie Li Qiangqiang Jia Min Zhang Lu Kang Zihan Li Yu Liu Hongyang Zhang Ping Hu 《Journal of separation science》2022,45(13):2140-2147
The isomerism of glucaric acids and the complexity of the composition of Leonurus japonicus Houtt. increased the difficulty of the separation of glucaric acids from the herb. In the present study, three glucaric acids were isolated from Leonurus japonicus Houtt. by using high-speed countercurrent chromatography combined with semi-preparative high-performance liquid chromatography. Cation exchange resin chromatography was applied to remove the alkaloids and enrich the glucaric acid fractions. Preliminary separation of the glucaric acid extract by high-speed countercurrent chromatography was carried out at 45℃ by using an optimized solvent system of ethyl acetate/n-butanol/formic acid/water (1:1:0.01:2, v/v/v/v) with satisfied stationary phase retention and separation factor. The semi-preparative high-performance liquid chromatography was used for further separation and purification of the target fractions, and three monomeric compounds were obtained with purities of 90.0, 91.0, and 95.3%. UV spectroscopy, NMR spectroscopy, and mass spectrometry were employed to identify their structures, which were assigned as 2-syringyl glucaric acid, 2,4-disyringyl glucaric acid, and 3,4-disyringyl glucaric acid, respectively, and 2,4-disyringyl glucaric acid was reported for the first time. 相似文献
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Peng Sun Zihan Xia Zhongfang Li Ziwei Fan Fengqi He Qiang Liu Xiaoyan Yin 《Materials Today Chemistry》2022
A high-temperature proton exchange membrane with high proton conductivity over a wide humidity range still remains a challenge. PBI dendrimer containing triazine rings (TPBI) was synthesized to approach this aim considering its high content of hygroscopic terminal groups and of larger free volume. A novel proton conductor previously synthesized (zirconium 3-sulfopropyl phosphonate, ZrSP) was doped due to its good proton conductivity over a wide humidity range. TPBI was post-crosslinked with a tetrafunctional epoxy resin (N,N,N′,N′-tetraglycidyl-4,4′-diaminodiphenylmethane, TGDDM) to enhance the mechanical stability at low cross-linking degrees, which allowed high doping levels of ZrSP, and thus, high conductivity. The prepared membranes (TPBI-TGDDM/ZrSP) showed good thermal stability, high proton conductivity over wide humidity range, and good dimensional stability. At suitable degrees of branching, TPBI-TGDDM/ZrSP exhibited superior mechanical property, oxidative stability, methanol barrier property, and membrane selectivity than its linear analog (mPBI-TGDDM/ZrSP). As ZrSP instead of PA was applied as the proton conductor, TPBI-TGDDM/ZrSP showed good durability of proton conductivity, especially in comparison with TPBI-TGDDM/PA, which highly retarded decline in conductivity caused by PA leaking. The proton conductivity at 180 °C of TPBI(20)-TGDDM(10)/ZrSP(50) achieved 142, 84.2 and 23.6 mS cm?1 at 100%, 50%, and 0 RH, respectively. 相似文献
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Fengjun Liu Zihan Wu Boshang Hou Zhiqiang Dong Yuhua Weng Rui Pan Zhenling Xu Chunyan Zhang Yinyun Lü Xiaoqing Ouyang Chanzi Ruan 《大学化学》2020,35(9):83-88
By using light sensors of the cellphone, we build a simple photometer which can be used in quantitative analysis experiments. We have performed 5 replicate measurements of iron with phenanthroline to verify reproducibility and stability. We find the absorbance of the sample has a good linear relationship with the concentrations of iron with a R2 value around 0.999 and the RSD of 2.81%. The result is 4.94 μg·mL-1 with spectrophotometer and 5.11 μg·mL-1 with our photometer. The photometer is simple, convenient, accurate and realistic by using a phone as detector, which can replace the traditional spectrophotometer in the laboratory class. The students can enhance their understanding of the structure and principle of spectrophotometer by the DIY photometer experiment. 相似文献
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本文采用传统固相反应法,成功制备了新型无铅弛豫铁电陶瓷(1-x)[0.9BaTiO3-0.1Bi(Mg0.25Ta0.5)O3]-xBi0.5Na0.5TiO3。结果表明,较高居里温度的Bi0.5Na0.5TiO3的引入,使得材料体系中建立了更多的以Bi—O耦合为主的极性纳米区域,弥补了因Bi(Mg0.25Ta0.5)O3的加入导致的宏观极化强度的减少,提高了材料的饱和极化强度,实现了较高储能密度的同时具有更好的温度稳定性。在245 kV/cm电场强度下,x=0.2样品的储能密度约为4.01 J/cm3,储能效率约为84.86%,同时该组分在20~170 ℃储能密度的变化率小于5%,储能效率的变化率小于6%,表现出优异的温度稳定性。 相似文献
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Sijing Zhang Jialong Tu Qiaobin Huang Zihan Liu Dongdong Li Qiang Chen Dongmei Deng 《Annalen der Physik》2023,535(10):2300211
The propagation dynamics of finite-energy Swallowtail beams in a dynamic parabolic potential, including uniformly moving, accelerating, and oscillating potentials, are investigated. The strong influence of dynamic potentials on the propagation trajectory of Swallowtail beams is demonstrated and various effective manipulations of the beams, including trajectory control, are validated. The intensity and the focal position can also be affected. In addition, the extension to 2D scenarios is also presented. The results theoretically provide more diverse manipulation possibilities for Swallowtail beams, and thus may broaden their potential applications in trajectory and particle manipulation. 相似文献
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文章通过构建博弈模型探讨了存在跟随企业搭便车行为时创新企业的定价策略及定价模式(稳定定价或动态定价),并分析了忠实消费者规模及需求溢出效应等特征对创新企业定价决策与利润的影响.结果表明,无论创新企业采用稳定定价或动态定价模式,跟随企业搭便车行为均会降低创新企业利润,需求溢出效应的增强总能使创新企业和跟随企业均获得更高的利润.动态定价模式下,当需求溢出效应较大时,创新企业会采用渗透定价策略;反之会采用撇脂定价策略.无论垄断或竞争市场情形下,均存在消费者规模阈值效应,即创新企业的利润随着忠实消费者规模的增大而先增大后减小.垄断市场下,动态定价模式能让创新企业获得更高利润;竞争市场下,当跟随企业质量处于较中间水平时,稳定定价模式能让创新企业获得更多优势. 相似文献
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Jiao Jiajia Li Hao Lin Wen Wang Rui Meng Zihan Guo Weibin Zhao Shengqiu Li Junsheng Tang Haolin 《Journal of Solid State Electrochemistry》2020,24(3):771-779
Journal of Solid State Electrochemistry - Practical application of Li-S battery is limited by the fast capacity decay and low coulombic efficiency caused by the shuttling phenomenon. Modification... 相似文献
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Xin Jin Yangyang Li Shuo Zhang Jiangwei Zhang Zihan Shen Chenlin Zhong Ziqiang Cai Chaoquan Hu Huigang Zhang 《中国化学快报》2022,33(1):491-496
Sodium(Na)O2 batteries have high energy density and low cost. However, high polarization, complex discharge products, and low Coulombic efficiency(CE) lead to poor cyclability. Here, we proposed an atomically dispersed Ru catalyst on nitrogen-doped graphene for Na-O2 batteries. The catalysts enable the discharge to proceed via a surface-mediated route, which leads to uniform deposition of Na2-xO2 and low polarization during recharge. The first-principl... 相似文献