叶栅全三维粘性反问题的数值解

本文发展了一种解叶栅全三维粘性反问题的新的数值方法.基于非正交曲线坐标与相应的非正交速度分量下完全守恒型的Navier－Stokes方程,全三维反问题规定叶片表面的无量纲压力分布反求叶型。计算中叶片表面的边界条件采用一种特殊的方式来处理，即一方面强加给定的压力分布条件,另方面叶面的几何位置在迭代过程中又是可移动的，其移动速度将与Navier—Stokes方程在当地的解联系起来，从而形成一种解定常问题的新的不定常过程.试算证明了本文方法的可行性。     

MEASUREMENTS OF Fe AND Cu K-Shell IONIZATION CROSS SECTIONS BY SLOW ELECTRON IMPACT

ＭＥＡＳＵＲＥＭＥＮＴＳＯＦＦｅＡＮＤＣｕＫ－ＳｈｅｌＩＯＮＩＺＡＴＩＯＮＣＲＯＳＳＳＥＣＴＩＯＮＳＢＹＳＬＯＷＥＬＥＣＴＲＯＮＩＭＰＡＣＴＬｉＴａｉｈｕａＡｎＺｈｕＬｕｏＺｈｅｎｇｍｉｎｇＣｅｎｔｅｒｆｏｒＲａｄｉａｔｉｏｎＰｈｙｓｉｃｓ，Ｉｎｓ...     

On the Decomposition of Hopf Module Coalgebra

In1969,Sweedler[1]giventhedecompositiontheoreyofcoalgebraswhicharecocommu-tative.In1975,Kaplansky[2]showedthatanycoalgebracanbeuniquelydecomposedintoadirectsumofitsindecomposablesubcoalgebras.From1978to1992,Shudo[3]andXu[4]consructuredtheindecomposabledirectsumcomponentsofacoalggebra,viadefineequivalenceralationforthesetofsimplesubcoalgebras.Asweknow,themodolecoalgebraisthennaturalgeneralizationofcoalgebra.AndittakesplayanimportentroleintheDrinfelddouble.Inthispaper,wediscussthedecompositio…     

超离子导体CaF2中的Ca2+亚晶格和F-亚晶格

CaF_2在熔化以前为超离子导体相。一些实验和理论的研究表明,在超离子导体相中,Ca~(2+)仍维持原有的面心立方骨架,而F~-则在Ca~(2+)骨架中运动。早期的分子动力学模拟结果表明Ca~(2+)的均方根位移仅约0.3A,而F~-的扩散系数可达2.6×10~(-5)cm·s~(-1),已是熔盐扩散系数量级。近年来的中子散射实验表明在扩散离子和近邻离子间存在着某种动力学相关。为解释这些事实,新近Gillan的分子动力学模拟表明扩散离子伴随着F~-亚晶格变形,而Kaneko和Ueda的分子动力学模拟则表明扩散离子伴随着近邻离子在同一运动方向的相关运动。进一步的研究尚待进行。八十年代初,Nelson等人提出了描述晶体、非晶和液态中键取向的键球谐函数方法。     

内吸性杀菌剂三唑醇(酮)立体异构体的研究Ⅱ

三唑醇(Triadimenol,又称Baytan)是一种优良的内吸性广谱杀菌剂。谷类作物的种子经处理后,防治病虫害的效果极为突出,可增产粮食20%。此化合物化学名称为1-(对-氯苯氧基)-1-(1′,2′,4′-三氮唑-1′基)-3,3二甲基丁醇-2,结构式(Ⅰ)见后。由于分子中含有两个手性碳原子,故应有四种光学异构体。我们实验室曾分离出毫克量的三唑醇两个非对映异构体(A体和B体),生物测定表明两者的药效有明显差別,并确定有效者为A体。根据~1H-NMR中偶合常数,     

Electrospinning of nylon-6,66,1010 terpolymer

Ultrafine nylon fibers were prepared by electrospinning of nylon-6,66,1010 terpolymer solution in 2,2,2-trifluoroethanol (TFE). The morphology, crystallinity and mechanical properties of the electrospun nylon-6,66,1010 fibers were investigated by scanning electron microscope (SEM), differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and tensile test. The effects of electrospun process parameters such as solution concentration, voltage and tip-to-collector distance on the morphology and the average size of the electrospun fibers were also studied. The results show that the spinnable concentration of nylon-6,66,1010/TFE solution is in the range of 6-14 wt%, and higher solution concentration favors the formation of uniform fibers without beads. The diameters of the electrospun fibers increase with increasing the solution concentration and decrease slightly with increasing the voltage and needle tip-to-collector distance. But no obvious morphology changes were found with the increase of the voltage and collection distance. DSC and WAXD results suggest that the electrospun nylon-6,66,1010 membranes have lower crystallinity than those of the corresponding casting films. The electrospun nylon-6,66,1010 membrane obtained from the 14 wt% concentration exhibits the largest tensile strength and elongation at break.     

1—取代苯基—1,4—二氢—6—甲基—4—哒嗪酮—3—酰胺的合成

用杂交方法培育新作物品种是农业增产的重要措施。与常规杂交育种方法相比,采用化学杀雄法(Chemical induction lf male sterility)育种具有程序简单,节省劳力,时间缩短等优点,可以诱导产生非遗传性的雄性不育母本,与另一品种的文本杂交而得优化组合的良种,国外在小麦上已试验成功但在水稻上尚在探索,美国Rohm and Haas公司曾报道一些哒嗪酮类     

A New Synthesis for Methyl 2-Benzyloxylphenylacetate

A new synthetic method for methyl 2-benzyloxylphenylacetate, a key intermediate of a new type of fungicides, had been found, which has only 3 steps. The 80% yield of the new method is a major improvement over the 30% 6-step-process reported by the literature.     

Construction of Dual Pore 3-D Digital Cores with a Hybrid Method Combined with Physical Experiment Method and Numerical Reconstruction Method

In order to further improve the accuracy of digital core modeling, a new hybrid method was proposed to construct the dual pore 3-D digital core with high precision. First of all, 3-D macro-pore digital cores were constructed by micro-CT. Secondly, based on the high-resolution 2-D scanning electron microscopy images of rock cores, micro-pore digital cores were constructed by simulated annealing method. And then, a superposition method was used to construct the digital core which could describe different pore characteristics. Finally, pore structures of digital cores were compared, and lattice Boltzmann method was used to analyze the percolation properties. The results show that the carbonate dual pore digital core constructed by the new hybrid method has a high accuracy, which can capture the pore properties of both macro-pore and micro-pore, and whose permeability simulation results are in good agreement with the experimental measurements. In addition, the new hybrid method is not only accurate and reliable, but also high efficient and economic, and can be applied to all kinds of reservoir modeling.     

马蹄金素杂环衍生物的合成及抗乙肝病毒活性

以马蹄金素[N-(N-苯甲酰基-L-苯丙氨酰基)-O-乙酰基-L-苯丙氨醇,MTS]为先导化合物,设计并合成了16个杂环取代的马蹄金素衍生物,其结构经NMR,ESI-MS和元素分析确证.以HepG2 2.2.15细胞为乙肝病毒(HBV)载体,对合成的马蹄金素衍生物进行了抗HBV活性测试.实验结果表明,在测试浓度范围内,化合物5b(IC50=8.20μg/L,SI=10.26),5g(IC50=5.58μg/L,SI=22.78)和5i(IC50=5.07μg/L,SI=16.67)的抗HBV活性较强;在8μg/mL的浓度下,其抑制率分别为56.57%,67.06%和66.83%.