排序方式: 共有37条查询结果,搜索用时 515 毫秒
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树脂对茶多酚与咖啡因的吸附分离 总被引:7,自引:1,他引:7
从低档绿茶末的水提取液中,利用离子交换,吸附树脂成功地分离出茶多酚与咖啡因,并详细考察了其交换与吸附性能。与其它方法相比,该树脂法具有产品收率高,成本低廉等特点。 相似文献
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Jinsheng Xu Mansheng Chen Chunhua Zhang Zhengji Yi 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(2):1375-1383
In this paper, the modified magnetic chitosan resin containing diethylenetriamine functional groups (DETA-MCS) was used for the adsorption of uranium ions from aqueous solutions. The influence of experimental conditions such as contact time, pH value and initial uranium(VI) concentration was studied. The Langmuir, Freundlich, Sips and Dubinin–Radushkevich equations were used to check the fitting of adsorption data to the equilibrium isotherm. The best fit for U(VI) was obtained with the Sips model. Adsorption kinetics data were tested using pseudo-first-order and pseudo-second-order models. Kinetic studies showed that the adsorption followed the pseudo-second-order kinetic model, indicating that the chemical adsorption was the rate-limiting step. The present results suggest that DETA-MCS is an adsorbent for the efficient removal of uranium(VI) from aqueous solution. 相似文献
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凹面光栅因同时具有聚焦和色散功能而广泛应用于各类紫外、可见和红外波段的光谱分析仪器中,尤其是平场凹面光栅可以结合线阵或面阵探测器来实现即时分析。凹面光栅衍射效率的高低直接影响光谱仪器的信噪比和信号采集,其相关研究也逐渐为人们所关注。介绍了凹面光栅衍射效率的研究进展,比较了由机械刻划法和全息法制作的凹面光栅在掠入射下衍射效率的差别,分析了现有计算衍射效率方法的优缺点,并且对凹面光栅衍射效率的研究趋势做了简要预测,提出了需要同时在凹面光栅的主截面和非主截面内考虑光束对其衍射效率的影响。 相似文献
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含对硝基偶氮苯基团的侧链液晶高分子的合成及其光致变色性能研究 总被引:4,自引:0,他引:4
报道了新型的含对硝基偶氮苯基团的甲基丙烯酸酯单体与含介晶基团的甲基丙烯酸酯单体的合成及其自由基共聚合.利用1H NMR、IR、UV Vis、GPC、元素分析、DTA及POM等手段对偶氮单体和聚合物进行了结构表征.证明两种单体的共聚合产物为无规共聚物,而且各聚合物在加热过程中均显示出明显的向列相液晶织构.研究了偶氮单体及其与介晶单体的共聚物的氯仿溶液和聚合物薄膜在紫外光诱导下的光异构化及热回复异构化行为.结果表明,它们在紫外光诱导下均能发生光致变色现象,而且介质对其光化学行为起决定作用. 相似文献
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A new coordination polymer {[Eu2(Cl2C6H3OCH2COO)6(H2O)4]·(DMF)4·(H2O)2}n with 2,4‐dichlorophenoxy acetic acid as the ligand has been synthesized. The crystal data for this complex are as follows: monoclinic, space group P2(1)/n, a=0.86474(17) nm, b=3.2475(7) nm, c=1.3843(3) nm, β=92.81(3) °, V=3.8827(13) nm3, Dc=1.718 g/cm3, Z=2, µ(Mo Kα)=2.093 mm−1, F(000) =2008, final discrepancy factors R1=0.0454, wR2=0.1165. The crystal structure shows that the title complex forms one‐dimensional chain structure by bridging 2,4‐dichlorophenoxy acetic acid anions. Every centric europium(III) ion is coordinated with ten oxygen atoms from five 2,4‐dichlorophenoxy acetic acid anions and two water molecules, giving a ten‐coordinated distorted bicapped square antiprism geometry. The luminescent property and thermal stability of the complex are also studied. 相似文献
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The methacrylate monomers bearing mesogenic group and heterocyclicazo dye have been synthesized. The monomeric dye was copolymerized with the mesogenicmonomer using a free radical initiator to produce polymers useful for nonlinear optics. Themonomers and polymers were characterized by IR, ~1H-NMR, and UV-Vis spectra. Theaverage molecular weight (M_w and M_n) of the polymers were determined by gel permeationchromatography. The thermal properties of the polymers such as thermal stability andphase transition behavior were studied by thermogravimetric analysis, differential thermalanalysis, polarizing optical microscope and X-ray diffractometer. The results demonstratethat the synthesized polymers are crystalline polymers at room temperature and no liquidcrystalline phases were observed for all of them. 相似文献
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Xuefeng Yang Dao Hua Zhang Zhengji Xu Yueke Wang Jun Wang 《Applied physics. B, Lasers and optics》2012,109(2):215-219
We report one- and two-dimensional arbitrary patterns which are achieved by nanocavity waveguides made of a quasi-metal?Cdielectric-metal heterostructure with omnidirectional illumination. This proposed heterostructure supports the surface plasmon polaritons whose phase and group velocities have opposite sign for given frequency. Negative refraction and reflection in the waveguide result in imaging nanolithography and the omnidirectional property can be well understood by the dispersive relation of the nanocavity waveguide. Numerical results demonstrate that such an omnidirectional nanolithography scheme is feasible for arbitrary 1D gratings and 2D linearly chirped gratings with TM and circular polarized incidence, respectively, at 365?nm. 相似文献