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T. Matsuo T. Maekawa A. Inaba O. Yamamuro M. Ohama M. Ichikawa T. Tsuchida 《Journal of Molecular Structure》2006,790(1-3):129
The heat capacities of HCrO2 and DCrO2 have been measured at temperatures between 5 and 360 K. A lambda anomaly occurred at 320 K for DCrO2 but not for HCrO2. Infrared spectra were recorded at temperatures between 5 and 405 K. The spectrum of DCrO2 changed at 320 K with respect to the peak wave-number and splitting of some of the vibrations, while those of HCrO2 depended smoothly on temperature. These experimental results are discussed in terms of a deuteration-induced phase transition. 相似文献
3.
Umakoshi H Morimoto K Ohama Y Nagami H Shimanouchi T Kuboi R 《Langmuir : the ACS journal of surfaces and colloids》2008,24(9):4451-4455
An antioxidative liposome catalysis that mimics both superoxide dismutase (SOD) and peroxidase (POD) activities has been developed by using the liposomes modified with lipophilic Mn-(5,10,15,20-tetrakis[1-hexadecylpyridium-4-yl]-21H,23H-porphyrin) (Mn-HPyP). The SOD- and POD-like activities of the Mn-HPyP-modified liposome were first investigated by varying the type of phospholipid, such as 1,2-distearyl-sn-glycero-3-phosphocholine (DSPC), 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC), 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC), and 1,2-dilauroyl-sn-glycero-3-phosphocholine (DLPC). Higher SOD-like activity was obtained in the case of DLPC and DMPC liposomes, in which the ligands were well-dispersed on the membrane in the liquid crystalline phase. The POD-like activity was maximal in the case of DMPC liposome, in which the Mn-HPyP complex was appropriately clustered on the membrane in the gel phase. On the basis of the above results, the co-induction of the SOD and POD activities to eliminate the superoxide and also hydrogen peroxide as a one-pot reaction was finally performed by using the Mn-HPyP-modified DMPC liposome, resulting in an increase in the efficiency of the elimination of both superoxide and hydrogen peroxide. 相似文献
4.
The nonequilibrium radiation of shock fronts in air is experimentally investigated by means of the imaging spectroscopy technique.
Shock velocity ranges from 9.7 to 11.6 km/s and initial pressure from 13.3 to 41.6 Pa. The spectral diagnostic system consists
of an imaging spectrograph, a streak camera, a gated image-intensified CCD camera and a personal computer for data acquisition/processing.
This spectral diagnostic system is capable of simultaneous wavelength-, intensity- and time-resolved spectroscopic measurements
in the nanosecond order. The image processing of the streak images includes a combined smoothing/deconvolution process in
the time direction to diminish experimental noise effects and the temporal broadening due to the streak camera entrance slit.
Wavelength range is chosen to investigate the first negative band of . “Large” and “slim” streak image types are observed. In the “large” streak images greater contribution from (1-)(1,0) behind the radiation peak is observed. Experimental data are compared with a streak image numerically simulated.
The numerical simulation agrees better with the “slim” streak image.
Received 7 July 1995 / Accepted 10 January 1996 相似文献
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Abe K Amako K Arai Y Asano Y Chiba M Chiba Y Daigo M Emura T Endo I Fukawa M Fukui T Fukushima Y Haba J Haidt D Hayashibara I Hemmi Y Higuchi M Hirose T Hojyo Y Homma Y Hoshi Y Ikegami Y Ishihara N Kamitani T Kanematsu N Kanzaki J Kikuchi R Kondo T Koseki T Kubo K Kurashige H Matsui T Minami M Miyake K Mori S Nagashima Y Nakamura T Nakano I Odaka S Ogawa K Ohama T Ohsugi T Ono A Osabe H Saito H Sakae H Sakamoto H Sakamoto S Sakano M Sakuda M Sasao N Sato M Shioden M Shirai J Suekane F 《Physical review letters》1988,61(8):915-918
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Novel dioxo-tungsten(VI) bis(1,2-benzenedithiolate) complexes with neighboring amide groups, as models for tungsten enzymes, (NEt4)2[W(VI)O2{1,2-S(2)-3,6-(RCONH)2C6H2}2] (R = CH3, t-Bu), were designed and synthesized. The presence of the NH...S hydrogen bond was confirmed through IR spectrometry and X-ray crystallographic analysis. In the W(VI)O2 complexes, the NH...S hydrogen bond trans to the oxo ligand is stronger than that cis to oxo. On the basis of comparisons with [W(VI)O2(1,2-S2C6H4)2](2-), the NH...S hydrogen bond positively shifted the W(VI)/W(V) redox potentials and depressed the reduction by benzoin or triphenylphosphine. These results suggest that the NH...S hydrogen bond stabilizes the oxo ligand through trans influence and regulates O-atom transfer in tungsten and molybdenum enzymes. 相似文献
7.
Baba K Okamura TA Suzuki C Yamamoto H Yamamoto T Ohama M Ueyama N 《Inorganic chemistry》2006,45(2):894-901
Novel molybdenum dithiolene compounds having neighboring amide groups as models for molybdoenzymes, (NEt(4))(2)[Mo(IV)O{1,2-S(2)-3,6-(RCONH)(2)C(6)H(2)}(2)] (R = CH(3), CF(3), t-Bu, Ph(3)C), were designed and synthesized. The contributions of the NH...S hydrogen bond to the electrochemical properties of the metal ion and the reactivity of the O-atom-transfer reaction were investigated by a comparison with [Mo(IV)O(1,2-S(2)C(6)H(4))(2)](2)(-). The MoOS(4) core of [Mo(IV)O{1,2-S(2)-3,6-(CH(3)CONH)(2)C(6)H(2)}(2)](2)(-) shows no significant geometrical difference from that of [Mo(IV)O(1,2-S(2)C(6)H(4))(2)](2)(-) in the crystal. The hydrogen bonds positively shifted the Mo(IV/V) redox potential and accelerated the reduction of Me(3)NO. 相似文献
8.
Shirai J Ohmoto T Abe K Amako K Arai Y Arima T Asano Y Chiba M Chiba Y Daigo M Fukawa M Fukushima Y Haba J Hanai H Hemmi Y Higuchi M Hinode F Hirose T Homma Y Hosoda N Ishihara N Iwata Y Kanda N Kanematsu N Kanzaki J Kikuchi R Kondo T Korhonen TT Krüger AE Kurashige H MacNaughton J Matsuda EK Matsui T Miura M Miyake K Mori S Nagashima Y Nakagawa Y Nakamura T Nakano I Odaka S Ogawa K Ohama T Ohsugi T Ohyama H Okamoto A Ono A Oyama T Sakamoto H Sakuda M Sato M Sato N Shioden M Shirakata M 《Physical review letters》1994,72(21):3313-3316
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Daisuke Sawai Kazuhiko Nagai Minato Kubota Toshio Ohama Tetsuo Kanamoto 《Journal of Polymer Science.Polymer Physics》2006,44(1):153-161
The effects of molecular weight (MW) and MW distribution on the maximum tensile properties of polyethylene (PE), achieved by the uniaxial drawing of solution‐grown crystal (SGC) mats, were studied. The linear‐PE samples used had wide ranges of weight‐average (Mw = 1.5–65 × 105) and number‐average MWs (Mn = 2.0–100 × 104), and MW distribution (Mw/Mn = 2.3–14). The SGC mats of these samples were drawn by a two‐stage draw technique, which consists of a first‐stage solid‐state coextrusion followed by a second‐stage tensile drawing, under controlled conditions. The optimum temperature for the second‐stage draw and the resulting maximum‐achieved total draw ratio (DRt) increased with the MW. For a given PE, both the tensile modulus and strength increased steadily with the DRt and reached constant values that are characteristic for the sample MW. The tensile modulus at a given DRt was not significantly affected by the MW in the lower DRt range (DRt < 50). However, both the maximum achieved tensile modulus (80–225 GPa) and strength (1.0–5.6 GPa), as well as those at higher DRts > 50, were significantly higher for a higher MW. Although the maximum modulus reached 225 ± 5 for Mn ≥ 4 × 105, the maximum strength continued to increase with Mn even for Mn > 4 × 105, showing that strength is more strongly dependent on the Mn, even at higher Mn. Furthermore, it was found that each of the maximum tensile modulus and strength achieved could be expressed by a unique function of the Mn, independently of the wide variations of the sample MW and MW distribution. These results provide an experimental evidence that the Mn has a crucial effect on the tensile properties of extremely drawn and chain‐extended PE fibers, because the structural continuity along the fiber axis increases with the chain length, and hence with the Mn. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 153–161, 2006 相似文献