排序方式: 共有23条查询结果,搜索用时 375 毫秒
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手性胺酰胺型液相色谱手性固定相的制备及几种氨基酸衍生物的拆分 总被引:1,自引:0,他引:1
用(R)-1-苯基2-对甲基苯基乙基胺(PTE)与L-异亮氨酸制得含两个手性中心的手性选择剂,以琥珀酸酐作为连接臂,将手性选择剂键合到氨基丙基硅胶上制得手性固定相。以正己烷-异丙醇为流动相,利用该固定相对氨基酸衍生物进行高效液相色谱手性拆分,并考察了流动相中异丙醇含量对手性拆分的影响。结果表明,该手性固定相对所分析的氨基酸衍生物大部分都具有一定的拆分能力。当异丙醇含量为1%时,亮氨酸与苯丙氨酸的苯甲酰甲酯衍生物获得基线分离。当异丙醇含量为20%时,亮氨酸、缬氨酸、丙氨酸、谷氨酸的3,5-二硝基苯甲酰甲酯衍生物获得基线分离。 相似文献
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A three-coordinate Ag(I) complex, [Ag(Mepzpy)(PAr3)]BF4·H2O(1, Mepzpy = 3-methyl-1-(2-pyridyl)pyrazole, PAr3 = tri(o-tolyl)phosphine), was synthesized from the reaction of Ag(CH3CN)4BF4, PAr3 and Mepzpy in CH3 CN at room temperature. The compound was characterized by UV-vis, NMR and X-ray single-crystal structure analysis. It crystallizes in triclinic space group P1 with a = 10.2251(5), b = 10.6014(5), c = 15.7012(5) , α = 92.963(3), β = 92.641(3), γ = 114.647(4)o, V = 1540.6(1) 3, Z = 2, Mr = 676.24, Dc = 1.458 g/cm3, F(000) = 688, μ = 6.187 mm-1, GOOF = 1.038, the final R = 0.0530 and w R = 0.1493 for 6371 observed reflections with I 2σ(I). Compound 1 is ionic. It is composed of a BF4- anion and a [Ag(Mepzpy)(PAr3)]+ cation. The Ag(I) ion adopts a distorted trigonal pyramidal coordination geometry defined by two nitrogen atoms and a phosphorous atom. The complex emits blue luminescence with maximum peaks at 470 nm in solid state at room temperature. 相似文献
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Sheng-Feng Hong Xiao-Huan Liang Hua-Cai Fang Xu-Lin Zhan Zheng-Yuan Zhou Li Chen Yue-Peng Cai 《Transition Metal Chemistry》2009,34(1):115-120
Two mononuclear complexes with the Schiff base ligand 2-((2-(dimethylamino)ethylimino)methyl)phenol (HL), namely ZnL2 and CoL2(N3), have been synthesized and characterized using single-crystal X-ray diffraction and spectroscopy (IR, 1H NMR, UV–Vis, MS and EA). Both complexes are mononuclear. The coordination geometry in the Zn(II) complex is distorted square-pyramidal
with a weak Zn···N interaction. The Co(III) complex is distorted octahedral, and the neutral molecule unit [CoIIIL2(N3)] is connected by C–H···N hydrogen bonds to form a one-dimensional infinite chain. The luminescence of the zinc compound
has been investigated.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
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集成化导光板下表面微结构分布是影响背光模组出射光均匀性的关键因素,因此是背光模组设计的重点之一.本文针对微棱镜一维分布设计中存在的大面积同一性影响背光模组亮度均匀性的问题,提出一种集成化导光板下表面微棱镜二维分布的设计思想,以提高背光模组的亮度均匀性.利用光学软件Lighttools对5.0英寸集成化导光板下表面微棱镜结构的较佳二维分布进行优化探索,通过与较佳的一维分布仿真结果对比分析可知,优化后的二维分布模式下,背光模组的光能利用率、照度均匀性、亮度均匀性分别达到92.03%,87.07%和91.94%,满足行业标准;其中,照度均匀性比一维分布提高了10%;同时,从亮度图观察,背光模组的整体亮度均匀性得到了有效提升.该研究结果对于背光模组轻薄化、集成化开发具有一定的参考价值. 相似文献
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以刚性配体1,3-bib(1,3-二(1H-咪唑-1-基)苯)与[Ru(η6-p-bip)Cl2]2(p-bip,联苯基团)为原料,合成了3种双核芳基钌配合物[Ru2(η6-p-bip)2(1,3-bib)2XY]X2(X=Y=Cl-(1),X=Y=Br-(2),X=I-和Y=Cl-(3),并用核磁和质谱等对配合物进行了表征。配合物1的单晶衍射结果表明其具有一种刚性双核M2L2碗状结构,空腔中心有一个阴离子Cl-。配合物3对A549细胞有较高的抗癌活性(IC50=13.9 μmol·L-1),与顺铂细胞毒性(IC50=15.2 μmol·L-1)相当。紫外吸收光谱、圆二色谱、凝胶电泳法研究表明配合物1~3与DNA发生强烈的相互作用并且诱发DNA发生解旋。 相似文献
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We report a self-collimating demonstration in planar photonic crystals (PhCs) fabricated in silicon-on-insulator (SOI) wafers using 0.18 μm silicon complimentary metal oxide semiconductor (CMOS) techniques. The emphasis was on demonstrating the self-collimation effect by using the standard CMOS equipment and process development of an optical test chip using a high-volume manufacturing facility. The PhCs are designed on the 230-nm-top-Si layer using a square lattice of air holes 280 nm in diameter. The lattice constant of the PhCs is 380 nm. The experimentally obtained wavelengths for self-collimation are in excellent agreement with theory. 相似文献
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本文对35 GHz和96 GHz电磁波在等离子体中的传输特性进行了理论与实验研究, 得到了电磁波衰减随等离子体密度、碰撞频率和电磁波频率的变化规律. 等离子体密度增加一个数量级时, 电磁波衰减增加一个数量级; 随着等离子体碰撞频率的增加, 电磁波衰减先增加后减小; 随着电磁波频率的增加, 衰减下降. 以激波管为实验平台进行了电磁波在等离子体中传输特性的实验研究, 实验结果和理论结果吻合较好. 理论和实验结果均表明, 提高电磁波频率是解决黑障问题的有效途径. 相似文献