全文获取类型
收费全文 | 5678篇 |
免费 | 819篇 |
国内免费 | 827篇 |
专业分类
化学 | 4322篇 |
晶体学 | 60篇 |
力学 | 449篇 |
综合类 | 28篇 |
数学 | 562篇 |
物理学 | 1903篇 |
出版年
2024年 | 9篇 |
2023年 | 100篇 |
2022年 | 140篇 |
2021年 | 227篇 |
2020年 | 240篇 |
2019年 | 231篇 |
2018年 | 181篇 |
2017年 | 196篇 |
2016年 | 237篇 |
2015年 | 245篇 |
2014年 | 289篇 |
2013年 | 402篇 |
2012年 | 482篇 |
2011年 | 535篇 |
2010年 | 343篇 |
2009年 | 308篇 |
2008年 | 351篇 |
2007年 | 294篇 |
2006年 | 298篇 |
2005年 | 262篇 |
2004年 | 220篇 |
2003年 | 204篇 |
2002年 | 190篇 |
2001年 | 153篇 |
2000年 | 139篇 |
1999年 | 158篇 |
1998年 | 100篇 |
1997年 | 95篇 |
1996年 | 92篇 |
1995年 | 86篇 |
1994年 | 61篇 |
1993年 | 71篇 |
1992年 | 54篇 |
1991年 | 56篇 |
1990年 | 46篇 |
1989年 | 37篇 |
1988年 | 22篇 |
1987年 | 23篇 |
1986年 | 25篇 |
1985年 | 18篇 |
1984年 | 12篇 |
1983年 | 14篇 |
1982年 | 14篇 |
1981年 | 8篇 |
1980年 | 6篇 |
1976年 | 8篇 |
1975年 | 6篇 |
1973年 | 7篇 |
1972年 | 5篇 |
1970年 | 4篇 |
排序方式: 共有7324条查询结果,搜索用时 171 毫秒
1.
2.
3.
Hu Duo-Duo Gao Qian Dai Jing-Cheng Cui Ru Li Yuan-Bo Li Yuan-Ming Zhou Xiao-Guo Bian Kang-Jie Wu Bing-Bing Zhang Kai-Fan Wang Xi-Sheng Li Yan 《中国科学:化学(英文版)》2022,65(4):753-761
Science China Chemistry - A light-induced, nickel-catalyzed three-component arylsulfonation of 1,3-enynes in the absence of photocatalyst is reported. This methodology exhibited mild conditions,... 相似文献
4.
In this research article, we describe the synthesis and characterization of mononuclear and dinuclear Cu complexes bound by a family of tridentate redox-active ligands with tunable H-bonding donors. The mononuclear Cu-anion complexes were oxidized to the corresponding “high-valent” intermediates by oxidation of the redox-active ligand. These species were capable of oxidizing phenols with weak O−H bonds via H-atom abstraction. Thermodynamic analysis of the H-atom abstractions, which included reduction potential measurements, pKa determination and kinetic studies, revealed that modification of the anion coordinated to the Cu and changes in the H-bonding donor did not lead to major differences in the reactivity of the “high-valent” CuY complexes (Y: hydroxide, phenolate and acetate), which indicated that the tridentate ligand scaffold acts as the H+ and e− acceptor. 相似文献
5.
A new asymmetric Salamo‐based ligand H2L was synthesized using 3‐tert‐butyl‐salicylaldehyde and 6‐methoxy‐2‐[O‐(1‐ethyloxyamide)]‐oxime‐1‐phenol. By adjusting the ratio of the ligand H2L and Cu (II), Co (II), and Ni (II) ions, mononuclear, dinuclear, and trinuclear transition metal (II) complexes, [Cu(L)], [{Co(L)}2], and [{Ni(L)(CH3COO)(CH3CH2OH)}2Ni] with the ligand H2L possessing completely different coordination modes were obtained, respectively. The optical spectra of ligand H2L and its Cu (II), Co (II) and Ni (II) complexes were investigated. The Cu (II) complex is a mononuclear structure, and the Cu (II) atom is tetracoordinated to form a planar quadrilateral structure. The Co (II) complex is dinuclear, and the two Co (II) atoms are pentacoordinated and have coordination geometries of distorted triangular bipyramid. The Ni (II) complex is a trinuclear structure, and the terminal and central Ni (II) atoms are all hexacoordinated, forming distorted octahedral geometries. Furthermore, optical properties including UV–Vis, IR, and fluorescence of the Cu (II), Co (II), and Ni (II) complexes were investigated. Finally, the antibacterial activities of the Cu (II), Co (II), and Ni (II) complexes were explored. According to the experimental results, the inhibitory effect was found to be enhanced with increasing concentrations of the Cu (II), Co (II), and Ni (II) complexes. 相似文献
6.
Abstract Gastrodigenin, also known as 4-hydroxybenzyl alcohol (HBA), is one of the main components of Gastrodia elata, which is a perfect lead compound of natural products. In order to get new active compounds, we modified the structure of HBA through esterification with carboxylic acid, and got a series of derivatives in which 4-hydroxybenzyl alcohol 2-naphthoate (NHBA) showed stronger antidepressant activity than HBA. In this paper, we firstly evaluated the antidepressant activity of NHBA by tail suspension test (TST) and forced swimming test (FST). Then, we carried out the biochemical assay and western blot to determine its mechanism. The results displayed that NHBA could increase the content of serotonin, dopamine, norepinephrine, γ-aminobutyric acid, brain-derived neurotrophic factor (BDNF) and tropomyosin receptor kinase B (TrkB) in mice brain. It suggested that NHBA exhibited an antidepressant-like effect through monoaminergic system, GABAergic system and BDNF/TrkB signaling pathways. 相似文献
7.
L. Tong Y. Tian Q. Y. Wang Y. S. Ling 《International Journal of Infrared and Millimeter Waves》2006,27(9):1307-1314
The paper introduces a special system calibration technology in s-parameters measurement of microwave and millimeter wave
devices. The 8-term errors module is built by analyzing the signals flowing in the measurement system. Then the calibration
technology using non-standard kits is designed on the base. Finally, the experiment using the calibration technology is introduced. 相似文献
8.
A lithium(I) coordination polymer has been formed from LiClO4 and the 2,2′‐bipyrimidine (bpym) ligand in which each square pyramidal lithium(I) atom is coordinated in the basal plane by four nitrogen donor atoms derived from two bpym ligands and one water molecule at the apical position. These are connected into a layer structure via hydrogen‐bonding interactions involving the perchlorate anions. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
9.
10.