全文获取类型
收费全文 | 1475篇 |
免费 | 45篇 |
国内免费 | 7篇 |
专业分类
化学 | 1023篇 |
晶体学 | 14篇 |
力学 | 17篇 |
数学 | 158篇 |
物理学 | 315篇 |
出版年
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 12篇 |
2019年 | 13篇 |
2018年 | 5篇 |
2017年 | 20篇 |
2016年 | 30篇 |
2015年 | 24篇 |
2014年 | 27篇 |
2013年 | 77篇 |
2012年 | 52篇 |
2011年 | 88篇 |
2010年 | 40篇 |
2009年 | 60篇 |
2008年 | 81篇 |
2007年 | 101篇 |
2006年 | 88篇 |
2005年 | 107篇 |
2004年 | 90篇 |
2003年 | 69篇 |
2002年 | 71篇 |
2001年 | 24篇 |
2000年 | 24篇 |
1999年 | 24篇 |
1998年 | 14篇 |
1997年 | 18篇 |
1996年 | 14篇 |
1995年 | 8篇 |
1994年 | 15篇 |
1993年 | 13篇 |
1992年 | 27篇 |
1991年 | 11篇 |
1990年 | 13篇 |
1989年 | 12篇 |
1988年 | 9篇 |
1987年 | 11篇 |
1986年 | 5篇 |
1985年 | 22篇 |
1984年 | 19篇 |
1983年 | 13篇 |
1982年 | 22篇 |
1981年 | 12篇 |
1980年 | 22篇 |
1979年 | 20篇 |
1978年 | 10篇 |
1977年 | 12篇 |
1976年 | 8篇 |
1975年 | 15篇 |
1974年 | 12篇 |
1973年 | 9篇 |
排序方式: 共有1527条查询结果,搜索用时 218 毫秒
1.
Atsuhiro Fujimori Mikako Ishitsuka Hiroo Nakahara Eisuke Ito Masahiko Hara Kaname Kanai Hisao Ishii Yukio Ouchi Kazuhiko Seki 《Journal of Polymer Science.Polymer Physics》2004,42(12):2329-2336
Photopolymerization of cadmium 10,12-pentacosadiynoate (CdDA) in Langmuir–Blodgett (LB) films, with the molecular packing well arranged by moderate preannealing, was investigated with near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. Greenish films of polydiacetylene with an absorption wavelength of 705 nm were obtained through the photopolymerization of preannealed monomer LB films, and this resulted in an extended π-conjugate system based on the well-ordered monomer in a two-dimensional arrangement. The electronic structures of the polydiacetylenes were found to be correlated to the variation of the molecular arrangements in the films from the changes in the NEXAFS spectra through photopolymerization in the LB films. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2329–2336, 2004 相似文献
2.
Akihide Itoh Taisuke Nagasawa Yanbei Zhu Kyue-Hyung Lee Eiji Fujimori Hiroki Haraguchi 《Analytical sciences》2004,20(1):29-36
In order to elucidate the distributions of the elements among the particulate and dissolved fractions in pond water, major-to-ultratrace elements in different sizes of particles as well as in the filtrate passed through the 0.05 microm filter were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The different sizes of particle samples (ca. 100-300 microg each) were collected on the membrane filters with pore sizes of 10, 3.0, 1.2, 0.4, 0.2 and 0.05 microm, respectively, by sequential fractionation. As a result, about 40 elements in different sizes of particles could be determined by ICP-AES and ICP-MS, after acid digestion using HNO3/HF/HClO4. Then, the fractional distribution factors of major-to-ultratrace elements among the particulate and dissolved fractions were estimated from the analytical results. The total contents of Al, Fe, Ti, REEs (rare earth elements), Bi, Pb and Ag in the particulate fractions (larger than 0.05 microm) were more than 80-90%, while those of Ca, Sr, Cs, W, Ba, Mn and Co in the dissolved fraction, which corresponded to the filtrate passed through the 0.05 microm membrane filter, were more than 80%. It was further found that the fractional distributions of Cu and Zn in the dissolved fraction were ca. 50%. In addition, the enrichment factors (EFs) of the elements in the particulate fractions with particle sizes of 3.0-10 microm and 0.05-0.2 microm were estimated to elucidate their geochemical characteristics in natural water. 相似文献
3.
4.
Endoscopic Observation of Tissue by Narrowband Illumination 总被引:6,自引:0,他引:6
Kazuhiro Gono Kenji Yamazaki Nobuyuki Doguchi Tetsuo Nonami Takashi Obi Masahiro Yamaguchi Nagaaki Ohyama Hirohisa Machida Yasushi Sano Shigeaki Yoshida Yasuo Hamamoto Takao Endo 《Optical Review》2003,10(4):211-215
We propose a new illumination method for a medical endoscope: narrow band imaging (NBI), in which the spectral bandwidth of the filtered light is narrowed. To confirm how the spectral specifications of the filtered light influence a reproduced image, an experiment was conducted observing the endoscopic images of the back mucosa of a human tongue. In addition, the effect of NBI on endoscopic images was investigated through preliminary clinical tests in colonoscopy and upper gastrointestinal endoscopy. It has been shown that NBI can enhance the capillary pattern and the crypt pattern on the mucosa. These patterns are useful features for diagnosing an early cancer. 相似文献
5.
A new method for rotation and brightness invariant pattern recognition was proposed by applying multiple circular harmonic expansions to the joint transform correlator. The amplitudes of the multiple orders of circular harmonic expansions made from a detecting image were synthetically modified to respond to the same auto-correlation peaks. These modified circular harmonic expansions were arranged in the input plane as reference patterns together with an arbitrary target pattern, and the correlation signals between them were calculated in the subtracted joint transform correlator. The fraction of the correlation-peak intensities between the target and the references were extracted as a new discrimination parameter. This new parameter performs pattern recognition under rotation and brightness invariance with good discriminability. Its high discriminability has been proved in computer simulations using the face image patterns of many individuals. 相似文献
6.
35Cl NQR as well as heat capacity measurements of [(PyO)H][AuCl4] and its deuterated analog [(PyO)D][AuCl4] revealed successive phase transitions at 70.5 and 62.5 K, and at 71 and 63 K, respectively. The NQR frequency varied continuously through the upper transition point while discontinuously through the lower transition point. In the intermediate-temperature phase a remarkable decrease in the signal intensity was observed. These NQR observations as well as the feature of the heat capacity anomaly in which a broad peak is succeeded by a sharp peak with decreasing temperature suggest a possibility of normal-incommensurate-commensurate phase sequence. 相似文献
7.
Linear propagation of two pulses through methanol solution of aluminum phthalocyanine chloride is investigated using a modified white-light Michelson interferometer. The observed coherence time of the white light is 6 fs, and the separation between the two-excitation pulses is set to about 10 fs. The excitation is dependent on the phase-relation between the two pulses. We have observed an enhancement of the excitation when the two pulses are in-phase and strong suppression of the excitation when the two pulses are out of phase by π. 相似文献
8.
Betancourt L Takao T Hernandez L Padron G Shimonishi Y 《Journal of mass spectrometry : JMS》1999,34(3):169-174
High-resolution matrix-assisted laser desorption/ionization time-of-flight mass spectrometry was used to characterize the primary structure of the levansucrase (EC 2.4.1.10) secreted by Acetobacter diazotropicus SRT4. The technique permitted not only the reading frame of this enzyme, the amino acid sequence of which was deduced from DNA, but also the elucidation of an N-terminal blocking group and the position of a disulfide bridge between Cys309 and Cys365 among the three Cys residues. A free cysteine (Cys127) was identified by modifying an intact molecule with a sulfhydryl reagent, 5-(octyldithio)-2-nitrobenzoic acid, under non-reducing conditions. In addition, the enzyme obtained by site-directed mutagenesis at Asp279 to Asn279 was also identified by the above methods. Post-source decay analysis of the tryptic peptide containing the mutation site unequivocally revealed an Asn residue at position 279. 相似文献
9.
10.