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排序方式: 共有152条查询结果,搜索用时 56 毫秒
1.
Total Synthesis of Proposed Structure of Yuremamine and All Diastereomers Using [3+2]‐Cycloaddition of Platinum‐Containing Azomethine Ylide 下载免费PDF全文
Tomoya Ohyama Masako Uchida Prof.Dr. Hiroyuki Kusama Prof. Dr. Nobuharu Iwasawa 《化学:亚洲杂志》2015,10(9):1850-1853
Total synthesis of the proposed structure of yuremamine has been achieved for the first time based on the intermolecular [3+2]‐cycloaddition reaction of the platinum‐containing azomethine ylide. All the possible diastereomers of yuremamine were also synthesized via the common intermediate. Through these syntheses, it was confirmed that the proposed structure of yuremamine and the diastereomers differ from the natural product. 相似文献
2.
M Ishibashi Y Ohyama K Watanabe Y Hayashi W Takasaki A Nakagawa M Mizugaki 《Chemical & pharmaceutical bulletin》1989,37(11):3171-3173
[1,1-18O2]11-Dehydrothromboxane B2 (11-dehydro-TXB2) was prepared by repetitive base-catalyzed hydrolysis of the lactone ring of its [1,1,11-18O3]-analogue, and evaluated for its suitability as an internal standard in gas chromatography/selected ion monitoring (GC/SIM) of 11-dehydro-TXB2. Use of the present [18O2]-analogue as an internal standard may make it a suitable candidate for specific immunoaffinity purification followed by GC/SIM. 相似文献
3.
Endoscopic Observation of Tissue by Narrowband Illumination 总被引:6,自引:0,他引:6
Kazuhiro Gono Kenji Yamazaki Nobuyuki Doguchi Tetsuo Nonami Takashi Obi Masahiro Yamaguchi Nagaaki Ohyama Hirohisa Machida Yasushi Sano Shigeaki Yoshida Yasuo Hamamoto Takao Endo 《Optical Review》2003,10(4):211-215
We propose a new illumination method for a medical endoscope: narrow band imaging (NBI), in which the spectral bandwidth of the filtered light is narrowed. To confirm how the spectral specifications of the filtered light influence a reproduced image, an experiment was conducted observing the endoscopic images of the back mucosa of a human tongue. In addition, the effect of NBI on endoscopic images was investigated through preliminary clinical tests in colonoscopy and upper gastrointestinal endoscopy. It has been shown that NBI can enhance the capillary pattern and the crypt pattern on the mucosa. These patterns are useful features for diagnosing an early cancer. 相似文献
4.
H. Ohyama E. Simoen C. Claeys K. Takakura H. Matsuoka T. Jono J. Uemura T. Kishikawa 《Physica E: Low-dimensional Systems and Nanostructures》2003,16(3-4):533
Results are presented of a detailed study of the effects of high-temperature 4-MeV neutron irradiation on the performance degradation of Si pin photodiodes together with the radiation-induced defects, observed by deep level transient spectroscopy. The degradation of the device performance and the introduction rate of the lattice defects decrease with increasing sample temperature during irradiation. For a 250°C irradiation, the reduction of the reverse current is only 20% of the starting value. This result suggests that the creation and recovery of the radiation damage proceeds simultaneously at high temperatures. Carbon-related complex as hole capture levels is also mainly responsible for the device degradation for high-temperature neutron irradiation. 相似文献
5.
Katsuo Ohkata Yoshihiko Ohyama Yuko Watanabe Kin-ya Akiba 《Tetrahedron letters》1984,25(40):4561-4564
Substituents at 5-position of 5-amino-3-methyl- and 3-p-chlorophenyl-5-methylisothiazoles (7 and 8) were silylated and then lithiated to couple with aromatic nitriles in order to afford the adducts (4 and 5) via 1,3-silyl group shift. Desilylation of 5 with TBAF gave solely non-ring-transformed product (3-α-form). By using the pure sample of 3-α-form, the reversible ring-trans- formation (bond switch) was observed for the first time. 相似文献
6.
Maria Madjarova Mitsugu Kakuta Takashi Obi Masahiro Yamaguchi Nagaaki Ohyama 《Optical Review》1998,5(3):143-151
Pseudo-random properties of a class of two-dimensional (2-D) 5-neighborhood cellular automata (CA), built around nonlinear (OR, AND) and linear (XOR) Boolean functions are studied. The site values at each step of the 2-D CA evolution are taken in parallel and form pseudo-random sequences, which satisfy the criteria established for pseudo random number generator (PRNG): long period, excellent random qualities, single bit error propagation (avalanche criteria), easy and fast generation of the random bits. A block-scheme for secure Stream Cipher based on 2-D CA is proposed. The 2-D CA based PRNG algorithm has simple structure, use space-invariant and local interconnections and can be easily realized in very large scale integration or parallel optoelectronic architectures. 相似文献
7.
We present the concept of integrated processing to combine intuitive processing of neural networks with logical processing of the conventional digital computer. We investigate a way to embody the concept in the neural network system by introducing external constraints in terms of external input. The effect of the external input is analyzed using the generalized projection method. The concept of integrated processing is applied to an image associative memory system, and the system is optically implemented for high-speed parallel processing incorporating it with the computer. The experimental result is presented to illustrate the effectiveness of the external input to control the output of the image associative memory. 相似文献
8.
N. Iwasa T. Akazawa S. Ohyama K. Fujikawa N. Takezawa 《Reaction Kinetics and Catalysis Letters》1995,55(2):245-250
Pd/ZnO and Pt/ZnO exhibited high catalytic performance for the dehydrogenation of methanol to methyl formate upon the formation of PdZn and PtZn alloys. 相似文献
9.
The single photon emission computed tomography (SPECT) imaging system has shift-variant characteristics due to non-uniform attenuation of gamma-ray, collimator design, scattered photons, etc. In order to provide quantitatively accurate SPECT images, these characteristics should be compensated in the reconstruction. This paper presents a new method to correct the shift-variant characteristics, which is based on a continuous-discrete mapping model and filtered backprojection (FBP) method, in which the projection data are assumed to be acquired by narrow ray sum beams in the FBP method and the assumed data set is expressed as a linear combination of the actual projection data. Narrow ray sum beams are approximated by a weighted sum of the original sensitivity functions. Thus, at the reconstruction the projection data are first modified using an approximation and the FBP method is then applied to the corrected projection data and a SPECT image is reconstructed. We further propose a technique that requires the inversion of smaller matrices than the conventional algebraic method; the amount of calculation and memory space become smaller and the stability of the calculation is greatly improved as well. The results of the numerical simulations are also demonstrated. 相似文献
10.
Analysis of Spectral Reflectance Using Normalization Method from Endoscopic Spectroscopy System 总被引:2,自引:0,他引:2
Masao Sambongi Makoto Igarashi Takashi Obi Masahiro Yamaguchi Nagaaki Ohyama Masahiko Kobayashi Yasushi Sano Shigeaki Yoshida Kazuhiro Gono 《Optical Review》2002,9(6):238-243
Objective assessment of gastrointestinal mucosal color is extremely important in the endoscopic diagnosis of digestive tract disease. In this paper, we propose a method to clarify the spectral characteristics of gastric and colon cancer. A large number of spectral reflectance data of mucous membrane are measured by the endoscopic spectroscopy system (ESS) in the National Cancer Center Hospital East, Kashiwa, Japan and the Department of Internal Medicine, Self-Defense Force Center Hospital, Tokyo, Japan. We assume that early cancer appears primarily in the spectral data of short wavelength, because it is usually present in a superficial cell where short wavelength light is scattered more strongly than long wavelength light. To identify the features in the short wavelength components, the spectral reflectance was divided by the reflectance of a long wavelength. We investigated the possibility of distinguishing early cancer from normal spectral data through statistical analysis, employing the projection axis as the mean difference between them. Early cancer and normal spectral data were projected on the projection axis, and the Student’s T-test was applied to evaluate the mean of the distribution between these data. 相似文献