全文获取类型
收费全文 | 94篇 |
免费 | 9篇 |
国内免费 | 11篇 |
专业分类
化学 | 65篇 |
晶体学 | 2篇 |
力学 | 20篇 |
综合类 | 1篇 |
数学 | 8篇 |
物理学 | 18篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2021年 | 4篇 |
2020年 | 2篇 |
2019年 | 6篇 |
2018年 | 4篇 |
2017年 | 6篇 |
2016年 | 7篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 9篇 |
2012年 | 4篇 |
2011年 | 10篇 |
2010年 | 4篇 |
2009年 | 5篇 |
2008年 | 2篇 |
2007年 | 7篇 |
2006年 | 3篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 4篇 |
2002年 | 3篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 5篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1993年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有114条查询结果,搜索用时 31 毫秒
1.
2.
The dehydration of 2-picolinamide to produce 2-cyanopyridine was investigated thoroughly using silica supported potassium oxide as a heterogeneous catalyst. Both large specific surface area and pore size of SiO_2 (B) contributed to the favorable catalytic performance for the synthesis of 2-CP. In addition, the yield of 2-CP showed the linear relationship with the amounts of medium basicity of the catalysts,demonstrating that medium basic sites were the active sites of silica supported potassium oxide catalysts. The catalysts were further characterized by XRD and FT-IR to clarify the active species. The results indicated the Si—O—K group produced by the reaction of K_2CO_3 with Si—OH was the active species, which was further evidenced by the adjustment of the amount of Si—OH by silylation and hydroxylation procedure. 相似文献
3.
4.
5.
6.
7.
Zhiber-Shabat方程,描述许多重要的物理现象,是一类重要的非线性方程,有着许多广泛的应用前景.本文给出Zhiber-Shabat方程的多辛几何结构和多辛Fourier拟谱方法.数值算例结果表明多辛离散格式具有较好的长时间的数值稳定性. 相似文献
8.
高功率宽调谐范围掺Yb3+光子晶体光纤激光器 总被引:1,自引:0,他引:1
采用闪耀光栅作为色散元件,构建了前向、后向输出两种结构的可调谐掺Yb3 光子晶体光纤激光器,并对其输出特性进行了分析研究.在抽运功率5.75W时,前向输出结构实现了1050.6~1110.2 nm的连续调谐输出,光谱线宽约0.1 nm,边模抑制比大于44 dB.在调谐激光波长为1085 nm时,得到最高输出功率677 mW.结构改进的后向输出结构的可调谐输出结构在抽运功率4.43 W,调谐波长1075 nm,实现了2.21 W的功率输出,斜率效率为73%;调谐范围50.9 nm(1042.1~1093 nm),光谱线宽小于0.08 nm,边模抑制比大于50 dB.两种结构的可调谐激光器输出均为线偏振光,偏振度大于89.5%. 相似文献
9.
Chunyang Zhou Chongfeng Wu Shengping Zhang Xuejun Huang 《Insurance: Mathematics and Economics》2008,42(1):255-260
In this paper, we discuss how a risk-averse individual under an intertemporal equilibrium chooses his/her optimal insurance strategy to maximize his/her expected utility of terminal wealth. It is shown that the individual’s optimal insurance strategy actually is equivalent to buying a put option, which is written on his/her holding asset with a proper strike price. Since the cost of avoiding risk can be seen as a risk measure, the put option premium can be considered as a reasonable risk measure. Jarrow [Jarrow, R., 2002. Put option premiums and coherent risk measures. Math. Finance 12, 135-142] drew this conclusion with an axiomatic approach, and we verify it by solving the individual’s optimal insurance problem. 相似文献
10.
Thermal behaviour and mechanical properties of novel RTV silicone rubbers using divinyl-hexa[(trimethoxysilyl)ethyl]-POSS as cross-linker 总被引:1,自引:0,他引:1
Divinyl-hexa[(trimethoxysilyl)ethyl]-POSS (DVPS) as an octavinyl-POSS derivative was first prepared. A series of novel polydimethylsiloxane (PDMS)/DVPS hybrid materials as room temperature vulcanized (RTV) silicone rubber were prepared. The chemical incorporation of novel POSS into hydroxyl-terminated PDMS system by hydrolytic condensation reaction was verified by attenuated total reflection (ATR) infrared spectroscopy. Thermal degradation, thermo-oxidative stability and mechanical properties of these novel RTV silicone rubbers were studied by means of thermogravimetric analysis and tensile testing. The results exhibited significantly enhanced effects on the thermal stabilities and mechanical properties as compared to the PDMS polymer prepared with tetraethoxysilane (TEOS). The observed improvements in thermal properties could be attributed to the effective three-dimensional network structures resulting from the structure of DVPS. The thermal decomposition of the RTV silicone rubbers in nitrogen was also monitored by TGA coupled with real-time FTIR, and the degradation residues were also characterized by FTIR. It was found that the POSS cross-linker facilitated the formation of cross-links in the degradation residues. The striking improvement in mechanical properties could be attributed to the synergistic action of the structure of three-dimensional multi-arm cross-linker (vinyl-POSS derivative), the plasticization of self-cross-linking Vinyl-POSS derivative and perfect distribution of vinyl-POSS derivative. 相似文献