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1.
Naoto Takase Junpei Kuwabara Seong Jib Choi Takeshi Yasuda Liyuan Han Takaki Kanbara 《Journal of polymer science. Part A, Polymer chemistry》2015,53(4):536-542
The Pd‐catalyzed polycondensation of 4‐octylaniline with various dibromoarylenes was carried out under microwave heating. Microwave heating led to a decrease in the reaction time and an increase in the molecular weight of the polymers as compared to conventional heating. Microwave heating also allowed the catalyst loading to be reduced to 1 mol %, yielding polymerization results that were comparable to those under conventional heating and 5 mol % catalyst. Investigations regarding field‐effect transistors and organic photovoltaic cells using the obtained poly(arylamine) with azobenzene units revealed that increasing the molecular weight of the polymer led to improved device performance, including hole mobility and power conversion efficiency. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 536–542 相似文献
2.
Hisatoyo Morinaga Natsumi Ogawa Mayu Sakamoto Hiroshi Morikawa 《Journal of polymer science. Part A, Polymer chemistry》2019,57(24):2466-2473
The thiol‐ene reaction between trans‐limonene oxide (trans‐LO) and ethane‐1,2‐dithiol in the presence of triethylborane affords a bio‐based bis‐functional epoxide (bis‐trans‐LO). The crosslinking reaction of bis‐trans‐LO with branched polyethyleneimine (BPEI; Mn = 600; BPEI600) at a feed ratio of bis‐trans‐LO/BPEI600 = 57/43 (wt/wt) yields the corresponding network polymer with Td10 (10% thermal decomposition temperature) of 304.7 °C in 98% yield. In contrast, negligible amounts of network polymer are obtained by the reaction of bis‐LO (bis‐functional epoxide derived from cis and trans‐LO) and BPEI600 regardless of the feed ratio. The mechanical strengths as measured by direct tensile tests of the network polymers derived from bis‐trans‐LO and BPEI600,1800 (Mn = 600 and 1800) were approximately 16 and 11 times higher than that of bis‐LO and BPEI1800, respectively. The tensile shear strengths of the metal‐to‐metal adhesive bonds induced by bis‐trans‐LO and BPEI600,1800 were 9.5 and 14.1 MPa, respectively. DMA revealed that the storage modulus of the network polymer derived from bis‐trans‐LO and BPEI1800 in the rubber region was higher than that of the material prepared from bis‐LO and BPEI1800, indicating higher crosslink density of the bis‐trans‐LO/BPEI1800 system. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 2466–2473 相似文献
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An optical fiber multi-function device consisting of a single gradient-index-rod lens and a multi-facet blazed reflection
grating is proposed to simultaneously realize functions of wavelength demultiplexing and optical signal distribution in a
multimode optical fiber transmission system. We analyzed the demultiplexing characteristics and the tolerance of optical components
using the ray trace method. This device can realize not only low loss optical signal distribution but also offers improved
demultiplexing characteristics in comparison with the previously proposed demultiplexer-multiposition switch. The following
characteristics are expected from the design using commercially available optical components: a working band of 0.64–0.88
μm, channel separation of 34–36 nm, 3 dB bandwidth of 27–28 nm, channel cross-talk of less than - 40 dB and minimum excess
insertion loss of 0.9–2.1 dB. 相似文献
7.
R. Minami A. Kasugai K. Takahashi N. Kobayashi Y. Mitsunaka K. Sakamoto 《International Journal of Infrared and Millimeter Waves》2006,27(1):13-24
A high efficiency launcher of quasi-optical (QO) mode converters for high power gyrotrons have been designed and tested. A
helical cut launcher radiates the RF power via its straight cut onto the first phase correcting mirror. The launchers have
been optimized for the TE31.8 mode at 170 GHz and TE22.6 mode at 110 GHz by numerically optimizing a launcher surface. The helical cut of the launcher has been optimized by taking
the taper angle into account. Further more, the amplitude of the surface perturbation have been optimized for improved focusing
in order to reduce the diffraction losses at the helical cut. Low power measurement shows a good agreement with the design.
High efficiency characteristics of the design have also been calculated on the assumption of frequency downshift due to the
thermal expansion of the cavity and stepwise frequency tuning by changing the operating mode. Besides, the possibility of
high efficiency launcher for higher mode is discussed, and these results give the prospect to high efficiency long pulse gyrotrons. 相似文献
8.
Tomohiro Kyotani Sonoko Kakui Takehito Mizuno Naoto Shimotsuma Soushi Inoue Junji Saito 《Analytical sciences》2006,22(7):1031-1034
A zeolite NaA (LTA) membrane supported by an alumina porous support tube for pervaporation (PV) dehydration of ethanol was characterized by transmission electron microscopy (TEM) using a focused ion beam (FIB) thin-layer specimen preparation technique and by Fourier transform infrared attenuated total reflectance method (FTIR-ATR) using a diamond prism as the waveguide. FIB-TEM clearly presented cross-section images up to about 15 microm depth from the membrane surface. FTIR-ATR monitored the Si-O asymmetric stretching vibration spectrum. The Si-O spectrum was compared with the TEM image and their relationships were discussed. By combining the two methods, we could study the thickness of surface LTA crystals, the grain boundary, the LTA/alumina interface structure and the crystallinity and density of materials inside of the alumina porous support. Consequently, fine structure changes of the LTA membrane corresponding to the hydrothermal synthesis condition could be sensitively detected. 相似文献
9.
The paper presents the first report on χ(2) polarization induced in molecular glass of conjugated compound by all-optical poling. Transparent thin film of molecular glass of 1,4-bis[2-[4-[N,N-di(p-tolyl)amino]phenyl]vinyl]benzene (BTAPVB) was prepared using a spin-cast technique. Dipolar as well as octupolar components in BTAPVB contributed to the formation of photoinduced χ(2) polarization. Growth rate of χ(2) polarization has good linear relation with Eω4E2ω, which suggested that the simultaneous processes of two-photon (ω + 2ω) and three-photon (ω + ω + ω) excitation on the same electronic level contributed to the formation of photoinduced χ(2) polarization. 相似文献
10.
Masaki Kurokiba Naoto TanakaAtusi Tani 《Journal of Mathematical Analysis and Applications》2002,272(2):448-457
In this paper we consider the Eguchi-Oki-Matsumura equation which consists of the fourth- and second-order coupled equations of parabolic type. It is shown that this system admits the unique global solution. 相似文献