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排序方式: 共有66条查询结果,搜索用时 312 毫秒
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A novel rapid, convenient and sensitive electrochemical method has been described for the determination of theophylline in pharmaceutical formulations, based on the extraordinary properties of an aligned carbon nanotubes (ACNTs) thin film. The voltammetric results suggest that the ACNTs-coated glass carbon electrode can exhibit excellent electrochemical activity for direct electrochemical oxidation of theophylline. Various experimental parameters such as solution pH value, amount of ACNTs suspension, accumulation conditions and scan rate were optimized for the determination of theophylline. Furthermore, it was found that the peak current increased linearly with the concentration of theophylline in the range of 8.0 × 10?8?1.0 × 10?5 M and the detection limit was 1.6 × 10?8 M using differential pulse voltammetry. This newly proposed method has been applied successfully to the determination of theophylline in drugs. 相似文献
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Jinlian Ren Binxin Yang Tao Jiang Hongyan Mai 《International Journal of Computational Fluid Dynamics》2013,27(7):365-386
In this article, an improved smoothed particle hydrodynamics (SPH) method is proposed to simulate the filling process with two inlets. Improvements are achieved by deriving a corrected kernel gradient of SPH and a density re-initialisation. In addition, a new treatment of solid wall boundaries is presented. Thus, the improved SPH method has higher accuracy and better stability, and conserves both linear and angular momentums. The validity of the new boundary treatment is shown by simulating the spin-down problem. The bench tests are also presented to demonstrate the performance of the improved SPH method. Then the filling process with a single inlet is simulated to show the ability to capture complex-free surface of the proposed method. Finally, the filling process with two inlets is numerically investigated. The numerical results show that the filling patterns are affected significantly by Reynolds number, aspect ratio of the container and the location of the inlets. 相似文献
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本文介绍了利用超声振动能量制取超细金属粉末的超声雾化方法,提出了超声制粉雾化室,等离子枪,阴极、阳极喷咀及换能器振动系统的最佳尺寸和工作参数,给出了实验结果及制得的粉末显微结构照片.实验结果表明,用本文所述方法制得的金属粉末组成为:-80目粉占84呢,-120目粉占63.7啪,而用PREP方法制得的粉末分别占19.5%和11.7%,由此看来,用本方法制取超细金属粉,在粒度组成方面优于PREP方法.文中还对粉末冷却速度做了估算,得到了粉末平均冷却速度大于1×10_5k/5 相似文献
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Luo X Chen Z Xiao W Li Z Wang Q Zhong J 《Journal of colloid and interface science》2011,362(1):113-117
The complexes of maleic N-monoalkylamides and aliphatic amines lead to the formation of sheet-like and fiber-shaped aggregates in diverse organic solvents. Their morphologies and microstructures were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), as well as small angle X-ray diffraction (SA-XRD). The results reveal that the alkyl chain lengths of 8-12 carbons for maleic N-monoalkylamides, and 12-18 carbons for aliphatic amines, are suitable for obtaining highly efficient two-component gelators. 相似文献
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Journal of Algebraic Combinatorics - In this paper, we demonstrate a method for calculating the production matrices for the Euler-genus polynomials of H-linear families of graphs. Particularly, for... 相似文献
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Jinlian Hu Bipin Kumar Harishkumar Narayana 《Journal of Polymer Science.Polymer Physics》2015,53(13):893-898
Like shape memory polymers, a novel phenomenon of stress memory was shown in which the stress of a material can respond to an external stimulus. This concept was further enlightened by a switch‐spring‐frame model that would eliminate the limitation of existing models which overlooked the stimulus responsive nature of such polymers. The discovery being reported in this article was stemmed from a real case study into shape memory polymer fibers in compression stocking for varicose veins. The breakthrough of stress memory enabled researchers to develop applications needing stimuli‐responsive forces, which can broaden the horizon of such smart polymers in emerging smart products in many multidisciplinary fields such as sensors, stress garments, and massage devices, electronic skins, and artificial muscles. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 893–898 相似文献
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Dr. Peng Dong Tingna Shao Jinlian Li Xiaohui Zhang Prof. Yu Zhao Prof. Xinhong Zhao Prof. Guixian Li 《欧洲无机化学杂志》2023,26(33):e202300483
Cyclohexane epoxide, which contains highly active epoxy groups, plays a crucial role as an intermediate in the preparation of fine chemicals. However, controlling the epoxidation pathway of cyclohexene is challenging due to issues such as the allylic oxidation of cyclohexene and the ring opening of cyclohexane epoxide during the cyclohexene epoxidation process to form cyclohexane oxide. This review focuses on the structure-activity relationships and synthesis processes of various heterogeneous transition metal-based catalysts used in cyclohexene epoxidation reactions, including molybdenum(Mo)-based, tungsten(W)-based, vanadium(V)-based, titanium(Ti)-based, cobalt(Co)-based, and other catalysts. Initially, the mechanism of cyclohexene epoxidation by transition metal-based catalysts is examined from the perspective of catalytic active centers. Subsequently, the current research of cyclohexene epoxidation catalysts is summarized based on the perspective of catalyst support. Additionally, the differences between alkyl hydroperoxide, hydrogen peroxide (H2O2), and oxygen (O2) as oxidants are analyzed. Finally, the main factors influencing catalytic performance are summarized, and reasonable suggestions for catalyst design are proposed. This work provides scientific support for the advancement of the olefin epoxidation industry. 相似文献