Effects of high hydrostatic pressure on secondary structure and emulsifying behavior of sweet potato protein

In this study, secondary structures of sweet potato protein (SPP) after high hydrostatic pressure (HHP) treatment (200–600?MPa) were evaluated and emulsifying properties of emulsions with HHP-treated SPP solutions in different pH values (3, 6, and 9) were investigated. Circular dichroism analysis confirmed the modification of the SPP secondary structure. Surface hydrophobicity increased at pH 3 and decreased at 6 and 9. Emulsifying activity index at pH 6 increased with an increase in pressure, whereas emulsifying stability index increased at pH 6 and 9. Oil droplet sizes decreased, while volume frequency distribution of the smaller droplets increased at pH 3 and 6 with the HHP treatment. Emulsion viscosity increased at pH 6 and 9 and pseudo-plastic flow behaviors were not altered for all emulsions produced with HHP-treated SPP. These results suggested that HHP could modify the SPP structure for better emulsifying properties, which could increase the use of SPP emulsion in the food industry.     

电解质浓度和温度对活性炭电容性能的影响

采用循环伏安、交流阻抗和恒流充放电技术考察了电解质浓度和温度对活性炭电容性能的影响. 活性炭电容器在0.1、0.5、1.0和6.0 mol·L^-1 KOH溶液中性能测试结果表明: 活性炭在高浓度电解质中具有高电容和低内阻, 但电位窗口较窄; 电容和内阻与KOH浓度的对数成正比. 活性炭电容在不同温度(20、40、80 °C)的性能测试结果表明: 高温能够增加电容和降低内阻, 但是却加速了长期充放电过程中电容的衰减.     

激光自外差相干测量中分布反馈半导体激光器电流调谐非线性的补偿方法

半导体激光器的电流调谐非线性对自外差相干测量的精度影响很大.研究了分布反馈半导体(DFB) 激光器的电流调谐特性,据此提出一种数学模型补偿方法.利用已知光程差下的差拍频率,建立了动态调频 系数的数学模型.以此模型对DFB激光器的电流调谐非线性进行补偿,可以将差拍信号频率预测值的相对误差 减小约3%,提高了系统的测量精度.数学模型补偿方法简化了测量系统的结构,适用于高精度的电流调谐 激光在线测量系统.     

DFB激光二极管电流-温度调谐特性的解析模型

从DFB型激光二极管调谐机理出发,提出了电流-温度调谐特性的解析模型,通过实验测量结果辨识出模型参数,将模型应用于四个不同厂家的DFB型二极管激光器,得到激光器电流-温度调谐的解析模型;将模型预测值与实验测量值比较,相关系数均在0.9999以上.同时,利用CO₂气体的多个吸收谱线测量激光的波长,验证了解析模型的预测波长值,与HITRAN谱库中CO₂气体吸收波长的误差在3 pm内.解析模型能够精确预测激光器在快速调谐过程中的瞬态输出波长,其精度能够满足光谱分析、光 关键词： DFB激光二极管 调谐机理 解析模型 电流调谐和温度调谐     

锰酸镧和氧化钇稳定的氧化锆复合阴极的研究

用交流阻抗,强极化和电导测量等方法考察了一系列不同氧化钇稳定氧化锆(YSZ)含量的锶掺杂锰酸镧(LSM)复合阴极的电化学性能,发现随着掺入YSZ量的增大,阴极性能大幅度提高,当YSZ质量分数为40%时,电极性能最好,电化学极化电阻约为1.18Ω/cm².通过分析发现,YSZ的掺杂使电极反应过程的控制步骤发生了变化.同时发现,随着YSZ含量的增加,电极的接触电阻增大.以Pt为电流收集层和40%的YSZ+LSM的复合电极形成的二层电极可有效地消除接触电阻,进一步提高了复合电极的性能.在1223K极化电阻从1.18Ω/cm²下降到0.41Ω/cm².     

Synergy of Electron Transfer and Charge Transfer in the Control of Photodynamic Behavior of Coordination Polymers

Photodynamic behavior controlled by the synergy of electron transfer and charge transfer has been characterized in two regioisomeric pyridinium-bearing coordination polymers ( Cd-Bip and Cd-Bpy ) with the help of a smart charge-distribution-related isoreticular strategy. Because it is relatively weak, the charge-transfer interaction between adjacent 2D networks in Cd-Bip can be easily perturbed by photoinduced electron transfer under irradiation with 365 nm light, and then successfully drives the occurrence of photodynamic behavior. In contrast, lower energy 450 nm light is absorbed to a lesser extent, and can only induce a low degree of electron transfer, which is insufficient to actuate operation of this photodynamic behavior in Cd-Bip .     

Synthesis,structural characterization,and Hirshfeld surface analysis of three cocrystals based on flexible bis(benzimidazole) derivatives with aromatic carboxylic acids

Research on Chemical Intermediates - Based on 1,3-bis(2-methylbenzimidazole)propane (L1), 1,4-bis(2-methylbenzimidazole)butane (L2) and 1,4-bis(2-methylbenzimidazol-1-ylmethyl)benzene (L3) with...     

Long-Lived Multiple Charge Separation by Proton-Coupled Electron Transfer

Multiple charge separation has been successfully realized by a proton-coupled electron transfer reaction in an organic cocrystal. Benefiting from the adjustable electronic energy level of the electron donor and acceptor through thermal-induced proton migration, distinct optical absorption behaviors combined with color changes to blue or green are observed in these charge-separated states. It is of interest to note that such charge-separated states exhibit a longer lifetime of over a month as a result of the excellent coplanarity and π-π interaction of the electron acceptors. Moreover, the enhanced absorption toward longer wavelengths endows the charge-separated state with near-infrared (808 nm) photothermal conversion for imaging and bacterial inhibition, whereby the conversion performance can be controlled by the degree of proton migration.     

Using simulated Tianqin gravitational wave data and electromagnetic wave data to study the coincidence problem and Hubble tension problem

In this study, we used electromagnetic wave data (H0LiCOW, \begin{document}$ H(z) $\end{document}, SNe) and gravitational wave data (Tianqin) to constrain the interacting dark energy (IDE) model and investigate the Hubble tension and coincidence problems. By combining these four types of data (Tianqin+H0LiCOW+SNe+\begin{document}$ H(z) $\end{document}), we obtained the following parameter values with a confidence interval of \begin{document}$ 1\sigma $\end{document}: \begin{document}$ \Omega_m=0.36\pm0.18 $\end{document}, \begin{document}$ \omega_x=-1.29^{+0.61}_{-0.23} $\end{document}, \begin{document}$ \xi=3.15^{+0.36}_{-1.1} $\end{document}, and \begin{document}$H_0=70.04\pm $\end{document}\begin{document}$ 0.42~ {\rm kms}^{-1}{\rm Mpc}^{-1}$\end{document}. According to our results, the best value of \begin{document}$ H_0 $\end{document} shows that the Hubble tension problem can be alleviated to some extent. In addition, the center value of \begin{document}$ \xi+3\omega_x = -0.72^{+2.19}_{-1.19}(1\sigma) $\end{document} indicates that the coincidence problem is slightly alleviated. However, \begin{document}$ \xi+3\omega_x = 0 $\end{document} is still within the \begin{document}$ 1\sigma $\end{document} error range, which indicates that the ΛCDM model is still the model in best agreement with the observational data at present. Finally, we compared the constraint results of the electromagnetic and gravitational waves on the model parameters and found that the constraint effect of electromagnetic wave data on model parameters is better than that of simulated Tianqin gravitational wave data.     

活性炭表面担载氧化锰复合电极的电化学电容性能

通过在两种商品活性炭XC-72(比表面250m2·g-1)和YEC-8(比表面1726m·2g-1)电极表面涂刷Mn(NO3)2,并在200℃进行热分解得到表面担载氧化锰的复合材料电极.采用扫描电子显微镜(SEM)和X射线衍射(XRD)表征电极的形貌和氧化锰的晶体结构,采用循环伏安、恒流充放电和交流阻抗考察了不同电极的电化学电容性能.结果表明,Mn(NO3)2在200℃的热解产物是α-Mn2O3和α-Mn3O4的混合物.当C和MnOx的质量比为2∶1和9∶1时,XC-72/MnOx中氧化锰的比电容分别达到499和435F·g-1,YEC-8/MnOx中氧化锰的比电容分别达到554和606F·g-1,表明氧化锰的赝电容对电极比电容的贡献十分显著.