排序方式: 共有39条查询结果,搜索用时 46 毫秒
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J. Sarah Caygill Stuart D. Collyer Joanne L. Holmes Frank Davis Séamus P. J. Higson 《Electroanalysis》2013,25(11):2445-2452
We describe the use of cobalt phthalocyanine as a mediator to improve the sensitivity for the electrochemical detection of TNT. Commercial screen‐printed electrodes containing cobalt phthalocyanine were employed for determination of TNT. Improved sensitivities compared to screen‐printed carbon electrodes without phthalocyanine were observed, current response for cyclic voltammetric measurements at modified electrodes being at least double that of unmodified electrodes. A synergistic effect between oxygen and TNT reduction was also observed. Correlation between TNT concentrations and sensor output was observed between 0–200 µM TNT. Initial proof‐of‐concept experiments combining electrochemical determinations, with the use of an air‐sampling cyclone, are also reported. 相似文献
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We prove that if G is a discrete group that admits a metrically proper action on a finite-dimensional CAT(0) cube complex X, then G is weakly amenable. We do this by constructing uniformly bounded Hilbert space representations π
z
for which the quantities
z
ℓ
(g) are matrix coefficients. Here ℓ is a length function on G obtained from the combinatorial distance function on the complex X. 相似文献
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Adrian P Higson Yury E Tsvetkov Michael A.J Ferguson Andrei V Nikolaev 《Tetrahedron letters》1999,40(52):297-9284
The triglycosyl monophosphate 1, heptaglycosyl triphosphates 2 and 3, and octaglycosyl triphosphate 4, which are fragments of the phosphoglycan part of Leishmania major lipo- and proteo-phosphoglycans have been prepared using di- and tri-saccharide H-phosphonates for construction of the phosphodiester bridges. 相似文献
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Erik Guentner Nigel Higson Shmuel Weinberger 《Publications Mathématiques de L'IHéS》2005,101(1):243-268
Let K be a field. We show that every countable subgroup of GL(n,K) is uniformly embeddable in a Hilbert space. This implies that Novikov’s higher signature conjecture holds for these groups. We also show that every countable subgroup of GL(2,K) admits a proper, affine isometric action on a Hilbert space. This implies that the Baum-Connes conjecture holds for these groups. Finally, we show that every subgroup of GL(n,K) is exact, in the sense of C*-algebra theory. 相似文献
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Using the constructions of the preceding two papers, we construct a natural transformation (after inverting 2) from the Browder-Novikov-Sullivan-Wall
surgery exact sequence of a compact manifold to a certain exact sequence of C
*-algebra K-theory groups.
Mathematics Subject Classification (1991): 19J25, 19K99 相似文献
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We develop the theory of analytically controlled Poincaré complexes over C
*-algebras. We associate a signature in C
*-algebra K-theory to such a complex, and we show that it is invariant under bordism and homotopy.
The authors were supported in part by NSF Grant DMS-0100464. 相似文献
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Within this work we present a ‘proof of principle’ study for the use of scanning electrochemical microscopy (SECM) to detect and image biomolecular interactions in a label-free assay as a potential alternative to current fluorescence techniques. Screen-printed carbon electrodes were used as the substrate for the deposition of a dotted array, where the dots consist of biotinylated polyethyleneimine. These were then further derivatised, first with neutravidin and then with a biotinylated antibody to the protein neuron specific enolase (NSE). SECM using a ferrocene carboxylic acid mediator showed clear differences between the array and the surrounding unmodified carbon. Imaging of the arrays before and following exposure to various concentrations of the antigen showed clear evidence for specific binding of the NSE antigen to the antibody derivatised dots. Non-specific binding was quantified. Control experiments with other proteins showed only non-specific binding across the whole of the substrate, thereby confirming that specific binding does occur between the antibody and antigen at the surface of the dots. Binding of the antigen was accompanied by a measured increase in current response, which may be explained in terms of protein electrostatic interaction and hydrophobic interactions to the mediator, thereby increasing the localised mediator flux. A calibration curve was obtained between 500 fg mL−1 to 200 pg mL−1 NSE which demonstrated a logarithmic relationship between the current change upon binding and antigen concentration without the need for any labelling of the substrate. 相似文献
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The biocompatibility and substrate diffusion limiting properties for a range of diamond like carbon (DLC) coated microporous polycarbonate and DLC coated dialysis (haemodialysis) membranes have been studied. This characterisation builds upon previous findings where DLC coated membranes imparted enhanced enzyme electrode performance. In this study electrode linear ranges have been extended from 10 mM glucose for a 0.01 μm pore size membrane to 160 mM. These findings correlated with the duration of DLC deposition and associated reductions in permeability for glucose. Permeability coefficient ratios for both microporous and dialysis membranes were also found to be important with low glucose/O2 permeability ratios imparting extensions in glucose linear response range. DLC coated membranes employed within enzyme electrodes have also been shown to exhibit enhanced haemocompatibility as determined by both sensitivity change and surface deposition of blood components examined by scanning electron microscopy. Correlations are made between the reduced losses in sensor response to biofouling/ working electrode passivation processes, and extended linear ranges that DLC coated membranes may impart to enzyme electrode performance. Particular reference is made to the determination of glucose levels within whole blood. 相似文献