真空蒸馏预富集-电感耦合等离子体发射光谱法测定铂

建立了真空蒸馏预富集-电感耦合等离子体发射光谱法测定铅试样中微量铂的方法.在真空条件下,利用Pb和Pt在较高温度下蒸汽压的差别进行分离,富集后的铂溶解制成溶液后进行电感耦合等离子体发射光谱检测,实现了真空密闭回收铅.针对试样的特点,对真空蒸馏方法理论上的可行性进行研究.结果表明:在蒸馏温度为1250 K,真空度为30 Pa,蒸馏时间为3 h条件下,铂的富集分离效果最好,可富集至99.01%以上.线性范围为0.023～20 mg/L,检出限(3σ)为0.0069 mg/L,对样品测定的相对标准偏差为1.7%(n=6).用本方法对样品中加入的铂标准溶液进行了测定,回收率为99.8%～103.0%.本方法简便快速、无污染,已应用于废电路板贵金属冶余物料中铂的测定.     

Soliton structures in the (1+1)-dimensional Ginzburg–Landau equation with a parity-time-symmetric potential in ultrafast optics

In this paper, the(1+1)-dimensional variable-coefficient complex Ginzburg–Landau(CGL) equation with a paritytime(PT) symmetric potential U(x) is investigated. Although the CGL equations with a PT-symmetric potential are less reported analytically, the analytic solutions for the CGL equation are obtained with the bilinear method in this paper. Via the derived solutions, some soliton structures are presented with corresponding parameters, and the influences of them are analyzed and studied. The single-soliton structure is numerically verified, and its stability is analyzed against additive and multiplicative noises. In particular, we study the soliton dynamics under the impact of the PT-symmetric potential. Results show that the PT-symmetric potential plays an important role for obtaining soliton structures in ultrafast optics, and we can design fiber lasers and all-optical switches depending on the different amplitudes of soliton-like structures.