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Freeradicalbiologyandmedicinehavedemonstratedthatfreeradicaldirectlyrelatestothepathogenesisofvariousbiologicaldisorder,e.g.carcinogenesis,cardiovasculardiseases,radiationinducedbiologicaldamagesandaging[1],theseradicals,includingOH·,O·-2,etc.,canbeproducedb… 相似文献
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The oxidizing mechanism of podophyllotoxin and its derivatives by sodium persulfate has been studied by laser flash photolysis and pulse radiolysis. The formation and decay processes of transient species of podophyllotoxin and its derivatives have been observed, and a series of rate constants for the formation and decay of transient species have been determined. It has been found that there is a light (UV) sensitive group on the C-4 of podophyllotoxin and two light (UV) sensitive groups on the C-4 and C-4' of 4'-demethylepipodophyllotoxin. 相似文献
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