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1.
通过双醚化反应、氯甲基化反应以及在强碱性条件下进行的脱氯化氢反应制备聚(2-甲氧基-5-丁氧基)对苯乙炔(PMOBOPV)、聚(2-甲氧基-5-己氧基)对苯乙炔(PMOHOPV)、聚(2,5-二丁氧基)对苯乙炔(PDBOPV)和聚(2,5-二己氧基)对苯乙炔(PDHOPV)等四种可溶性聚对苯乙炔(PPV)衍生物,通过紫外-可见吸收光谱对产物分子结构进行表征.结果显示,PMOBOPV、PMOHOPV、PDBOPV和PDHOPV的共轭π电子发生π → π* 跃迁的吸收峰分别位于491 nm、495nm、504nm和510nm处,相应的光学禁带宽度分别为2.23eV、2.18eV、2.12eV和2.07eV.利用简并四波混频技术测量PPV衍生物的三阶非线性光学性能,探讨了分子结构对PPV衍生物三阶非线性极化率(χ(3))的影响.研究发现,激发波长为532 nm时,PMOBOPV、PMOHOPV、PDBOPV和PDHOPV的共振χ(3)值分别为3.45×10-10、5.13×10-10、7.15×10-10和9.61×10-10 esu;激发波长为1064 nm时,它们的非共振χ(3)值分别为1.09×10-11、1.42×10-11、1.62×10-11和2.14×10-11 esu. 相似文献
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聚芳香杂环甲烯的三阶非线性光学效应与时间分辨光克尔效应 总被引:6,自引:4,他引:2
合成了一系列聚芳香杂环甲烯,包括聚吡咯甲烯和聚噻吩甲烯.采用四波混频法研究材料的共振三阶非线性光学效应(λ=532nm),其共振二阶超分子极化率γ三阶非线性光学系数分别达到10-30esu和10-8esu.选择具有良好溶解性、成膜性的聚吡咯对二甲氨基苯甲烯(PPDMAB),采用飞秒时间分辨光克尔效应方法研究材料的非共振三阶非线性光学效应(λ=790nm).实验表明,翠绿亚胺碱溶液的光克尔信号仅表现一超快响应的成分,归功于π电子云扭转产生的非共振激发.PPDMAB的非共振二阶超分子极化率γ三阶非线性光学系数分别达到γ=5.78×10-32esu和χ(3)=1.26×10-10esu. 相似文献
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Study on third-order nonlinear optical properties of a soluble poly(p-phenylene vinylene) derivative
Recently, π-conjugated polymers with large π-electrondelocalization have received much attention because oftheir larger and ultra faster nonlinear optical (NLO)response due to the distortion of π-conjugated elec-tronic charge distribution along the main chain[1-3].Poly(p-phenylene vinylene) (PPV) and its derivativesare typical π-conjugated polymers that have been de-scribed in the literature for the possibility of using themin light-emitting device and large-area multicolor dis-play, whi… 相似文献
5.
We have employed phase-diffusion model to study the effects of laser field correlation on the Raman-enhanced nondegenerate four-wave mixing (RENFWM). The different roles of the field fluctuations have been pointed out. A time-delayed method has been proposed to suppress the thermal background. An enhancement of the ratio between the resonant and nonresonant RENFWM signal intensities was found as the time delay is increased when the laser has broadband linewidth. When the lasers have Gaussian line shape, we also present a second-order coherence function theory to elucidate the temporal asymmetry behavior of the RENFWM. 相似文献
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NONLINEAR EFFECTS OF THIRD-AND FIFTH-ORDER ON POLARIZATION BEATS IN A FOUR-LEVEL SYSTEM 总被引:1,自引:0,他引:1 下载免费PDF全文
We have employed second-order coherence function theory to study the nonlinear effects of third-and fifth-order on polarization beats in a four-level system (TPBFS and FPBFS). It is found that the different temporal behavior of the beat signal in TPBFS and FPBFS depends on the stochastic properties of the lasers and transverse relaxation rate of the transition. We have considered the cases that pump beams have either narrow band or broadband linewidth and found that for both cases a Doppler-free precision can be achieved in the measurement of the energy-level difference between two excited states which are dipolar forbidden from the ground state. We also discussed the spatiall modulation behavior of the beat signal. 相似文献
8.
Nanocomposites of
poly[(2-methoxy,5-octoxy)1,4-phenylenevinylene]-zinc selenide
(MOPPV-ZnSe) are synthesized by mixing the polymerization of 1,4-bis
(chloromethyl)-2-methoxy-5-octoxy-benzene in the presence of ZnSe
quantum dots. The resulting MOPPV-ZnSe nanocomposites possess a
well-defined interfacial contact, thus significantly promoting the
dispersion of ZnSe within the MOPPV matrix and facilitating the
electronic interaction between these two components. Raman and
UV--visible absorption spectra are influenced by the incorporation
of ZnSe nanocrystals. High-resolution transmission electron
microscopic and tapping-mode atomic force microscopic results show
clearly the evidence for phase-segregated networks of ZnSe
nanocrystals, which provide a large area of interface for charge
separation to occur. Steady-state spectra of MOPPV-ZnSe
nanocomposites are markedly quenched by the introduction of intimate
polymer/ZnSe junctions. Time-resolved photoluminescence
measurements show that the lifetime decays quickly, which further
confirms the occurrence of charge transfer in MOPPV-ZnSe
nanocomposites. 相似文献
9.
高能激光能量计校准方法研究 总被引:1,自引:3,他引:1
给出了一种绝对式高能激光能量计光电校准方法.该方法以大功率灯作为校准光源,通过测量灯两端的电压以及电流获得电能值,去掉灯所消耗的热能,得到灯所发出的光能.所设计平板能量计将大功率灯密封在高能激光能量计内,光能全部被能量计吸收.根据能量计输出值以及光能值便可实现能量计光电校准.结果表明,能量计光电校准不确定度约为1.5%. 相似文献
10.
The Raman-enhanced polarization beats (REPB) with phase-conjugation geometry in carbon disulfide are investigated using chaotic and phase-diffusion models. The overall accuracy of using REPB to measure the resonant frequency of Raman-active vibrational mode is determined by the relaxation rates of the Raman mode and the molecularreorientational grating. Different stochastic models of the laser field only affect the sixth- and fourth-order coherence function. The difference between the REPB and the fourth-order coherence on ultrafast modulation spectroscopy is discussed as well from a physical viewpoint. 相似文献