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基于二茂铁独特的分子结构及其作为新型液相色谱分离基质的潜质,制备了新型(4-环戊二烯基苯甲酸-铁-甲苯)六氟磷酸盐键合硅胶固定相,利用红外光谱、元素分析、热重分析等手段对其进行了表征。分别选取多环芳烃、萘胺位置异构体、硝基苯胺位置异构体、硝基咪唑类化合物和有机磷化合物溶质作为探针,对其色谱性能进行了评价。结果表明,该色谱固定相能提供 π-电子转移、 π-π 作用、偶极-偶极作用及与底物的静电相互作用等多种作用力,并探讨了可能的分离机理。 相似文献
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近年来,随着分布式光纤传感技术在各大基础设施健康监测领域的广泛应用,人们对能够实现毫米量级精准定位和监测技术的需求日益增长.本文提出了一种基于宽线宽混沌激光的高分辨率分布式光纤测温技术.实验通过改变光反馈混沌源的偏振匹配态和反馈强度等外部参数,产生了–3 dB线宽约为7.5 GHz的宽线宽混沌激光,并在300 m传感光纤实现了空间分辨率为7.05 mm的分布式温度测量.同时,为了抑制光源线宽增加造成的布里渊增益谱恶化,在泵浦路中引入了时间门控技术,其中经脉冲调制后的泵浦光峰值功率提高了约9.5 dB,同时脉冲调制使混沌互相关锁定于脉冲持续时间内,从而布里渊增益谱的信号背景噪声比由约2.28 dB提升为4.55 dB,最终实现了空间分辨率为3.12 mm的分布式温度测量. 相似文献
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We propose and experimentally demonstrate a novel Raman-based distributed fiber-optics temperature sensor(RDTS) for improving the temperature measurement accuracy and engineering applicability. The proposed method is based on double-ended demodulation with a reference temperature and dynamic dispersion difference compensation method, which can suppress the effect of local external physics perturbation and intermodal dispersion on temperature demodulation results. Moreover, the system can omit the pre-calibration process by using the reference temperature before the temperature measurement. The experimental results of dispersion compensation indicate that the temperature accuracy optimizes from 5.6°C to 1.2°C, and the temperature uncertainty decreases from 16.8°C to 2.4°C. Moreover, the double-ended configuration can automatically compensate the local external physics perturbation of the sensing fiber, which exhibits a distinctive improvement. 相似文献
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