全文获取类型
收费全文 | 6795篇 |
免费 | 812篇 |
国内免费 | 977篇 |
专业分类
化学 | 4269篇 |
晶体学 | 59篇 |
力学 | 665篇 |
综合类 | 33篇 |
数学 | 1571篇 |
物理学 | 1987篇 |
出版年
2024年 | 13篇 |
2023年 | 252篇 |
2022年 | 356篇 |
2021年 | 378篇 |
2020年 | 465篇 |
2019年 | 290篇 |
2018年 | 312篇 |
2017年 | 337篇 |
2016年 | 388篇 |
2015年 | 397篇 |
2014年 | 470篇 |
2013年 | 633篇 |
2012年 | 634篇 |
2011年 | 544篇 |
2010年 | 498篇 |
2009年 | 447篇 |
2008年 | 388篇 |
2007年 | 373篇 |
2006年 | 391篇 |
2005年 | 238篇 |
2004年 | 134篇 |
2003年 | 117篇 |
2002年 | 91篇 |
2001年 | 134篇 |
2000年 | 84篇 |
1999年 | 119篇 |
1998年 | 20篇 |
1997年 | 14篇 |
1996年 | 19篇 |
1995年 | 4篇 |
1994年 | 11篇 |
1993年 | 8篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1979年 | 1篇 |
1959年 | 1篇 |
1957年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有8584条查询结果,搜索用时 31 毫秒
1.
《中国化学快报》2022,33(10):4461-4477
In recent years, with the emergence of new pollutants, the effective treatment of wastewater has become very important. Persulfate-based advanced oxidation processes have been successfully applied to the treatment of wastewater, such as wastewater containing antibiotics, pharmaceuticals and personal care products, dyes, endocrine-disrupting chemicals, chlorinated organic pollutants, and phenolics, for the degradation of refractory organic contaminants. This paper summarizes the production of sulfate radicals, which can be generated by the activation of persulfate via conventional and emerging approaches. The existing problems of persulfate-based advanced oxidation processes were analyzed in detail, including residual sulfates, coexisting factors (coexisting inorganic anions and natural organic matter), and energy consumption. This paper proposes corresponding possible solutions to the problems mentioned above, and this paper could provide a reference for the application of persulfate-based advanced oxidation processes in actual wastewater treatment. 相似文献
2.
Hao Lu Xiaodong Wang Hang Wang Andong Zhang Xinming Zheng Na Yu Zheng Tang Xinjun Xu Yahui Liu Ya-Nan Chen Zhishan Bo 《中国科学:化学(英文版)》2022,65(3):594-601
Three nonfused ring electron acceptors (NFREAs) TTC6,TT-C8T and TT-TC8 were purposefully designed and synthesized.The molecular geometry can be adjusted by the steric hindrance of lateral substituents.According to the DFT calculations,from TTC6 to TT-C8T and TT-TC8,planarity of the molecular backbone is gradually improved,accompanying with the enhancing of intramolecular charge transfer effect.As for TT-TC8,the two phenyl substituents are almost perpendicular to the molecular backbone,which endues the acceptor with good solubility and suppresses it to form over-aggregation.Multidirectional regular molecular orientation and closer molecular stacking are formed in TT-TC8 film.As a result,TT-TC8 based devices afford the highest PCE of 13.13%,which is much higher than that of TTC6 (4.41%) and TT-C8T (10.42%) and among the highest PCE values based on NFREAs. 相似文献
3.
Tongyu Bi Yi Xu Xin Xu Bixi Tang Qing Yang Yi Zang Zhenyang Lin Jia Li Weibo Yang 《中国化学快报》2022,33(4):2015-2020
The development of innovative strategies and methods to provide natural product-like macrocycles not accessible by biosynthesis, but endowed with novel bioactivities and simplified structure, is highly desirable. Inspired by the key scaffolds of rapamycin and FR252921, herein, we report a Rh(III)-catalyzed C–H alkylation macrocyclization, which enables access to CF3-substituted macrolides. DFT calculations reveal that the chemoselectivity between C–H alkylation and olefination macrocyclization w... 相似文献
4.
5.
An adaptive tracking design strategy based on quantized state feedback is developed for uncertain nonholonomic mobile robots with unknown wheel slippage effects. All state variables and control torques are assumed to be quantized by the state and input quantizers, respectively, in a network control environment. Thus, the quantized state feedback information is only available for the tracking control design. An approximation-based adaptive controller using quantized states is recursively designed to ensure the robust adaptive tracking against unknown wheel slippage effects where the quantized-states-based adaptive mechanism is derived to compensate for unknown wheel slippage effects, system nonlinearities, and quantization errors. The boundedness of the quantization errors and estimated parameters in the closed-loop system is analyzed by presenting some theoretical lemmas. Based on these lemmas, we prove the uniform ultimate boundedness of closed-loop signals and the convergence of the trajectory tracking error in the presence of wheel slippage effects. Simulations verify the effectiveness of the resulting tracking scheme. 相似文献
6.
7.
《Journal of Saudi Chemical Society》2022,26(6):101573
In this study, vanadium nanoparticles (VNPs) were green synthesized using Foeniculum vulgare extract. VNPs were characterized using chemical analysis techniques including FT-IR, XRD, FE-SEM, TEM and EDS. The microscopy techniques revealed a spherical morphology for the particles with size less than 50 nm. According to XRD data V2O5 was confirmed for VNPs. Maybe significant anti-human acute leukemia potentials of the synthesized nanoparticles against common human acute leukemia cell lines are linked to their antioxidant activities. MTT assay was used on common acute leukemia cell lines i.e., 32D-FLT3-ITD, MOLT-3 and Jurkat, Clone E6-1 to survey the cytotoxicity and anti-acute leukemia effects of the synthesized nanoparticles. The synthesized nanoparticles had very low cell viability and high anti-acute leukemia activities dose-dependently against 32D-FLT3-ITD, MOLT-3 and Jurkat, Clone E6-1 cell lines without cytotoxicity on the normal cell line (HUVEC). To determine the antioxidant properties of the synthesized nanoparticles, the DPPH test was used in the presence of butylated hydroxytoluene as the positive control. The IC50 of VNPs were 25, 33 and 26 µg/mL against 32D-FLT3-ITD, MOLT-3 and Jurkat, Clone E6-1 cell lines, respectively. The synthesized nanoparticles inhibited half of the DPPH molecules in the concentration of 28 µg/mL. 相似文献
8.
Dengqi Xue Yani Liu Yilin Zheng Heling Niu Liying Dong Xiangshuo Ouyang Siyu Song Denggao Zhang Qianwei Ge Kewei Wang Liming Shao 《中国化学快报》2022,33(3):1643-1646
Three novel series of α-aminoamides derivatives were designed and synthesized based on ralfinamide,and their Nav1.7 inhibitory activities were evaluated using manual patch clamp electrophysiology. Active compounds inhibited Nav1.7 with half maximal inhibitory concentration(IC50) values ranging from2.9 μmol/L to 21.4 μmol/L. Among them, the most potent compound 19h exhibited about 12-fold potency better than ralfinamide. The investigation of their structure-activity relationship gives a strategy ... 相似文献
9.
10.
Chang Mingning Wang He Zheng Yonglei Li Ningning Chen Siheng Wan Yong Yuan Feng Shao Weiquan Xu Sheng 《Journal of Solid State Electrochemistry》2019,23(2):607-613
Journal of Solid State Electrochemistry - Li1.2Ni1/3Co1/3Mn1/3O2 was synthesized as a cathode material for lithium-ion batteries and coated with various amounts of CoAl2O4 (0–5 wt%)... 相似文献