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1.
Crystal engineering, as a burgeoning technology, has been widely used to construct metalloporphyrins biomimetic catalysts. Herein, a bimetallic metal-organic framework (MOF) was constructed by 4-(4-carboxyphenyl)-1,2,4-triazole ligand, Co2+ and Zr4+ metal ions by solvothermal reaction(named PFC-88). A N,N-chelation site was found between the two adjacent ligands in PFC-88, consequently a porphyrin-like structure was obtained through chelating Fe3+ in this site by post-modification, named PFC-88-Fe. The result of a single crystal X-ray technology verified that Fe ions were successfully metalated in the N,N-chelation site of PFC-88, which is assisted by the X-ray absorption near-edge structure(XANES) spectra. An o-phenylenediamine oxidation reaction was applied to assessing the catalytic activity of PFC-88-Fe, in which the absorbance increases of phenazine-2,3-diamine at λ=418 nm were recorded by absorption spectroscopy in kinetic mode, exhibiting the application potential as a biomimetic catalyst. 相似文献
2.
An adaptive tracking design strategy based on quantized state feedback is developed for uncertain nonholonomic mobile robots with unknown wheel slippage effects. All state variables and control torques are assumed to be quantized by the state and input quantizers, respectively, in a network control environment. Thus, the quantized state feedback information is only available for the tracking control design. An approximation-based adaptive controller using quantized states is recursively designed to ensure the robust adaptive tracking against unknown wheel slippage effects where the quantized-states-based adaptive mechanism is derived to compensate for unknown wheel slippage effects, system nonlinearities, and quantization errors. The boundedness of the quantization errors and estimated parameters in the closed-loop system is analyzed by presenting some theoretical lemmas. Based on these lemmas, we prove the uniform ultimate boundedness of closed-loop signals and the convergence of the trajectory tracking error in the presence of wheel slippage effects. Simulations verify the effectiveness of the resulting tracking scheme. 相似文献
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Using first principles density functional theory, we predict a monolayer B2Si structure with space group Pmm2 in the present work. This structure is confirmed to be dynamically stable. Based on the plane wave pseudopotential approach, the charge density, electron localization function, density of states, energy band, phonon property and thermal conductivity of Pmm2-B2Si are systematically studied. It is interesting that the sp2 hybridization and coordination bond of Si are found in Pmm2-B2Si, which is the most important factor for its structural stability. The density of states and energy band analysis reveals that Pmm2-B2Si is metallic because of the partial occupied Si 3pz and B 2pz states. Moreover, the acoustic-optical coupling is important for phonon transport in Pmm2-B2Si, and the contribution of optical modes to the lattice thermal conductivity along the [100] and [010] directions is 13% and 12%, respectively. This study gives a fundamental understanding of the structural, electronic and phonon properties in Pmm2-B2Si. 相似文献
5.
A novel organized multipulse pattern and its birth dynamics under strong optomechanical effect in microfiber-assisted ultrafast fiber laser are investigated in this work. The background pulses are observed to obviously exhibit selectively amplifying self-organized process of evolving into quasi-stable equidistant clusters. The radio frequency spectrum of the multipulse pattern displays a harmonic mode-locking-like behavior with a repetition rate of 2.0138 GHz, corresponding to the frequency of torsional-radial (TR2m) acoustic mode in microfiber. The results show the evidence of optomechanical effect in dominating the birth dynamics and pattern of multipulse. 相似文献
6.
In this work,(-201) β-Ga_2O_3 films are grown on GaN substrate by metal organic chemical vapor deposition(MOCVD). It is revealed that the β-Ga_2O_3 film grown on GaN possesses superior crystal quality, material homogeneity and surface morphology than the results of common heteroepitaxial β-Ga_2O_3 film based on sapphire substrate. Further, the relevance between the crystal quality of epitaxial β-Ga_2O_3 film and the β-Ga_2O_3/GaN interface behavior is investigated. Transmission electron microscopy result indicates that the interface atom refactoring phenomenon is beneficial to relieve the mismatch strain and improve the crystal quality of subsequent β-Ga_2O_3 film. Moreover, the energy band structure of β-Ga_2O_3/GaN heterostructure grown by MOCVD is investigated by X-ray photoelectron spectroscopy and a large conduction band offset of 0.89 eV is obtained. The results in this work not only convincingly demonstrate the advantages of β-Ga_2O_3 films grown on GaN substrate, but also show the great application potential of MOCVD β-Ga_2O_3/GaN heterostructures in microelectronic applications. 相似文献
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《中国化学快报》2020,31(8):2155-2158
Detection of trace-level hydrogen sulfide (H2S) gas is of great importance whether in industrial production or disease diagnosis. This research presents a novel H2S gas sensor based on integrated resonant dual-microcantilevers which can identify and detect trace-level H2S in real-time. The sensor consists of two integrated resonant microcantilever sensors with different functions. One cantilever sensor can identify H2S by outputting positive frequency shift signals, while the other cantilever sensor will detect H2S as a normally used cantilever sensor with negative frequency shifts. Combined the two cantilever sensors, the proposed gas sensor can distinguish H2S from a variety of common gases, and the detection limit to H2S of the sensor is as sensitive as below 1 ppb. 相似文献
9.
《Wave Motion》2015
We present the study of the wave motion in the Talbot interferometer with an additional element such as a lens for all related audiences. Our solutions are in the analytic form. A general principle of the Talbot effect, which is the optical near-field effect, is the Fresnel diffraction. The Fresnel integral is rather complicated. We therefore introduce an alternative method which is based on the wave propagation through the transmission functions of the grating and the lens. Our method has been proved by a simple experimental setup. 相似文献
10.
A nanoisland consists of center spin-5/2 and perimeter spin-3/2 atoms, which is described by transverse Ising model with single-ion anisotropy. Magnetic behaviors of the nanoisland are studied by the effective-field theory with correlations and the differential operator technique. The formulas of the magnetization and the phase transition of the system are given. The numerical results of the phase transition, the magnetization, the initial susceptibility and the internal energy have been discussed. Some interesting phenomena, such as a new reentrant, are found. Namely there are multitransition temperatures dependent on competition among the single-ion anisotropies, the transverse field and the interlayer coupling. These results can provide some guidance to structure design in the nanoislands. 相似文献