Luminescence from Tube-Arrest Bubbles in Pure Glycerin

Single transient cavitation bubble with luminescence has been generated in pure glycerin by using the ‘tube arrest‘ method. The analyses of high-speed photograph and light emission data suggest that the light emission would be a single bubble sonoluminescence. The luminescence pulse width is observed to vary from sub-nanosecond to about 30 ns. The width and intensity of luminescence pulses increases with the height of the liquid column height and decreases with the liquid temperature.     

飞秒激光直写生物凝胶模板原位合成纳米粒子

为了制备具有可控复杂形状和特定化学性质的聚合物微结构,提出了一种飞秒激光直写生物凝胶模板原位合成纳米粒子的方法。首先,采用飞秒激光直写技术加工带有COOH基团的复杂三维结构的生物凝胶模板,用氢氧化钠处理使COOH基团离子化为COO^-基团;然后,用金属盐溶液处理,使金属离子与COO^-基团螯合,形成纳米粒子结晶核。通过多次循环盐溶液处理步骤,控制模板中纳米粒子的粒径与含量。实验结果表明：所制备的生物凝胶模板具有亚100 nm分辨率和10 μm量级尺寸,纳米粒子含量高达9%。该法简单高效,具有很好的应用前景。     

飞秒超快光谱技术及其互补使用

超快光谱技术是研究物质激发态过程的重要手段,本文对飞秒时间分辨荧光技术和飞秒泵浦探测技术这两个重要的超快光谱技术进行了详细介绍,阐述了系统的原理、光路及数据处理方法,给出了不同的实现方法并比较了其优缺点。最后通过一个实例说明这两个技术的互补性,通过结合使用两个系统,能够对科学问题进行更全面可靠的研究。     

圆锥气泡发光的光谱性质

在改进的U型管装置中观察到一种圆锥气泡声致发光现象。声致发光产生的单个光脉冲的能量可达到约1.4 毫焦. 脉冲宽度约100 毫秒。发光光谱由连续光谱上叠加C2,CN,和CH的激发态光谱构成。这种圆锥气泡声致发光为单泡声致发光和多泡声致发光提供了一种联系。     

声致发光的流体动力学实验方法

介绍两种使用流体动力学实现声致发光的方法:刹管法和U管圆锥泡法.这两种方法的设备简单,操作方便,容易在普通物理实验中进行,所得结果和传统单泡声致发光有所不同.U管圆锥泡法创造了发光功率和单脉冲能量的新记录,并首次用条纹相机得到了时间分辨发射光谱.     

基于TiO_2纳米粒子薄膜的低阈值随机激光器的动力学研究

本文利用共轭聚合物(MEH-PPV)覆盖TiO_2纳米粒子薄膜制作随机激光器。随机TiO_2纳米粒子薄膜的激光辐射阈值比平面MEH-PPV薄膜的放大自发辐射阈值缩小了9倍。这是由于TiO_2纳米粒子诱导的多重散射造成的。进一步的飞秒荧光上转换实验表明,随机激光器中,光在增益介质里的停留时间有所增加,这直接证实了光在随机激光器结构中的多重散射引起光的传播路径增加。因此,这会促进更多的光发生辐射,从而降低随机激光器的阈值。     

Investigation of fluorescence resonance energy transfer ultrafast dynamics in electrostatically repulsed and attracted exciton-plasmon systems

Following the gradual maturation of synthetic techniques for nanomaterials,exciton-plasmon composites have become a research hot-spot due to their controllable energy transfer through electromagnetic fields on the nanoscale.However,most reports ignore fluorescence resonance energy transfer(FRET)under electrostatic repulsion conditions.In this study,the FRET process is investigated in both electrostatic attraction and electrostatic repulsion systems.By changing the Au:quantum dot ratio,local-field induced FRET can be observed with a lifetime of ns and a fast component of hundreds of ps.These results indicate that the intrinsic transfer process can only elucidated by considering both steady and transient state information.     

圆锥气泡声致发光光脉冲和光谱

对一种U形管圆锥气泡发光装置进行了改进，使其发光效果更好，利用光电倍增管和光谱仪 得到了水中空气圆锥气泡的发光脉冲和发光光谱图. 得到的发光脉冲在几百个ps和几个ns之 间不等；在近红外波长范围内观测到了水分子振动能级的特征谱，其连续谱发光强度随着波 长的增加而升高. 另外还得到了在水中加入NaCl溶液的气泡发光光谱图. 关键词： 声致发光 圆锥气泡 光脉冲 光谱     

Production of large size single transient cavitation bubbles with tube arrest method

Large size single transient cavitation bubbles of maximum diameter up to 3 cm with sonoluminescence have been generated in water by the ‘tube arrest' method. A simplified one-dimensional model of bubble growing and water column motion is proposed. The results of numerical simulation are compared with the experimental data of the bubble size and oscillation period as the key parameters.