二硫化钨纳米片制备及其钙钛矿太阳能电池空穴传输层应用

开发新型无机空穴传输层材料是钙钛矿电池实现商业应用的重要挑战之一。本文开展了二硫化钨纳米片制备及其钙钛矿太阳能电池空穴传输层应用研究。采用液相超声剥离法成功制备了WS 2纳米片,并将其引入钙钛矿太阳能电池中用作空穴传输层。结果表明,当WS 2纳米片溶液浓度为1 mg/mL时,制备的WS 2纳米片空穴传输层具有较合适的厚度,并且后续在其上生长的钙钛矿活性层成膜质量高、结晶性能好,电池取得6.3%的光电转换效率。结果证实WS 2纳米片可作为新型无机空穴传输层材料用于钙钛矿太阳能电池。     

四自由度非线性系统的随机分岔混沌特性研究

以四自由度迟滞非线性随机振动模型为研究对象,以速度和位移立方的模型来模拟振动系统的迟滞非线性力,并以Monte Carlo法模拟随机位移激励,对迟滞非线性随机系统的动力学特性进行分析.通过系统的Poincare截面、分岔图及最大Lyapunov指数分析了系统迟滞非线性力各参数对系统混沌状态的影响.研究表明,非线性刚度系数对振动系统混沌状态的影响较小,线性阻尼项和线性刚度项次之,而非线性阻尼项的影响最为明显.不仅证明了非线性振动系统随机混沌振动现象的存在,更重要的是可以为非线性振动系统参数的合理取值提供理论依据.     

Multi-photon upconversion luminescence of Er~(3+)-doped Y_2O_3 nanocrystals

Visible upconversion emission intensities are investigated in Er3＋-doped Y203 nanocrystals. We also find that the upconversion intensity varies nonlinearly with the excitation power with a threshold of 110 mW, which indicates that the green and red emissions would be photon avalanche upconversion when the excitation power exceeds the threshold.     

外延单片式激光二极管抽运被动调Q微激光器

基于液相外延工艺,实现了一种结构新颖的单片式被动调Q微片激光器。采用了在激光介质Nd3 ∶YAG表面直接液相外延生长一层具有饱和吸收特性的Cr4 ∶YAG膜的微谐振腔的结构,由于是同质外延生长过程,能够确保饱和吸收体与增益介质间(Nd3 ∶YAG/Cr4 ∶YAG)良好的界面特性。采用光纤耦合激光二极管,在激光二极管输出为1W的抽运条件下,实现了峰值功率近千瓦、稳定重复频率在4kHz以上、脉宽1.8ns、TEM00单横模式、波长1.064μm的调Q脉冲序列输出。在对新型单片式微激光器的性能报道的基础上,阐述了外延单片式结构及其相应工艺的潜在优势。     

Plasmonic microcavity formed by the Möbius strip

We propose a Möbius-strip-type plasmonic cavity with a silver Möbius strip sandwiched between dielectric layers. By brief theoretical and simulation analyses, we obtain that the Q factor of the cavity remains about 40 and the mode volume is ultrasmall (less than 1 μm³) which is more compact than that of the cylindric cavity. This Möbius-strip-type plasmonic cavity supporting the propagation of surface plasmon polaritons owns some unusual properties such as more effective volume and the spatial separation. More potential applications based on this cavity remain to be explored in future nanophotonics.     

基于氧化石墨烯空穴传输层的钙钛矿太阳能电池

采用溶液旋涂法在平面异质结型钙钛矿电池中引入氧化石墨烯(Graphene oxide,GO),制备了GO、GO∶(PEDOT:PSS)复合薄膜和GO/PEDOT∶PSS双层薄膜作为空穴传输层的电池,其光电转换效率分别为1.86%、7.35%、7.69%,基于PEDOT∶PSS空穴传输层的对照电池的效率为7.38%.主要原因是GO具有绝缘性,作为阳极界面层时,随着GO薄膜厚度增加,器件的串联电阻增大,从而降低了电池的短路电流和效率.为提高GO导电性,并改善其功函数,将GO氨化改性后与PEDOT:PSS组合构成双空穴传输层,所得电池取得了7.69%的较高效率,表明该方式是GO用于钙钛矿电池空穴传输层的有效途径.     

Sb掺杂Si_3N_4基Si量子点薄膜的制备与结构

基于多靶射频磁控溅射技术,结合快速光热退火后处理制备了Sb掺杂Si_3N_4基Si量子点(SiQDs)薄膜。采用透射电镜、掠入射X射线衍射、拉曼光谱和光致发光光谱等手段对薄膜的微结构和发光特性进行了研究,分析了Sb掺杂对Si-QDs薄膜的微结构和发光特性的影响规律.结果表明,Sb掺杂表现出明显的诱导晶化作用.掺杂的Sb有助于Si原子在Si_3N_4基质中的扩散并形成Si-QDs.随着Sb掺杂量的增加,Si-QDs的尺寸逐渐增大,薄膜的结晶率X_c有效提高,其PL谱峰随之增强,谱峰的半高峰宽逐渐变窄;由于Si-QDs尺寸的增加还导致PL发光谱峰位产生红移.     

Intracavity power addition with a close-ended composite four-mirror cavity

We present a novel four-mirror cavity with two active gains to combine power intracavity and also give a detailed theoretical analysis of the combined gain. By using the effective field method, the four-mirror cavity with two gain media can be regarded as a linear resonator with one effective combined gain (ECG), and we procure a theoretical model of the ECG and deduce its exact analytical expression. When the two branch gains are close to each other, the combined gain can be reduced to their product, and the simplified presentation of ECG has been demonstrated. The combined output power which directly reflects the small signal ECG of the four-mirror cavity is studied experimentally, and the results are in good agreement with the theoretical ones.