全文获取类型
收费全文 | 139篇 |
免费 | 35篇 |
国内免费 | 17篇 |
专业分类
化学 | 30篇 |
晶体学 | 7篇 |
力学 | 19篇 |
综合类 | 2篇 |
数学 | 75篇 |
物理学 | 58篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 5篇 |
2019年 | 1篇 |
2018年 | 3篇 |
2017年 | 6篇 |
2016年 | 7篇 |
2015年 | 5篇 |
2014年 | 5篇 |
2013年 | 13篇 |
2012年 | 9篇 |
2011年 | 5篇 |
2010年 | 6篇 |
2009年 | 7篇 |
2008年 | 13篇 |
2007年 | 9篇 |
2006年 | 9篇 |
2005年 | 8篇 |
2004年 | 9篇 |
2003年 | 11篇 |
2002年 | 5篇 |
2001年 | 5篇 |
2000年 | 9篇 |
1999年 | 4篇 |
1998年 | 3篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有191条查询结果,搜索用时 31 毫秒
1.
在地球中传播的地震波主要有体波和表面波,而表面波中Rayleigh波对建筑物造成的破坏最为强烈。针对Rayleigh波的振动控制,提出一种田字形超材料结构。相比于传统的地震超材料,这种超材料屏障是由外部口字形框体内部嵌套十字形柱体组成,形成4个可填充区域,其外部框体采用部分埋入的方式,具有高强度、强稳定性、填充方式灵活的特点。应用有限元法计算了田字形超材料的能带结构和传输特性,并通过分析带隙边界处模态振型可知,带隙的打开是由于柱体的局域共振。结合带隙机理可知,柱体结构中土壤填充量不同可改变柱体的质量,形成不同的谐振频率,产生甚低频带隙。为进一步拓宽带隙,设计研究了正、负梯度的质量填充方式,均可得到3.3~13.1 Hz甚低频宽带隙,在谐振频率范围内两者的隔震方式分别为Rayleigh波彩虹捕获和Rayleigh波到体波的转化。最后,采用EI-Centro地震波对填充屏障进行了时程验证,加速度最大幅值衰减超过80%,为地震超材料在减震隔震方面应用提供了新的设计思路和方法。 相似文献
2.
目的 探讨早期干预对极低出生体重早产儿智能发育的影响,为极低出生体重早产儿的早期干预提供依据。方法 239 例极低出生体重早产儿为早产随访组,采用鲍秀兰早期教育资料制定的干预计划,进行系统干预,并与326 例失访的早产儿童以及与随访组相似的326 例正常儿童进行对照分析。采用Gesell 儿童发育量表等标准化工具进行发育评估。结果 早产随访组Gesell 儿童发育量表5 项均分、总发育商(developmental quotient,DQ)总分与早产失访组相比差异均有统计学差异(均P<0.05)。结论 早期干预能显著促进极低出生体重早产儿的智能发育,提高患儿的生活质量。 相似文献
3.
On the reactivity of naphthalene and biphenyl dianions: tying up loose ends concerning an SN2‐ET dichotomy in alkylation reactions 下载免费PDF全文
Inmaculada Blasco Henoc Pérez Albert Guijarro 《Journal of Physical Organic Chemistry》2015,28(6):388-395
Naphthalene and biphenyl dianions are interesting compounds that can be obtained by double reduction of the corresponding arenes in solution with certain alkali metals. These dianions are highly reactive and rather elusive species with very high laying and highly delocalized electrons. They share many aspects of the reactivity of the alkali metal they originated from and consequently behave primarily as strong electron transfer (ET) reagents. We report here kinetic evidence for a different type of reactivity in their alkylation reactions with alkyl fluorides. By using cyclopropylmethyl fluoride (c‐C3H5CH2F) as a very fast radical probe, we were able to settle that this alkylation does not involve the classical electron transfer reaction followed by radical coupling between diffusing radicals, but supports the alternative SN2 concerted mechanism, discerning thus this mechanistic SN2‐ET dichotomy. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
4.
Analytic steady-state results for FENE-P model macromolecules, in the nearly coiled-up and nearly stretched state respectively, in general two-dimensional flow fields are derived. These results are utilized in the flow through a sudden planar contraction. Special emphasis is devoted to the structure tensor R R, which furnishes, among other things, the mean square extension and the average orientation of the macromolecules. 相似文献
5.
The paper describes the validation of a newly developed very LES (VLES) method for the simulation of turbulent separated flow. The new VLES method is a unified simulation approach that can change seamlessly from Reynolds‐averaged Navier–Stokes to DNS depending on the numerical resolution. Four complex test cases are selected to validate the performance of the new method, that is, the flow past a square cylinder at Re = 3000 confined in a channel (with a blockage ratio of 20%), the turbulent flow over a circular cylinder at Re = 3900 as well as Re = 140,000, and a turbulent backward‐facing step flow with a thick incoming boundary layer at Re = 40,000. The simulation results are compared with available experimental, LES, and detached eddy simulation‐type results. The new VLES model performs well overall, and the predictions are satisfactory compared with previous experimental and numerical results. It is observed that the new VLES method is quite efficient for the turbulent flow simulations; that is, good predictions can be obtained using a quite coarse mesh compared with the previous LES method. Discussions of the implementation of the present VLES modeling are also conducted on the basis of the simulations of turbulent channel flow up to high Reynolds number of Reτ = 4000. The efficiency of the present VLES modeling is also observed in the channel flow simulation. From a practical point of view, this new method has considerable potential for more complex turbulent flow simulations at relative high Reynolds numbers. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
6.
7.
Asymptotic large- and short-time behavior of solutions of the linear dispersion equation μt = Uxxx in IR× IR+, and its (2k+l)th-order extensions are studied. Such a refined scattering is based on a "Hermitian" spectral theory for a pair {B,B*} of non self-adjoint rescaled operators 相似文献
8.
《中国物理 B》2021,30(9):95204-095204
The discharge characteristics of capacitively coupled argon plasmas driven by very high frequency discharge are studied. The mean electron temperature and electron density are calculated by using the Ar spectral lines at different values of power(20 W–70 W) and four different frequencies(13.56 MHz, 40.68 MHz, 94.92 MHz, and 100 MHz). The mean electron temperature decreases with the increase of power at a fixed frequency. The mean electron temperature varies nonlinearly with frequency increasing at constant power. At 40.68 MHz, the mean electron temperature is the largest. The electron density increases with the increase of power at a fixed frequency. In the cases of driving frequencies of 94.92 MHz and 100 MHz, the obtained electron temperatures are almost the same, so are the electron densities. Particle-in-cell/MonteCarlo collision(PIC/MCC) method developed within the Vsim 8.0 simulation package is used to simulate the electron density, the potential distribution, and the electron energy probability function(EEPF) under the experimental condition.The sheath width increases with the power increasing. The EEPF of 13.56 MHz and 40.68 MHz are both bi-Maxwellian with a large population of low-energy electrons. The EEPF of 94.92 MHz and 100 MHz are almost the same and both are nearly Maxwellian. 相似文献
9.
为提高微晶硅薄膜的纵向结晶性能, 在甚高频等离子体增强化学气相沉积技术的基础上, 采用过渡参数缓变和两步法相结合的方法在普通玻璃衬底上高速沉积薄膜. 当功率密度为2.1 W/cm2, 硅烷浓度在6%和9.6%之间变化时, 从薄膜方向和玻璃方向测算的Raman晶化率的差异维持在2%以内. 硅烷浓度为9.6%时, 薄膜沉积速率可达3.43 nm/s, 从薄膜方向和玻璃方向测算的Raman晶化率分别为50%和48%, 差异的相对值仅为4.0%. 合理控制过渡阶段的参数变化, 可使两个方向的Raman晶化率差值下降到一个百分点. 表明采用新方法制备薄膜, 不仅可以抑制非晶孵化层的形成, 改善微晶硅薄膜的纵向结构, 还为制备优质薄膜提供了较宽的参数变化空间.
关键词:
微晶硅薄膜
非晶孵化层
高速沉积
甚高频等离子体增强化学气相沉积 相似文献
10.