Wacker Oxidation of Methylenecyclobutanes: Scope and Selectivity in an Unusual Setting

Methylenecyclobutanes are found to undergo Wacker oxidation via a semi-pinacol-type rearrangement. Key to a successful process is the use of tert-butyl nitrite as oxidant, which not only enables efficient catalyst turn-over but also ensures high Markovnikov-selectivity under mild conditions. Thus, cyclopentanones (26 examples) can be accessed in an overall good yield and excellent selectivity (up to 97 % yield, generally >99 : 1 ketone:aldehyde ratio). Stereochemical analysis of the reaction sequence reveals migration aptitudes in line with related 1,2-shifts. By introducing a pyox ligand to palladium, prochiral methylenecyclobutanes can be desymmetrized, thus realizing the first enantioselective Wacker oxidation.     

On the dynamics of rings rotating with variable spin speed

This work investigates nonlinear dynamic response of circular rings rotating with spin speed which involves small fluctuations from a constant average value. First, Hamilton's principle is applied and the equations of motion are expressed in terms of a single time coordinate, representing the amplitude of an in-plane bending mode. For nonresonant excitation or for slowly rotating rings, a complete analysis is presented by employing phase plane methodologies. For rapidly rotating rings, periodic spin speed variations give rise to terms leading to parametric excitation. In this case, the vibrations that occur under principal parametric resonance are analyzed by applying the method of multiple scales. The resulting modulation equations possess combinations of trivial and nontrivial constant steady state solutions. The existence and stability properties of these motions are first analyzed in detail. Also, analysis of the undamped slow-flow equations provides a global picture for the possible motions of the ring. In all cases, the analytical predictions are verified and complemented by numerical results. In addition to periodic response, these results reveal the existence of unbounded as well as transient chaotic response of the rotating ring.     

Large amplitude free flexural vibration of rings using finite element approach

Here, the large amplitude free flexural vibrations of isotropic/laminated orthotropic rings are investigated, using a shear flexible curved beam element based on field consistency principle. A laminated refined beam theory is introduced for developing the element, which satisfies the interface transverse shear stress and displacement continuity, and has a vanishing shear stress on the inner and outer surfaces of the beam. The formulation includes in-plane and rotary inertia effects, and the non-linearity due to the finite deformation of the ring. The governing equations obtained using Lagrange's equations of motion are solved through the direct integration technique. Amplitude-frequency relationships evaluated from the dynamic response history are examined. Detailed numerical results are presented considering various parameters such as radius-to-thickness ratio, circumferential wave number and ovality for isotropic and laminated orthotropic rings. The nature and degree of the participation of various modes in non-linear asymmetric vibration of oval ring brought out through the present study are useful for accurate modelling of the closed non-circular structures.     

关于强Armendariz环和强拟Armendariz环

提出了强拟Armendariz环的概念,给出了强Armendariz环和强拟Armendariz环上的一些结果.     

On the notion of Cohen–Macaulayness for non-Noetherian rings

There exist many characterizations of Noetherian Cohen–Macaulay rings in the literature. These characterizations do not remain equivalent if we drop the Noetherian assumption. The aim of this paper is to provide some comparisons between some of these characterizations in non-Noetherian case. Toward solving a conjecture posed by Glaz, we give a generalization of the Hochster–Eagon result on Cohen–Macaulayness of invariant rings, in the context of non-Noetherian rings.     

A purely algebraic characterization of the hyperreal numbers

The hyperreal numbers of nonstandard analysis are characterized in purely algebraic terms as homomorphic images of a suitable class of rings of functions.

     

关于绝对半素环和绝对半素根

本文了绝对半素环的概念，研究了绝对半素与与半素环及素环之间的关系，讨论了由全体绝对半素环类决定的上根－－绝对半半素根及其性质。     

On exchange rings with primitive factor rings artinian

Abstract

In this paper we introduce generalized ideal-stable regular rings. It is shown that if a regular ring R is a generalized I-stable ring, then every square matrix over I is the product of an idempotent matrix and an generalized invertible matrix and admits a diagonal reduction by some generalized invertible matrices.     

Essential Ideals in Rings of Measurable Functions

In this article, we study essential ideals, socle, and some related ideals of rings of real valued measurable functions. We also study the Goldie dimension of rings of measurable functions.     

STABILITY OF CERTAIN RINGS OF HIGHEST WEIGHT VECTORS

51. IntroductionLet Cm'" be the space of complex m x n matrices, P(Cm)") be the algebra of complexpolynomials on Cd'~. Let GLm(C) x GL.(C) act on P(Cm,") as the following:(gi, gZ)f(x) ~ f(g,'xg,),where x E Cat", (gi, g2) E GLm x GL., f E P(Cm'"). This action induces an action of thesubgroup Of x GL. on P(Cm)") by restriction.Let G be a complex reductive algebraic group, (V, p) be a rational representation of G.Let B = TU be a Borel subgroup of G, where T is a majximal torns of …