Y2O3掺杂WO3光催化剂的制备及其性能

采用浸渍法合成了Y2O3 -WO3光催化剂,通过XRD和UV-Vis DRS测试手段对其进行了表征.以对苯二甲酸为探针分子,结合化学荧光技术研究了Y2O3 -WO3表面羟基自由基的生成.以溴百里香酚蓝(BTB)催化降解实验评价了其光催化活性.结果表明:与纯WO3相比,1.2％ Y2O3-WO3样品的吸收带边发生明显红移、在200～800 nm 区域有更强的光吸收.Y2O3-WO3样品的紫外和可见光催化活性随Y2O3含量增加先增加,当Y2O3含量为1.2％时分别达到最大值,然后随Y2O3含量的进一步增加而减小.与纯WO3相比,1.2％ Y2O3-WO3样品明显具有更高的紫外和可见光催化活性以及更大的羟基自由基生成速率.     

The homogeneous dirichlet problem for quasilinear anisotropic degenerate parabolic-hyperbolic equation with L initial value

The aim of this paper is to prove the well-posedness (existence and uniqueness) of the L^p entropy solution to the homogeneous Dirichlet problems for the anisotropic degenerate parabolic-hyperbolic equations with L^p initial value. We use the device of doubling variables and some technical analysis to prove the uniqueness result. Moreover we can prove that the L^p entropy solution can be obtained as the limit of solutions of the corresponding regularized equations of nondegenerate parabolic type.     

关于信用期内含缺陷产品EOQ模型

考虑到在实际中供应链上游供应商提供给下游零售商的信用支付期通常为一个订货周期,建立了缺陷率服从一定分布的缺陷产品在信用支付策略下的最优订货批量模型.模型中允许缺货发生并且以最大期望利润为目标函数,通过分析得到模型最优解.最后给出仿真实验,并且分析了模型参数变化对最优解的影响.     

高效液相色谱法测定肉制品中甘草抗氧化物的含量

建立了测定肉制品中甘草抗氧化物含量的方法。样品经流动相提取，采用C．8色谱柱分离，以甲醇-0．2mol／L乙酸铵-冰乙酸（体积比70：29：1）为流动相，流速为1．0mL／min，波长为250nm，以保留时间进行定性，峰面积进行定量。甘草酸在1．0-80．0μg／mL范围内线性关系良好，回归方程为y=8．55×10^-5x-0．599（r=0．9997），检出限为1．0mg／kg，定量限为3．0mg／kg，加标回收率为95．7％-103．4％，测定结果的相对标准偏差为1．57％-3．53％（n=6）。该方法适用于检验机构日常检验中大批量肉制品中甘草抗氧化物含量的测定。     

高效液相色谱-串联质谱法测定山茶油中黄曲霉毒素B1

建立了山茶油中黄曲霉毒素B1含量的高效液相色谱-串联质谱分析方法。通过对前处理方法的优化,选择了甲醇和水作为山茶油中黄曲霉毒素B1的提取溶剂,经免疫亲和柱富集浓缩后,采用高效液相色谱-串联质谱进行分析,经C18色谱柱分离,在电喷雾离子化正离子模式(ESI+)及多反应监测模式(MRM)下进行测定,基质匹配标准溶液外标法定量。在优化条件下,该方法线性范围为0.4～6.4μg/L,相关系数r2>0.998,最低检出限为0.026μg/kg,在添加水平为0.008,0.016和0.032μg时,方法回收率在85.9%～93.8%之间;相对标准偏差为1.8%～5.0%。方法可满足山茶油中黄曲霉毒素B1的检测要求。     

Complete noncompact manifolds with harmonic curvature

Let (M ⁿ , g) be an n-dimensional complete noncompact Riemannian manifold with harmonic curvature and positive Sobolev constant. In this paper, by employing an elliptic estimation method, we show that (M ⁿ , g) is a space form if it has sufficiently small L ^n/2-norms of trace-free curvature tensor and nonnegative scalar curvature. Moreover, we get a gap theorem for (M ⁿ , g) with positive scalar curvature.     

A New Metal-organic Framework Constructed from Flexible Polycarboxylate Acid and Rigid Imidazole-based Ligands

A new complex, [Ni3(L)2(BTA)2]·2H2O (1, L=1,4-di(1H-imidazol-4-yl)benzene, H3BTA=benzene-1,3,5-triacetic acid), has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis, TG and PXRD. The complex crystallizes in monoclinic, space group P1 with a=9.0303(12), b=10.0796(13), c=12.7966(17) , α=99.268(2), β=94.490(2), γ=103.722(3)o, V=1108.5(3) 3 , Z=2, C48H38N8O14Ni3 , Mr=1126.99, Dc=1.688 g/cm3 , μ=1.344 mm-1 , S=1.001, F(000)=578, the final R=0.0389 and wR=0.0895 for 3083 observed reflections (I > 2σ(I)). In the title complex, the flexible BTA3- ligands utilize oxygen atoms of carboxylate groups to coordinate with Ni(II) ions to form two-dimensional double-layer networks which are further pillared into a three-dimension framework via the rigid ditopic ligand L. Topological analysis revealed that complex 1 is a typical (3,8)-connected tfz-d 3D network based on the trinuclear [Ni3(CO2)6N4] subunits.     

二层信用策略下部分延期付款的库存模型

当前二层信用期相关文献考虑的都是零售商提供给其顾客相同的信用期,但现实中零售商往往会根据物品的种类不同提供给顾客不同的信用期.为研究此问题,建立了优化供货周期使零售商平均相关成本最小的库存模型,证明了最优供货周期的存在性,并给出实例加以说明.     

关于一类择优增长系统的度分布的注记

本文研究文[1]中提出的一类择优增长系统,说明文[1]中利用主方程法求解系统的平均度分布及稳态度分布是值得商榷的,然后通过考虑系统中空团体的存在的可能性,对系统进行修正,并证明空团体存在的必要性。     

Synthesis, Crystal Structure and Biological Activity of a Planar Copper Complex Derived from S-benzyldithiocarbazate

A planar transition metal complex Cu(L)2 (L = (E)-benzyl-2-(4-nitrobenzylidene)-hydrazinecarbodithioate) has been prepared and determined by X-ray single-crystal diffraction. The crystal belongs to the monoclinic system,space group P21/c with a = 6.7101(11),b = 16.952(3),c = 13.962(3) ,β = 92.458(4)°,V = 1586.7(5) 3,Z = 4,Mr = 724.33,Dc = 1.516 g·m-3,μ = 0.998 mm-1,F(000) = 742,S = 1.021,R = 0.0634 and wR = 0.1077 for 813 observed reflections with Ⅰ> 2σ(Ⅰ) and 205 parameters. In the molecular structure of the title complex,the copper atom exhibits a slightly distorted square-planar geometry in which the basal plane is defined by two N and two S atoms from two bidentate ligands. The complex was evaluated for its antitumor activity against two kinds of cell lines (MKN45 and HepG2) by MTT method. The preliminary bioassay indicates that the complex exhibits weak antitumor activity.