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1.
Recyclable carbon fiber‐reinforced plastics (CFRP) containing degradable acetal linkages: Synthesis,properties, and chemical recycling 下载免费PDF全文
Ayaka Yamaguchi Tamotsu Hashimoto Yoshinori Kakichi Michio Urushisaki Toshikazu Sakaguchi Kazumasa Kawabe Keiichi Kondo Hirohumi Iyo 《Journal of polymer science. Part A, Polymer chemistry》2015,53(8):1052-1059
Two epoxy resins containing degradable acetal linkages were synthesized by the reaction of cresol novolak‐type phenolic resin (CN) with vinyl ethers containing a glycidyl group [cyclohexane dimethanol vinyl glycidyl ether (CHDMVG) and 4‐vinyloxybutyl glycidyl ether (VBGE). Carbon fiber‐reinforced plastics (CFRPs) were prepared by heating laminated prepreg sheets with CN‐CHDMVG resin (derived from CN and CHDMVG) and CN‐VBGE resin (derived from CN and VBGE), in which carbon fibers are impregnated with epoxy resins containing curing agents [dicyandiamide (DICY)] and curing accelerator [3‐(3,4‐dichlorophenyl)‐1,1‐dimethylurea (DCMU)]. CN‐CHDMVG‐based CFRPs and CN‐VBGE‐based CFRPs exhibited almost the same tensile strength as the conventional bisphenol‐A‐based CFRPs. CN‐CHDMVG‐based CFRPs and CN‐VBGE‐based CFRPs underwent smooth breakdown with the treatment of hydrochloric acid in tetrahydrofuran at room temperature for 24 h to regenerate strands of carbon fibers. The surface conditions of the recovered carbon fibers had little changes during degradation and recovery processes on the basis of scanning electron microscopy (SEM) and X‐ray photoelectron spectroscopy (XPS). The recovered carbon fibers exhibited almost the same tensile strength as virgin carbon fibers and hence would be reused for the production of CFRPs. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1052–1059 相似文献
2.
The National Natural Science Foundation of China (NSFC) is a vital government agency supporting basic research and people to create knowledge and meet major national needs, where a rigorous and objective merit-based peer review mechanism is the key to funding the most promising research proposals. This invited comment overviews some recent attempts aimed at bettering the academic evaluation environment at the Department of Chemical Science in 2019, through measures such as grouped panel committee meetings, standardized panel committee meeting procedures, and review process refinement to improve the project review at panel committee meeting levels. 相似文献
3.
多属性决策时因掌握的信息有限,加之问题本身的复杂性、不确定性以及人类思维的模糊性,其属性的精确值往往难以获取,常用区间数形式表示针对多属性决策中各指标区间数不能直接进行大小比较的问题,提出一种基于集对分析联系数的区间数型多属性决策投影模型.模型用备择方案在理想方案上的投影进行集结,根据区间数的误差分布形式,沟通区间数与联系数的关系,根据a+bi型联系数大小比较法则,综合评价方案优劣.以某大厦基坑支护拟用的4种方案优化选择为例,说明方法的应用与模糊优化理论模型和灰色物元分析优化模型进行了对比,得到的结果一致. 相似文献
4.
Samsul Rizal N. I. Saharudin N. G. Olaiya H. P. S. Abdul Khalil M. K. Mohamad Haafiz Ikramullah Ikramullah Umar Muksin Funmilayo G. Olaiya C. K. Abdullah Esam Bashir Yahya 《Molecules (Basel, Switzerland)》2021,26(7)
The degradation and mechanical properties of potential polymeric materials used for green manufacturing are significant determinants. In this study, cellulose nanofibre was prepared from Schizostachyum brachycladum bamboo and used as reinforcement in the PLA/chitosan matrix using melt extrusion and compression moulding method. The cellulose nanofibre(CNF) was isolated using supercritical carbon dioxide and high-pressure homogenisation. The isolated CNF was characterised with transmission electron microscopy (TEM), FT-IR, zeta potential and particle size analysis. The mechanical, physical, and degradation properties of the resulting biocomposite were studied with moisture content, density, thickness swelling, tensile, flexural, scanning electron microscopy, thermogravimetry, and biodegradability analysis. The TEM, FT-IR, and particle size results showed successful isolation of cellulose nanofibre using this method. The result showed that the physical, mechanical, and degradation properties of PLA/chitosan/CNF biocomposite were significantly enhanced with cellulose nanofibre. The density, thickness swelling, and moisture content increased with the addition of CNF. Also, tensile strength and modulus; flexural strength and modulus increased; while the elongation reduced. The carbon residue from the thermal degradation and the glass transition temperature of the PLA/chitosan/CNF biocomposite was observed to increase with the addition of CNF. The result showed that the biocomposite has potential for green and sustainable industrial application. 相似文献
5.
通过对高性能 (AS系列 )固化剂与水泥的对比试验 ,研究其在天津软弱地基加固中适用性和优越性 ,并得出一套实用的固化剂加固软土地基的施工设计参数 相似文献
6.
In this article, both thermal buckling and post-buckling of pinned–fixed beams resting on an elastic foundation are investigated. Based on the accurate geometrically non-linear theory for Euler–Bernoulli beams, considering both linear and non-linear elastic foundation effects, governing equations for large static deformations of the beam subjected to uniform temperature rise are derived. Due to the large deformation of the beam, the constraint forces of elastic foundation in both longitudinal and transverse directions are taken into account. The boundary value problem for the non-linear ordinary differential equations is solved effectively by using the shooting method. Characteristic curves of critical buckling temperature versus elastic foundation stiffness parameter corresponding to the first, the second, and the third buckling mode shapes are plotted. From the numerical results it can be found that the buckling load-elastic foundation stiffness curves have no intersection when the value of linear foundation stiffness parameter is less than 3000, which is different from the behaviors of symmetrically supported (pinned–pinned and fixed–fixed) beams. As we expect that the non-linear foundation stiffness parameter has no sharp influence on the critical buckling temperature and it has a slight effect on the post-buckling temperature compared with the linear one. 相似文献
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8.
圆形截面是工程中常使用的截面形式之一,但圆形截面的配筋计算较为困难,存在双重非线性(材料和截面宽度变化的非线性),《混凝土结构设计规范》给出了计算均匀配筋的超越方程组,且须迭代求解,无法手算.另外,一些圆形截面构件(如桥墩、桩基的预制桩和灌注桩等)的截面尺寸大,构件长,钢筋用量大,若采用均匀布置的配筋方式,中性轴附近的钢筋应力小,强度利用率低,经济性差.若采用非均匀配筋,在远离中性轴的外围区域布置受力钢筋,可大幅节省钢筋用量,且能充分利用钢筋及混凝土的强度.为此本文通过应变计算应力,再计算出内力的方法推导计算圆形截面配筋的公式,并将计算结果绘制成了能计算配筋的无量纲诺模图,由此可快速手算配筋,该图通用性强,可用于任意直径大小及C50以下的混凝土强度等级,是一能快速计算配筋的实用工具. 相似文献
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10.
弹性地基梁振动特性的近似分析方法 总被引:4,自引:1,他引:4
文中介绍了用模态摄动法分析复杂情况下弹性地基梁动力特性的近似方法。这一方法中可考虑纵向钢筋以及变地基弹性系数对弹性地基梁振动特性的影响,通过算例说明了这一方法的有效性。 相似文献