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1.
《Comptes Rendus Chimie》2015,18(1):45-55
The aim of this work is to investigate the contribution of the binder (NiAl2O4) on the performances of the oxygen carrier NiO/NiAl2O4. To this purpose, oxidation/reduction cycles have been performed in a fixed bed reactor using CO as a fuel. The results reveal that the binder can react with the fuel to form CO2, and that its total reduction capacity increases with temperature. XRD characterizations performed on the binder (on the fresh and after several cycles) show a shift of the diffraction peaks of NiAl2O4 toward the ones of γ-alumina, which can be attributed to a progressive decomposition of NiAl2O4 to alumina and NiO. 相似文献
2.
《Particuology》2015
Anti-wear beams installed on water walls of circulating fluidized bed (CFB) boilers are one of the most effective ways to protect against water-wall erosion. Beam effects from, for example, beam size and superficial gas velocity were investigated on gas–solid hydrodynamics in a CFB test rig using CFD simulations and experimental methods. The downward flow of the wall layer solids is observed to be disrupted by the beam but is then restored some distance further downstream. When falling solids from the wall layer hit the anti-wear beam, the velocity of the falling solids decreases rapidly. A fraction of the solids accumulates on the beam. Below the beams, the falling solids have reduced velocities but upward-moving solids were observed on the wall. The effect of the beam increases with width and superficial gas velocity. Wear occurs mainly above the beam and its variation with width is different above to below the beam. There is an optimum width that, when combined with beam height, results in less erosion. 相似文献
3.
本文介绍了床面固体颗粒随水流绕过圆柱体时,将在圆柱周围的床面上形成一个无粒子运动区的试验现象。水槽试验结果表明,当固体颗粒的粒径减小时,无粒子区的范围将增大;无粒子区的范围随圆柱直径的增大而增大;水流条件的变化直接影响着床面固体颗粒的运动情况,同无粒子区的形成、消失及范围大小有密切的关系。根据试验资料,结合量纲分析,建立了无粒子区的无量纲经验关系式 相似文献
4.
A fluid flow and heat transfer model has been developed for the reactive, porous bed of the biomass gasifier to simulate pressure drop, temperature profile in the bed and flow rates. The conservation equations, momentum equation and energy equation are used to describe fluid and heat transport in porous gasifier bed. The model accounted for drag at wall, and the effect of radial as well as axial variation in bed porosity to predict pressure drop in bed. Heat transfer has been modeled using effective thermal conductivity approach. Model predictions are validated against the experiments, while effective thermal conductivity values are tested qualitatively using models available in literature. Parametric analysis has been carried out to investigate the effect of various parameters on bed temperature profile and pressure drop through the gasifier. The temperature profile is found to be very sensitive to gas flow rate, and heat generation in oxidation zone, while high bed temperature, gas flow rate and the reduction in feedstock particle size are found to cause a marked increase in pressure drop through the gasifier. The temperatures of the down stream zones are more sensitive to any change in heat generation in the bed as compared to upstream zone. Author recommends that the size of preheating zone may be extended up to pyrolysis zone in order to enhance preheating of input air, while thermal insulation should not be less than 15 cm. 相似文献
5.
Investigation of operational parameters for an industrial CFB combustor of coal, biomass and sludge 总被引:1,自引:0,他引:1
Manon Van de Velden Jan Baeyens Bill Dougan Alan McMurdo 《中国颗粒学报》2007,5(4):247-254
The combustion of coal and/or biomass (sludge, wood waste, RDF, etc.) in a circulating fluidized bed has been a commercial topper for over 20 years, and references to principles and applications are numerous and widespread although few data are presented concerning the operation of large scale CFB-units. The authors studied the CFB-combustion at UPM-Kymmene (Ayr), a major paper mill relying for its steam production upon the combustion of coal (80-85 %), wood bark (5-10%) and wastewater treatment sludge (5-10%). The maximum capacity of the CFB is 58 MWth. A complete diagnostic of the operation was made, and additional tests were performed to assess the operating mode. The plant schematics, relevant dimensions and process data are given. To assess the operation of the UPM-CFB, it is important to review essential design parameters and principles of CFB combustors, which will be discussed in detail to include required data, heat balance and flowrates, operating versus transport velocity, kinetics and conversion (including the possible effect of the Bouduard reaction if carbon is present). Since the residence time in the riser and the cyclone efficiency determine the burnout of circulating fuel-particles, the UPM-CFB was subjected to a stimulus response technique using nickel oxide as tracer. Results illustrate the efficiency of the cyclone separation and the number of recycle loops for particles of a given size. Results will also be used to assess the cyclone operation and efficiency and to comment upon expected and measured carbon conversion. 相似文献
6.
7.
增殖剂球床是聚变堆或混合堆产氚包层可选结构之一,准确把握增殖剂球床中载带气体的流动特性有助于提高对球床载氚过程的认识并优化包层设计。采用离散元程序PFC3D模拟增殖剂小球的填充行为,在球床内不同位置随机截取不同尺寸的控制体,利用布尔运算中的"差集"得到孔隙范围,建立孔隙分布的三维几何模型,进一步划分网格并用计算流体力学(CFD)方法求解,得出控制体上单位长度的压降以及单元体内的速度分布特征,计算结果发现载带气体速度分布与γ分布很类似,且只要选取恰当的控制体,通过计算流体力学方法可以较好地分析整个球床孔隙内流体的流动,有利于进一步研究载氚及相关过程。 相似文献
8.
the measurements of flow over non-uniform gravel open channel have been conducted with Laser Doppler Velocimetry (LDV). The experimental results indicate that the distribution of mean velocity agrees well with the Nikuradse's law. From the distributions of resistance coefficient, reference level and turbulence intensity, the classification of small scale roughness case is obtained.Project supported by the National Science Foundation of China 相似文献
9.
V. I. Erofeev N. V. Klyueva I. N. Soldatov 《Journal of Applied Mechanics and Technical Physics》2005,46(4):549-555
The far-zone structure of the wave field in an elastic bed on a rigid foundation is considered. The wave field is generated by a tangential periodic force applied to the bed surface. The amplitude- frequency characteristics of surface vibrations for propagating modes are found. The partition of energy between different modes is considered.__________Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 46, No. 4, pp. 109–115, July– August, 2005. 相似文献
10.
Hengzhi Chen Dawei Yang Hongzhong Li Shiyu Tan 《中国颗粒学报》2006,4(3):153-159
A pressure balance model for a circulating fluidized bed unit that incorporates a downer has been proposed. The model predictions were validated with the experimental data obtained from a special cold-model circulating fluidized bed. Comparison of the operation stability between a CFB downer and a CFB riser has been carried out. Only one critical gas velocity exists in the CFB-riser for a given riser solids flux, while there can be many critical gas velocities for the operation of a CFB downer. Therefore, it is possible to achieve high solids concentration in a CFB downer if appropriate operating conditions are used. 相似文献