首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4323篇
  免费   553篇
  国内免费   686篇
化学   3256篇
晶体学   19篇
力学   300篇
综合类   133篇
数学   742篇
物理学   1112篇
  2024年   5篇
  2023年   51篇
  2022年   86篇
  2021年   92篇
  2020年   114篇
  2019年   101篇
  2018年   73篇
  2017年   106篇
  2016年   120篇
  2015年   95篇
  2014年   440篇
  2013年   473篇
  2012年   396篇
  2011年   429篇
  2010年   345篇
  2009年   392篇
  2008年   347篇
  2007年   248篇
  2006年   198篇
  2005年   195篇
  2004年   198篇
  2003年   150篇
  2002年   110篇
  2001年   97篇
  2000年   96篇
  1999年   88篇
  1998年   81篇
  1997年   57篇
  1996年   49篇
  1995年   56篇
  1994年   51篇
  1993年   48篇
  1992年   37篇
  1991年   39篇
  1990年   22篇
  1989年   12篇
  1988年   10篇
  1987年   5篇
  1986年   6篇
  1985年   4篇
  1984年   6篇
  1983年   6篇
  1982年   9篇
  1981年   8篇
  1980年   1篇
  1979年   3篇
  1978年   3篇
  1974年   2篇
  1959年   1篇
  1936年   1篇
排序方式: 共有5562条查询结果,搜索用时 156 毫秒
1.
Over the last 20 years a large number of algorithms has been published to improve the speed and domain of convergence of continued fractions. In this survey we show that these algorithms are strongly related. Actually, they essentially boil down to two main principles.We also prove some results on asymptotic expansions of tail values of limit periodic continued fractions.Dedicated to Luigi Gatteschi on his seventieth birthdayThis research was partially supported by The Norwegian Research Council and by the HMC project ROLLS, under contract CHRX-CT93-0416.  相似文献   
2.
幅相一致行波管高频电路CAD研究   总被引:2,自引:2,他引:0       下载免费PDF全文
 在行波管的设计和装配过程中,各部件的尺寸必须严格控制,高频电路参数的离散对行波管色散特性有极大的影响。使用螺旋导电面模型,模拟计算了高频结构各主要参数离散对色散特性和轴向互作用耦合阻抗的影响。分析计算了夹持杆宽度、翼片高度、螺旋线平均半径、螺距、夹持杆介电常数等离散时对色散特性和轴向互作用耦合阻抗的影响,为新型幅相一致行波管的设计和生产提供了很有价值的参考建议。  相似文献   
3.
Modified three-dimensional formulations of bending problems of homogeneous elastic plates and beams are considered. Modification of the known three-dimensional formulations reduces to using additional constraints imposed on displacement functions. An advantage of the formulations proposed is that complex fixing conditions of plates and beams can be taken into account.  相似文献   
4.
Yanmao Shi  Ping Wu  Pan Du  Chenxin Cai 《Acta Physico》2006,22(10):1227-1233
A new electroactive polynuclear inorganic compound of rare earth metal, gadolinium hexacyanoferrate (GdHCF), was prepared and characterized using the techniques of FTIR spectroscopy, thermogravimetric analysis (TG), UV-Vis spectrometry, X-ray photoelectron spectroscopy (XPS), ICP atomic emission spectroscopy, and EDX. The results of ICP atomic emission spectroscopy, EDX, and TGA indicated that the prepared GdHCF sample had a stoichiometry of NaGdFe(CN)6·12H2O (when GdHCF was prepared in NaCl solution). The FTIR spectrum of GdHCF showed that there were two types of water molecules in the structure of GdHCF: one was the interstitial water (5 H2O), which resulted from the association of water due to H-bonding, and the other was water coordinated with Gd (7 H2O). The results obtained using XPS showed that the oxidation state of Fe and Gd in the GdHCF sample was +2 and +3, respectively. GdHCF was immobilized on the surface of spectroscopically pure graphite (SG) electrode forming the GdHCF/SG electrode, and the solid-state electrochemistry of the resultant electrode was studied using cyclic voltammetry. The cyclic voltammetric results indicated that the GdHCF/SG electrode exhibited a pair of well-defined and stable redox peaks with the formal potential of E0′=(197±3) mV. The effects of the concentration of the supporting electrolyte on the electrochemical characteristics of GdHCF were studied, and the results showed that the value of E0′ increased linearly with the activity of the cationic ion of the supporting electrolyte (lgaNa+), with a slope of 54.1 mV, which may become a novel method for determining the activity of Na+ in solution. Further experimental results indicated that GdHCF had electrocatalytic activities toward the oxidation of dopamine (DA) and ascorbic acid (AA), and the electrocatalytic current increased linearly with the concentration of DA (or AA) in the range of 1.0–10.0 mmol·L?1 (for DA) or 0.5–20.0 mmol·L?1 (for AA).  相似文献   
5.
The purpose of this paper is to investigate the problem of approximating fixed points of non-Lipschitizian asymptotically pseudocontractive mappings in an arbitrary real Banach space by the modified Ishikawa iterative sequences with errors.  相似文献   
6.
A series of new poly(butylene succinate) (PBS)/layered silicate nanocomposites were prepared successfully by simple melt extrusion of PBS and organically modified layered silicates (OMLS). Three different types of OMLS were used for the preparation of nanocomposites: two functionalized ammonium salts modified montmorillonite and a phosphonium salt modified saponite. The structure of the nanocomposites in the nanometer scale was characterized with wide-angle X-ray diffraction and transmission electron microscopic observations. With three different types of layered silicates modified with three different types of surfactants, the effect of OMLS in nanocomposites was investigated by focusing on four major aspects: structural analysis, materials properties, melt rheological behavior, and biodegradability. Interestingly, all these nanocomposites exhibited concurrent improvements of material properties when compared with pure PBS. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 3160–3172, 2003  相似文献   
7.
研究了多壁碳纳米管(MWNTs)薄膜的湿敏特性,实验所用的多壁碳纳米管是用热灯丝化学气相沉积法(CVD)合成的.分别对未修饰和修饰的多壁碳纳米管膜温度和湿度特性进行研究后发现,修饰的多壁碳纳米管对温度和湿度非常敏感,且对湿度的响应时间和恢复时间短,重复性好.而未修饰的多壁碳纳米管对温度和湿度不太敏感.对修饰多壁碳纳米管的湿敏特性进行了理论分析,给出了其理论表示式. 关键词: 多壁碳纳米管 化学修饰 湿敏特性 物理吸附  相似文献   
8.
 对氧碘化学激光器的单重态氧发生器(SOG)进行了改进,采用横向射流方式,并对该横向射流式单重态氧发生器的性能进行了检测。实验中过氧化氢碱溶液温度控制在-16℃左右,氯气流量为530mmol/s,He与氯气的流量比为3;采用PS法测量单重态氧分子的产率,吸收法测量氯气的利用率和相对水含量。得出如下结论:在不使用冷阱和分离器的情况下,最高单重态氧分子产率达到58%, 氯气利用率在80%以上,相对水含量小于等于0.5;气体达到最大流量时,发生器仍然能稳定地工作。  相似文献   
9.
与q形变玻色算符逆算符相关的相干态及其量子统计性质   总被引:1,自引:1,他引:0  
奚定平  韦联福 《光学学报》1998,18(12):606-1610
讨论了q形变玻色算符的广义逆算符作用于q-相干态所得到的两类量子态的数学及量子统计性质。结果表明,q-相干态的光子激发态不存在压缩但呈现反聚束效应,而q-相干态的光子湮灭态却存在压缩但不呈现反聚束效应。  相似文献   
10.
Modified Stern-Volmer equation is obeyed by bovine serum albumin (BSA)-iodide system showing selective quenching of tryptophanyl fluorescence of BSA. The fraction of accessible protein fluorescence is 0.56 and the effective Stern-Volmer constant is 290 M-1 at pH 7.4 in 0.005 M phosphate buffer at 25°C. Collisional quenching is operative both in the BSA -I−1 system and the model system, tryptophan-I−1. It is supported by the observed relationship between the ratio of quenching rate constants (k q ) and diffusion coefficients and alsok q with bulk viscosity.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号