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Synthesis and characterization of the stable bromonium ion of 4-equ-chloroadamantylideneadamantane is described. 13C and 1H NMR spectroscopy reveal preferred formation of the syn-isomer, which might be used as chiral bromination reagent using resolved starting material. 相似文献
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Min Young Park 《Tetrahedron letters》2004,45(25):4887-4890
Direct bromination of wide range of aromatic compounds substituted with electron donating groups such as methoxy, hydroxy, or amino groups have been achieved with high regioselectivity by the reaction with Br2 in the presence of tetrabutylammonium peroxydisulfate 1 under mild conditions in acetonitrile in excellent yields. The use of lithium bromide as a bromination reagent afforded high yields of monobromo compounds with complete regioselectivity under neutral and mild reaction conditions in acetonitrile. 相似文献
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我们曾报道2-溴间苯二酚在BF_3催化下酰化时的脱溴现象。本文在以下述反应制备6-溴代异黄酮时发现4-溴间苯二酚脱溴现象更为显著。 相似文献
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Howard Haubenstock 《Tetrahedron》2005,61(35):8358-8365
Density functional computations were carried out whose objectives were to quantify the interactions of chlorine and bromine with neighboring cationic centers in a series of 1-aryl-2-haloethyl cations. Analysis of structural changes and bonding interactions gave rise to linear correlations with σ+ values of the aryl substituents. Electron-donating groups diminished bridging and electron-withdrawing groups gave rise to stronger bridging. 相似文献
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