全文获取类型
收费全文 | 54193篇 |
免费 | 3241篇 |
国内免费 | 5676篇 |
专业分类
化学 | 37018篇 |
晶体学 | 1176篇 |
力学 | 783篇 |
综合类 | 804篇 |
数学 | 10549篇 |
物理学 | 12780篇 |
出版年
2023年 | 518篇 |
2022年 | 590篇 |
2021年 | 1638篇 |
2020年 | 1168篇 |
2019年 | 1361篇 |
2018年 | 945篇 |
2017年 | 1138篇 |
2016年 | 1312篇 |
2015年 | 1390篇 |
2014年 | 1935篇 |
2013年 | 3769篇 |
2012年 | 2673篇 |
2011年 | 3069篇 |
2010年 | 2953篇 |
2009年 | 3584篇 |
2008年 | 3688篇 |
2007年 | 3946篇 |
2006年 | 3207篇 |
2005年 | 2402篇 |
2004年 | 2301篇 |
2003年 | 2044篇 |
2002年 | 1843篇 |
2001年 | 1573篇 |
2000年 | 1281篇 |
1999年 | 989篇 |
1998年 | 946篇 |
1997年 | 765篇 |
1996年 | 810篇 |
1995年 | 784篇 |
1994年 | 739篇 |
1993年 | 773篇 |
1992年 | 742篇 |
1991年 | 526篇 |
1990年 | 385篇 |
1989年 | 378篇 |
1988年 | 375篇 |
1987年 | 281篇 |
1986年 | 266篇 |
1985年 | 372篇 |
1984年 | 309篇 |
1983年 | 162篇 |
1982年 | 328篇 |
1981年 | 508篇 |
1980年 | 465篇 |
1979年 | 485篇 |
1978年 | 384篇 |
1977年 | 294篇 |
1976年 | 252篇 |
1974年 | 80篇 |
1973年 | 157篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
Pavitra Laohapaisan Kanyapat Lumyong Jumreang Tummatorn Charnsak Thongsornkleeb Jaruwan Chatwichien Nantamon Supantanapong Somsak Ruchirawat 《化学:亚洲杂志》2022,17(1):e202101212
ortho-Alkynylarylketone derivatives were employed as key precursors for a one-pot synthesis of arylnaphthalenelactone and furanonaphthol libraries. In this work, we discovered a cost-effective protocol to prepare arylnaphthalenelactones in one-pot using inexpensive starting material, malonate ester, which was conveniently functionalized leading to a variety of structures. Moreover, we also found an unexpected oxy-dearylation reaction which could be used to synthesize furanonaphthol analogs. These novel methods could be applied to a broad range of substrates to give the corresponding products in up to 83% yield. Notably, these classes of compounds exhibited more significant inhibition against protein-tyrosine phosphatase 1B (PTP1B) enzyme than a standard compound, ursolic acid. 相似文献
2.
Carotenoids are an essential component of cashew and can be used in pharmaceuticals, cosmetics, natural pigment, food additives, among other applications. The present work focuses on optimizing and comparing conventional and ultrasound-assisted extraction methods. Every optimization step took place with a 1:1 (w:w) mixture of yellow and red cashew apples lyophilized and ground in a cryogenic mill. A Simplex-centroid design was applied for both methods, and the solvents acetone, methanol, ethanol, and petroleum ether were evaluated. After choosing the extractor solvent, a central composite design was applied to optimize the sample mass (59–201 mg) and extraction time (6–34 min). The optimum conditions for the extractor solvent were 38% acetone, 30% ethanol, and 32% petroleum ether for CE and a mixture of 44% acetone and 56% methanol for UAE. The best experimental conditions for UAE were a sonication time of 19 min and a sample mass of 153 mg, while the CE was 23 min and 136 mg. Comparing red and yellow cashews, red cashews showed a higher carotenoid content in both methodologies. The UAE methodology was ca. 21% faster, presented a more straightforward composition of extracting solution, showed an average yield of superior carotenoid content in all samples compared to CE. Therefore, UAE has demonstrated a simple, efficient, fast, low-cost adjustment methodology and a reliable alternative for other applications involving these bioactive compounds in the studied or similar matrix. 相似文献
3.
Photocatalytic CO2 reduction to C1 fuels is considered to be an important way for alleviating increasingly serious energy crisis and environmental pollution. Due to the environment-friendly, simple preparation, easy formation of highly-stable metal-nitrogen(M-Nx) coordination bonds, and suitable band structure, polymeric carbon nitride-based single-atom catalysts(C3N4-based SACs) are expected to become a potential for CO2 reduction under visible-light irradiation. In this review, we summarize the recent advancement on C3N4-based SACs for photocatalytic CO2 reduction to C1 products, including the reaction mechanism for photocatalytic CO2 reduction to C1 products, the structure and synthesis methods of C3N4-based SACs and their applications toward photocatalytic CO2 reduction reaction(CO2RR) for C1 production. The current challenges and future opportunities of C3N4-based SACs for photoreduction of CO2 are also discussed. 相似文献
4.
Dariusz Marek Adam Domaski Joanna Domaska Jakub Szygua Tadeusz Czachrski Jerzy Klamka 《Entropy (Basel, Switzerland)》2021,23(5)
In this article, a way to employ the diffusion approximation to model interplay between TCP and UDP flows is presented. In order to control traffic congestion, an environment of IP routers applying AQM (Active Queue Management) algorithms has been introduced. Furthermore, the impact of the fractional controller and its parameters on the transport protocols is investigated. The controller has been elaborated in accordance with the control theory. The TCP and UDP flows are transmitted simultaneously and are mutually independent. Only the TCP is controlled by the AQM algorithm. Our diffusion model allows a single TCP or UDP flow to start or end at any time, which distinguishes it from those previously described in the literature. 相似文献
5.
In this work, we present and analyze a mathematical model for tumor growth incorporating ECM erosion, interstitial flow, and the effect of vascular flow and nutrient transport. The model is of phase-field or diffused-interface type in which multiple phases of cell species and other constituents are separated by smooth evolving interfaces. The model involves a mesoscale version of Darcy’s law to capture the flow mechanism in the tissue matrix. Modeling flow and transport processes in the vasculature supplying the healthy and cancerous tissue, one-dimensional (1D) equations are considered. Since the models governing the transport and flow processes are defined together with cell species models on a three-dimensional (3D) domain, we obtain a 3D–1D coupled model. 相似文献
6.
7.
采用溶剂热法,1,3,5-三(羧基甲氧基)苯为定向配体和乙酸镍反应构筑了一个新型的金属配位聚合物[Ni(TB)2(H2O)2]n·2H2O,其中H3TB=1,3,5-三(羧基甲氧基)苯,通过元素分析、IR及X射线单晶衍射对配合物结构进行表征,并研究其荧光性质、热稳定性及Hirshfeld表面作用力。单晶结构分析表明,该配合物属于三斜晶系,空间群$P \overline{1}$,配合物中心离子Ni(Ⅱ)分别与来自两个水分子上的氧原子及四个不同1,3,5-三(羧基甲氧基)苯配体的羧酸氧原子配位,形成六配位的NiO6八面体构型,并通过与1,3,5-三(羧基甲氧基)苯配体的氧原子配位不断延伸形成具有孔洞结构的一维链状构型。配合物具有良好的荧光性能和热稳定性。Hirshfeld表面作用分析表明配合物分子中O…H/H…O作用占主导且占比为39.0%,而H…H的作用力占比为25.9%,O…O的作用力占比为13.6%。 相似文献
8.
Yerko Torres-Nova 《Journal of Pure and Applied Algebra》2021,225(1):106465
Let be integers. A generalized Fermat curve of type is a compact Riemann surface S that admits a subgroup of conformal automorphisms isomorphic to , such that the quotient surface is biholomorphic to the Riemann sphere and has branch points, each one of order k. There exists a good algebraic model for these objects, which makes them easier to study. Using tools from algebraic topology and integration theory on Riemann surfaces, we find a set of generators for the first homology group of a generalized Fermat curve. Finally, with this information, we find a set of generators for the period lattice of the associated Jacobian variety. 相似文献
9.
《中国物理 B》2021,30(5):56501-056501
Thermal expansion control is always an obstructive factor and challenging in high precision engineering field. Here,the negative thermal expansion of Nb F_3 and Nb OF_2 was predicted by first-principles calculation with density functional theory and the quasi-harmonic approximation(QHA). We studied the total charge density, thermal vibration, and lattice dynamic to investigate the thermal expansion mechanism. We found that the presence of O induced the relatively strong covalent bond in Nb OF_2, thus weakening the transverse vibration of F and O in Nb OF_2, compared with the case of Nb F_3.In this study, we proposed a way to tailor negative thermal expansion of metal fluorides by introducing the oxygen atoms.The present work not only predicts two NTE compounds, but also provides an insight on thermal expansion control by designing chemical bond type. 相似文献
10.
《Expositiones Mathematicae》2022,40(4):910-919
This paper proves such a new Hilbert’s Nullstellensatz for analytic trigonometric polynomials that if are analytic trigonometric polynomials without common zero in the finite complex plane then there are analytic trigonometric polynomials obeying in , thereby not only strengthening Helmer’s Principal Ideal Theorem for entire functions, but also finding an intrinsic path from Hilbert’s Nullstellensatz for analytic polynomials to Pythagoras’ Identity on . 相似文献