首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   801075篇
  免费   2976篇
  国内免费   1744篇
化学   397713篇
晶体学   15758篇
力学   38243篇
综合类   33篇
数学   99746篇
物理学   254302篇
  2021年   7081篇
  2020年   8011篇
  2019年   8981篇
  2018年   10613篇
  2017年   10899篇
  2016年   15378篇
  2015年   9198篇
  2014年   14407篇
  2013年   34374篇
  2012年   26560篇
  2011年   31968篇
  2010年   23256篇
  2009年   23113篇
  2008年   30131篇
  2007年   29734篇
  2006年   27610篇
  2005年   24925篇
  2004年   23049篇
  2003年   20865篇
  2002年   20903篇
  2001年   21990篇
  2000年   17257篇
  1999年   13629篇
  1998年   11721篇
  1997年   11513篇
  1996年   10843篇
  1995年   9663篇
  1994年   9589篇
  1993年   9324篇
  1992年   9976篇
  1991年   10499篇
  1990年   10018篇
  1989年   10006篇
  1988年   9804篇
  1987年   9445篇
  1986年   9196篇
  1985年   11941篇
  1984年   12284篇
  1983年   10340篇
  1982年   10980篇
  1981年   10264篇
  1980年   9931篇
  1979年   10424篇
  1978年   10876篇
  1977年   10708篇
  1976年   10635篇
  1975年   10190篇
  1974年   10026篇
  1973年   10398篇
  1972年   7417篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
3.
    
The reaction of [{(η5-C5Me5)M(μ-Cl)Cl}2] {where M = Rh (1), Ir (2)} with functionalized phosphine viz., diphenyl-2-pyridylphosphine (PPh2Py) in dichloromethane solvent yield neutral ϰ1-P-coordinated rhodium and iridium complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3 and [(η5-C5Me5) IrCl21-P-PPh2Py)]4. Reaction of complexes 1 and 2 with the ligand PPh2Py in methanol under reflux give bis-substituted complexes such as [(η5-C5Me5)RhCl(ϰ1-P-PPh2Py)2]+ 5 and [(η5-C5Me5)IrCl(ϰ1-P-PPh2Py)2]+ 6, whereas stirring in methanol at room temperature gives P-, N-chelating complexes of the type [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5)IrCl(ϰ2-P-N-PPh2Py)]+ 8. Neutral ϰ1-P-coordinated complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3 and [(η5-C5Me5)IrCl21-P-PPh2Py)]4 easily undergo conversion to the cationic P-, N-chelating complexes [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5) IrCl(ϰ2-P, N-PPh2Py)]+ 8 on stirring in methanol at room temperature. These complexes are characterized by FT-IR and FT-NMR spectroscopy as well as analytical methods. The molecular structures of the representative complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3, [(η5-C5Me5)IrCl21-P-PPh2Py)]4 and hexafluorophosphate salt of complex [(η5-C5Me5)IrCl(ϰ2-P-PPh2Py)2]+ 6 are established by single-crystal X-ray diffraction methods  相似文献   
4.
An optimal control model of exhaustible resources is used to clarify the long run relationship between mineral rent and depletion cost at the industry level. A standard first order condition of the time rate of change of rents is reformulated to reveal that rent data may be used to help forecast the rise in extraction costs resulting from resource depletion. This application of the theory of exhaustible resources is illustrated using historical mineral industry rent and extraction cost data. A forecast of U.S. coal extraction costs, following the method proposed in this paper, suggests that future rates of extraction cost increases will be similar to rates experienced in the past.  相似文献   
5.
Preface     
  相似文献   
6.
7.
A new solvent-free sample preparation method using silver trifluoroacetate (AgTFA) was developed for the analysis of low molecular weight paraffins and microcrystalline waxes by laser desorption/ionization time-of-flight mass spectrometry (LDI-TOFMS). Experiments show that spectral quality can be enhanced by dispersing AgTFA directly in liquid paraffins without the use of additional solvents. This preparation mixture is applied directly to the MALDI probe. Solid waxes could be examined by melting prior to analysis. The method also provides sufficiently reproducible spectra that peak area ratios between mono- and bicyclic alkane peaks indicated variations in the cycloalkane content of paraffin samples. Dehydrogenation of hydrocarbons observed during the desorption/ionization process was studied by analysis of alkane standards.  相似文献   
8.
V. A. Steklov Mathematics Institute, USSR Academy of Sciences. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 79, No. 3, pp. 347–358, June, 1989.  相似文献   
9.
A detailed analysis is made within perturbative QCD of the decays into gluon jets of P-wave and S-wave quarkonia (JPC = 0++, 1++, 2++, 1+? and 0?+, 1??). For all those states we compute to leading non-trivial order in αs the conventional fraction f(?, δ) of the jet-like hadronic final states, characterized by the back-to-back cone of half angle δ, in which all but a small fraction ? of the total energy is emitted. To the same order we give also the average values of thrust momenta and spherocity distributions.  相似文献   
10.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号