简单碰撞理论的一种推导方法

设想双分子气体反应是由硬球分子先活化、再反应的模式进行,不仅能使简单碰撞理论(SCT)的推导变得更为简便,而且阈能和Arrhenius活化能等概念也变得更加明确。     

P507负载泡塑吸附分离-中子活化法测定地质样品中的稀土元素

研究了P507负载泡塑萃取柱吸附、分离和富集稀土元素的条件,确定了地学样品中微量稀土元素的化学前处理方法和中子活化测量条件。方法的RSD在3.4%~10%之间,回收率大于92%。用国家标准物质进行分析验证,测定结果与推荐值相符。     

负离子远红外纳米银、锌、硒元素中药外治烧烫伤药剂的应用研究进展

烧烫伤为热源造成体表组织的损伤,大面积的深度烧烫伤可并发休克、败毒症等。介绍了用纳米粉碎技术,将中药超微粒化,添加纳米锌、硒等微量元素,加广谱强效纳米银系(AT)抗菌剂、麦饭石纳米粉、远红外二氧化钛、电气石在传统中药配方基础上制成的纳米中药,用于烧烫伤的治疗,提高了药物疗效。     

非线性再生散度模型的几何结构及其渐近推断

本文基于唐年胜等(1999)对非线性再生散度模型在欧氏空间建立的微分几何结构导出了与估计有关的随机展开以及与统计曲率有关的若干渐近推断,推广了韦博成等人关于非线性回归模型和指数族非线性模型的相应结果.     

Fano-Like Resonance in Cylinders Including Nonlocal Effects

We investigate the optical response of a metallic wire calculated from the classical electromagnetic theory. The Drude （local） approach is compared with the semi-classical hydrodynamical theory calculations that reveal the Fano-like resonances of subsidiary peaks originated from the nonlocality. The bulk plasma resonances containing the nonlocal effects could be depressed by increasing the dissipation, while the blue shift of the surface localized plasma resonances could be enhanced by increasing the Fermi velocity.     

Stability of elliptic vortex solitons in anisotropic nonlocal media

Elliptic vortex solitons are investigated in anisotropic nonlocal media with more general formulations. We address the existence and dynamics of such solitons analytically and numerically. The solution of elliptic vortex solitons depends on the eccentricity of both the input beam and nonlocal response function. With different degrees of nonlocality, we numerically investigate the evolution of the elliptic vortex solitons, and find that, typically, the elliptic vortex solitons with single and double charges collapse into spiraling dipole- and tripolelike soliton clusters, respectively.     

Observation of tropospheric NO_2 by airborne multi-axis differential optical absorption spectroscopy in the Pearl River Delta region,south China

An airborne multi-axis differential optical absorption spectroscopic （AMAX-DOAS） instrument was developed and applied to measure tropospheric NO2 in the Pearl River Delta region in the south of China. By combining the measurements in nadir and zenith directions and analyzing the UV and visible spectral region using the DOAS method, information about tropospheric NO2 vertical columns was obtained. Strong tropospheric NO2 signals were detected when flying over heavilly polluted regions and point sources like plants. The AMAX-DOAS results were compared with ground-based MAX-DOAS observations in the southwest of Zhuhai city using the same parameters for radiative transport calculations. The difference in vertical column data between the two instruments is about 8%. Our data were also compared with those from OMI and fair agreement was obtained with a correlation coefficient R of 0.61. The difference between the two instruments can be attributed to the different spatial resolution and the temporal mismatch during the measurements.     

爆炸地冲击作用下浮放设备滑移抛离分析

从基础和设备间的接触力特点出发,采用Matlab/SIMULINK仿真软件建立了爆炸地冲击作用下浮放设备的滑移抛离模型,并验证了该模型的正确性。通过输入实测爆炸地冲击加速度波得出在真实爆炸环境中浮放设备的运动历程可分为相对静止、滑移、抛离、滑移减速等四个阶段。并根据其特点,提出了合理简化加速度波,采用该加速度波形,分析得到了浮放设备运动响应与动摩擦系数、爆炸地运动参数的关系。     

乙烯、乙炔和苯与氨基锂间的π型锂键相互作用

分别在DFT-B3LYP和MP2/6-311++G**水平上求得乙烯、乙炔和苯与氨基锂锂键复合物势能面上的3个几何构型. 频率分析表明,3个构型均为稳定构型. 计算结果表明,形成锂键复合物后,质子供体N(2)- Li(4)的键长明显增大,且其伸缩振动的频率发生了不同程度的红移. 分别在乙烯…氨基锂、乙炔…氨基锂和苯…氨基锂三种复合物中,经MP2/6-311++G**水平计算的同时含基组重叠误差(BSSE)和零点振动能校正的单体间锂键相互作用能分别为-26.04、-24.86 和 -30.02 kJ·mol-1. 自然键轨道理论（NBO）分析表明单体间的弱相互作用属于π-s型锂键.     

纳米电化学生物传感器

纳米电化学生物传感器是将纳米材料作为一种新型的生物传感介质,与特异性分子识别物质如酶、抗原/抗体、DNA等相结合,并以电化学信号为检测信号的分析器件。本文简要介绍了生物传感器的分类和纳米材料在电化学生物传感器中的应用及其优势,综述了近年来各类纳米电化学生物传感器在生物检测方面的研究进展,包括纳米颗粒生物传感器,纳米管、纳米棒、纳米纤维与纳米线生物传感器,以及纳米片与纳米阵列生物传感器等。