不过滤水样中铁离子的反射吸光光度法研究

自制了与商品化吸光光度计匹配的反射吸光度测定装置,并利用该装置研究了水样浊度对铁(Ⅱ)-邻菲罗啉络合物反射吸光度的影响。实验结果表明,当铁离子质量浓度在0~10.00 mg/L范围内时,具有一定浊度(T)的试样按标准方法显色后,试样浊度的反射吸光度(AT)与铁(Ⅱ)-邻菲罗啉络合物的反射吸光度具有加和性。通过大量实验数据,推导出AT=4.49×10~(-4)T+0.0264(R~2=0.9774,n=20)。基于此,建立了不过滤水样中铁离子的反射吸光光度法,即:水样无需过滤,按标准方法加入试剂显色,测得吸光度AS;同时,用以上推导公式计算AT;以AS-AT代入标准曲线方程即可计算待测水样中的铁离子质量浓度。采集4个实际河水水样为基底,随机加入适量铁离子标准溶液,分别用本论文研究的方法和标准方法测定水样中的铁离子质量浓度,两者的测定结果无显著差异。     

Electrosynthesis,characterization and optical sensing application of amino acid functionalized polyfluorene

An amino acid side chain functionalized polyfluorene derivative poly[N-(9-fluorenylmethoxycarbonyl)-glycine](P9FG) was facilely electrosynthesized and characterized, and the structure, properties and optical sensing application of the obtained polymer were described and discussed. The electropolymerization occurred at C2 and C7 positions of fluorene units, and amino acid side chain groups were not cleaved from polyfluorene backbone in mixed electrolytes of boron trifluoride diethyl etherate and dichloromethane. Thermal analysis demonstrated good thermal stability of P9 FG. Fluorescent spectra indicated that P9 FG was a good blue light emitting material that could be employed as optical sensors. The soluble P9 FG as a turn-off fluorescent sensor could realize the detection of Fe3+, Cu2+ and Cr2O72?, respectively. In addition, P9 FG as a turn-off ultraviolet sensor could realize the detection of Cu2+ while as turn-on ultraviolet sensors could also realize the determination of Fe3+ and Cr2O72?, respectively. All results indicate that P9 FG is a promising candidate for optical sensing.     

非紧L-凸空间中的一个新的极大元定理及其对鞍点的应用(英文)

在非紧L-凸空间中建立一个新的极大元定理.作为应用,获得了非紧L-凸空间中的极大极小不等式和鞍点定理.     

Nonlinear images of scatterers in chirped pulsed laser beams

The bandwidth and the duration of incident pulsed beam are proved to play important roles in modifying the nonlinear image of amplitude-type scatterer.It is found that the initially positive chirp-type bandwidth can suppress the nonlinear image,while the negative one can enhance it,and that both effects are inversely proportional to the incident pulse duration.Numerical simulations further demonstrate that the location of nonlinear image is at the conjugate plane of the scatterer and that,for negatively pre-chirped pulsed beam,the nonlinear image peak intensity can be higher than that in the corresponding monochromatic case under certain conditions.Moreover the effect of group velocity dispersion on nonlinear image is found to be similar to that of chirp-type bandwidth.     

各向异性超常材料平板透镜的聚焦特性分析

运用矢量角谱理论研究各向异性超常材料平板透镜的聚焦特性,得到了光束在平板透镜内外各区域的矢量场分布,揭示了超常材料平板透镜的聚焦特性跟材料的各向异性参数之间的定量关系,发现聚焦场的偏振态因平板透镜的各向异性特性而发生改变.作为矢量理论的具体应用,分析了光轴方向磁导率为-1,其他各向异性参数均为1的超常材料平板透镜的聚焦特性,发现此类透镜对初始沿某一横向方向偏振的光束能实现部分聚焦,并发生偏振旋转现象.     

非线性极大极小问题一个新的QP-free算法

本文研究非线性无约束极大极小优化问题. QP-free算法是求解光滑约束优化问题的有效方法之一,但用于求解极大极小优化问题的成果甚少.基于原问题的稳定点条件,既不需含参数的指数型光滑化函数,也不要等价光滑化,提出了求解非线性极大极小问题一个新的QP-free算法.新算法在每一次迭代中,通过求解两个相同系数矩阵的线性方程组获得搜索方向.在合适的假设条件下,该算法具有全局收敛性.最后,初步的数值试验验证了算法的有效性.     

大黄素-铜（Ⅱ）配合物与核酸的相互作用

用光谱法研究了大黄素-铜（Ⅱ）配合物与核酸相互作用。在pH=5.6时和最大发射波长434nm处,核酸能显著地猝灭大黄素-铜（Ⅱ）的荧光强度。在最佳条件下,对ctDNA和yRNA的线性范围分别是0.18—2.2μg/mL和0.16—2.3μg/mL。通过合成试样实验,结果令人满意。     

A preliminary quadrupole asymmetry study of a Iβ=0.12 superconducting single spoke cavity

An Accelerator Driven System (ADS) has been launched in China for nuclear waste transmutation. For the application of high intensity proton beam acceleration, the quadrupole asymmetry effect needs to be carefully evaluated for cavities. Single spoke cavities are the main accelerating structures in the low energy front-end. The single spoke cavity has small transverse electromagnetic field asymmetry, which may lead to transverse RF defocusing asymmetry and beam envelope asymmetry. A superconducting single spoke resonator (PKU-2 Spoke) of β =0.12 and f=325 MHz with a racetrack-shaped inner conductor has been designed at Peking university. The study of its RF field quadrupole asymmetry and its effect on transverse momentum change has been performed. The quadrupole asymmetry study has also been performed on a β =0.12 and f=325 MHz ring-shaped single spoke cavity. Our results show that the quadrupole asymmetry is very small for both the racetrack-shaped and the ring-shaped single spoke cavity.     

平头弹丸撞击下薄金属靶板Wen-Jones模型的进一步研究(英文)

针对平头弹丸穿透固支圆形金属薄靶问题,对Wen-Jones模型进行了推广应用。根据前人的研究成果,提出了等效应变失效准则,以预测金属薄靶的穿透。与实验数据的对比表明,新模型的预测结果与有关低碳钢和铝合金的实验结果相吻合。尽管新模型与WenJones模型采用的破坏准则不同,但是两者的预测结果相近。分析发现,当靶板材料的延性足够大时,Wen-Jones模型可看作是新模型的一种特殊情况。     

搅拌法制备聚合物微球中油水相对壁厚的影响

为了研究乳液微封装技术中油水相对微球壁厚的影响,推导了在理想状态下微球壁厚、油相质量分数和油水相比这三者之间的函数关系。结果表明:当内相水滴半径和油相质量分数为常数时,微球壁厚是油水相比的单增函数;而当内相水滴半径和油水相比为常数时,微球壁厚是油相质量分数的单增函数。即提高油相质量分数或增大油水相比对增加壁厚而言具有等效性。根据此规律,在搅拌法制备小直径聚苯乙烯微球中,通过调整油水相的各参数,确定了制备小直径厚壁聚苯乙烯微球的关键工艺参数。实验表明:采用搅拌法制备10~25 m壁厚的小直径聚苯乙烯微球时,油相质量分数宜配制为5.3%~7.0%,油水相比宜控制在1.6~2.2之间,而外水相中聚乙烯醇质量分数宜控制在1%~3%之内。