锂参与合成MOF-5用于CO_2/CH_4混合气体分离

利用溶剂热法合成了不同锂含量的MOF-5(x Li-MOF-5,x=0,1,3,5)。在MOF-5结晶过程中,锂离子被合并入其骨架结构中。实验表明,合并入骨架的锂能够改变MOF-5的结构和表面化学性质。不同的x Li-MOF-5能够不同程度降低骨架相互穿插的程度从而导致其吸附分离能力的大幅改变。其中,3Li-MOF-5具有最高的二氧化碳捕获能力(5.47 mmol·g-1),对40%CO2/60%CH4混合气体具有最优吸附选择性。     

锂参与合成MOF-5用于CO2/CH4混合气体分离

利用溶剂热法合成了不同锂含量的MOF-5(xLi-MOF-5, x=0, 1, 3, 5).在MOF-5结晶过程中,锂离子被合并入其骨架结构中.实验表明,合并入骨架的锂能够改变MOF-5的结构和表面化学性质.不同的xLi-MOF-5能够不同程度降低骨架相互穿插的程度从而导致其吸附分离能力的大幅改变.其中,3Li-MOF-5具有最高的二氧化碳捕获能力(5.47 mmol·g^-1),对40% CO₂/60% CH₄混合气体具有最优吸附选择性.     

碱性金属修饰金属有机骨架材料MOF-5吸附位点及其常态下分离二氧化碳/甲烷的应用

利用“一步法”合成并表征了4种碱性金属修饰的金属有机骨架材料MOF-5(记作M-MOF-5,M=Li,Na,K,Mg)。 并应用理想溶液吸附理论(IAST)对样品吸附选择性进行计算比较。 结果表明,碱性金属掺入可以降低MOF-5材料骨架结构的“互穿”程度,同时,在常温常压下,M-MOF-5对CO₂/CH₄的吸附选择性相对MOF-5(选择性为3.79)有着显著提高,尤其是Li-MOF-5(选择性为7.39)。 此外,Li-MOF-5的CO₂捕获能力相对MOF-5也有提高。     

金属氧化物@金属有机骨架复合材料研究进展

金属有机骨架(Metal-Organic Framework,MOF)复合材料是一种新型功能性材料,其中金属氧化物@MOF复合材料因结合了金属氧化物和MOFs的许多特性而受到人们的广泛关注,成为近年来MOFs材料研究的一个重要方向。本文综述了金属氧化物@MOF复合材料制备方法的研究进展,主要包括外延生长法、气相沉积法、模板法等,并分析了它们各自的优缺点;概述了金属氧化物@MOF复合材料在催化、传感、生物医药、吸附与分离方面的具体应用性能,以及在电化学研究领域的潜在应用;并提出今后金属氧化物@MOF复合材料研究的主要方向是开发简单高效的制备方法、选取新功能性金属氧化物以及探索复合材料的其它新型结构,以拓展其在工业上的应用。     

9MeV,小于0.1mm微焦点X射线源验证实验

密度高、成像分辨率高、成像速度快的X射线数字成像检测需要高能微焦点大剂量X射线源,高品质电子源是实现这一X射线源的关键手段。基于中国工程物理研究院太赫兹自由电子激光的主加速器,验证了低发射度、低能散度的高亮度电子束实现高能微焦点的可行性,得到电子束半高全宽尺寸小于70μm的9 MeV微焦点,并初步开展成像实验,双丝像质计焦斑清晰分辨9D号丝,丝直径0.13 mm。     

Geometry dependent multipacting of a superconducting quarter-wave resonator at PKU

A superconducting quarter-wave resonator (QWR) of frequency=162.5 MHz and β=0.085 (β =v/c) has been designed at Peking University. The multipacting (MP) simulation and analysis for the QWR with CST Particle Studio has been performed. The simulation results reveal that there is no sign of MP with its normal operating accelerating gradients in the range of 6-8 MV/m. The accelerating gradient range that may incur MP is from about 1.4 to 3.2 MV/m, and the places where MP may be encountered are mainly located at the top part of the QWR. So the effect of different top geometries on MP has also been studied in depth. Our results show that an inward convex round roof is better than other round roofs, and plane roofs have an advantage over round roofs on the suppression of MP in general. While considering the optimization of its electromagnetic (EM) design, our initial designed model is also acceptable.     

A preliminary quadrupole asymmetry study of a β=0.12 superconducting single spoke cavity

An Accelerator Driven System(ADS) has been launched in China for nuclear waste transmutation. For the application of high intensity proton beam acceleration, the quadrupole asymmetry effect needs to be carefully evaluated for cavities. Single spoke cavities are the main accelerating structures in the low energy front-end. The single spoke cavity has small transverse electromagnetic field asymmetry, which may lead to transverse RF defocusing asymmetry and beam envelope asymmetry. A superconducting single spoke resonator(PKU-2 Spoke) of β=0.12 and f =325 MHz with a racetrack-shaped inner conductor has been designed at Peking university. The study of its RF field quadrupole asymmetry and its effect on transverse momentum change has been performed. The quadrupole asymmetry study has also been performed on a β=0.12 and f =325 MHz ring-shaped single spoke cavity. Our results show that the quadrupole asymmetry is very small for both the racetrack-shaped and the ring-shaped single spoke cavity.     

A preliminary study of the feasibility of using superconducting quarter-wave resonators foraccelerating high intensity proton beams

The superconducting (SC) cavities currently used for the acceleration of protons at a low velocity range are based on half-wave resonators. Due to the rising demand on high current, the issue of beam loading and space-charge problems has arisen. Qualities of low cost and high accelerating efficiency are required for SC cavities, which are properly fitted by using SC quarter-wave resonators (QWR). We propose a concept of using QWRs with frequency 162.5 MHz to accelerate high current proton beams. The main factor limiting SC QWRs being applied to high current proton beams is vertical beam steering, which is dominantly caused by the magnetic field on axis. In this paper, we intend to analyze steering and eliminate it to verify the qualification of using QWRs to accelerate high intensity proton beams.     

Electromagnetic design and optimization of a superconducting quarter wave resonator

Superconducting (SC) cavities currently used for the acceleration of protons at a low velocity range are based on half wave resonators. Due to the rising demand on high current, the issue of beam loading and space charge problems has arisen. Qualities of low cost and high accelerating efficiency are required for SC cavities, which are properly fitted by using an SC quarter wave resonator (QWR). We propose a concept of using QWRs with frequency 162.5 MHz to accelerate high current proton beams. The electromagnetic design and optimization of the prototype have been finished at Peking University. An analytical model derived by the transmission line theory is used to predict an optimal combination of the geometrical parameters, with which the calculation by Microwave Studio shows a good agreement. The thermal analysis to identify the temperature rise of the demountable bottom plate under various levels of thermal contact also has been done, and the maximum increment is less than 0.5 K even though the contact state is poor.     

A preliminary quadrupole asymmetry study of a Iβ=0.12 superconducting single spoke cavity

An Accelerator Driven System (ADS) has been launched in China for nuclear waste transmutation. For the application of high intensity proton beam acceleration, the quadrupole asymmetry effect needs to be carefully evaluated for cavities. Single spoke cavities are the main accelerating structures in the low energy front-end. The single spoke cavity has small transverse electromagnetic field asymmetry, which may lead to transverse RF defocusing asymmetry and beam envelope asymmetry. A superconducting single spoke resonator (PKU-2 Spoke) of β =0.12 and f=325 MHz with a racetrack-shaped inner conductor has been designed at Peking university. The study of its RF field quadrupole asymmetry and its effect on transverse momentum change has been performed. The quadrupole asymmetry study has also been performed on a β =0.12 and f=325 MHz ring-shaped single spoke cavity. Our results show that the quadrupole asymmetry is very small for both the racetrack-shaped and the ring-shaped single spoke cavity.