1,2,3-三唑羧酸铜(Ⅱ)配合物的合成、晶体结构与性质

通过水热的方法制备了两个新的1,2,3-三唑羧酸铜配合物:[Cu(L1)2· 2H2O](1)和[Cu(L2)2]n(2)(HL1=4-苯基-1,2,3-三唑-1-乙酸,HL2=4-苯基-1,2,3-三唑-2-乙酸),并利用红外光谱、质谱(MS)、核磁共振氢谱(1 H NMR)、元素分析、X-射线单晶衍射、X-射线粉末衍射和热重分析进行了表征.晶体结构表明:配合物1中,每一个单核分子通过分子间氢键作用形成二维层状结构.配合物2中,铜原子通过与羧基上的氧原子采用顺-反双齿桥联,形成了二维的网状结构,进一步通过每层网状结构间的π-π堆积作用形成三维超分子结构.磁性测试结果表明配合物2在低温下表现为铁磁性相互作用.     

A prototype silicon detector system for space cosmic-ray charge measurement

A readout electronics system used for space cosmic-ray charge measurement for multi-channel silicon detectors is introduced in this paper, including performance measurements. A 64-channel charge sensitive ASIC (VA140) from the IDEAS company is used. With its features of low power consumption, low noise, large dynamic range, and high integration, it can be used in future particle detecting experiments based on silicon detectors.     

Probe the 2s_(1/2) and 1d_(3/2) state level inversion with electron-nucleus scattering

The neutron-rich even-even nuclei26–40Mg,28–46Si,30–48S,and32–56Ar are calculated with the RMF model and the phase-shift electron scattering method.Results show that level inversion of the 2s1/2and 1d3/2proton states may occur for the magnesium,silicon,sulphur,and argon isotopes with more neutrons away from the stability line.Calculations show that the variation of the central charge densities for30–48S,and32–56Ar are very sensitive to the 2s1/2and 1d3/2proton state level inversion,and the level inversion can lead to a large measurable central charge depletion to the charge density distributions for the neutron-rich isotopes.Calculations also show that the charge density diferences between the isotopes with and without central charge depletion can reveal not only the level inversion of the 2s1/2and 1d3/2proton states but also the behavior of the proton wave functions of both states.The results can provide references for the possible study of the nuclear level inversion and nuclear bubble phenomenon with electron scattering of short-lived nuclei at RIKEN or/and GSI in the future.In addition,direct nuclear reaction44S(n,d)43P or44S(3H,α)43P might also be a possible way to study the 2s1/2and 1d3/2proton state level inversion.     

金等离子体M带谱3d→4f和3d→5f电子离子碰撞激发强度

电子离子碰撞激发强度在超组态碰撞辐射模型中真实模拟非局域热动平衡金激光等离子体M带谱跃迁中离子的平均电离度、电荷态分布和能级布居数等离子的电离态特性是必不可少的.基于全相对论扭曲波电子碰撞激发计算程序REIE06,系统计算了高离化态金离子(Au51+、Au50+、Au49+)精细结构能级3d→4f和3d→5f的碰撞强度,计算中详细考虑了电子关联效应和Breit相互作用对碰撞强度的影响.计算结果与可获得的其它理论及实验结果进行了比较,取得了好的一致性.     

基于运动方向估计的管道滤波算法

管道滤波算法提出了从时域角度解决弱小目标检测问题的思路,对于红外强起伏天空背景中弱点目标的检测问题,管道内强噪音的干扰以及低信噪比的条件会导致检测概率降低的情况出现.本文提出了一种运动方向估计的管道滤波算法,分析了红外弱点目标的运动特性,依据弱点目标在相邻帧间位置具有连贯性的特征,建立了弱点目标的运动方向估计模型.在模型中利用弱点目标逐帧检测的先验位置信息,估计弱点目标的运动方向和轨迹,根据估计结果去除管道内噪音对弱点目标的干扰.仿真结果表明,该方法能够很好地抑制管道内噪音的影响,提高弱点目标的检测概率,增强弱点目标抗管道内噪音干扰的能力.     

智能声速测量仪

针对大学物理实验中声速测量装置存在的缺陷,对仪器进行了改进.运用物理实验中的共振干涉法,利用单片机、步进电机搭建的基本框架,结合AD采样、设计运放电路,形成一套智能控制的声速测量系统,来代替人的手工操作,降低了实验的误差,提高了实验精确度.     

Chemical composition of the lunar surface from neutron leakage fluxes

The neutron leakage fluxes from the lunar surface are calculated by Monte Carlo transport code based on Geant4. The integral fluxes of fast neutrons, epi-thermal neutrons and thermal neutrons are analyzed. Numerical results for 20 kinds of lunar soils and 7 minerals show that the fast neutron fluxes are linearly related to the average atomic mass numbers of the lunar materials used in simulations. Meanwhile, the average atomic mass numbers are strongly modulated by the abundances of iron (Fe) and titanium (Ti), and a linear relationship between the average atomic mass numbers and the abundances of Fe and Ti is found. Furthermore, the results show that the ratios of epi-thermal to thermal fluxes for lunar soils are linearly related to the macroscopic absorption cross sections of lunar materials, and that the macroscopic absorption cross sections monotonically increase with the abundances of Fe and Ti by a simple function. Then we reach the conclusion that the neutron fluxes can provide the information about the Fe and Ti contents.     

电子和原子核散射研究原子核结构(英文)

本文综述了近年来我们组利用电子散射结合相对论平均场模型对奇特核结构的研究。我们发展了相对论平均场框架下的磁电子散射方法,并用其研究一些中子晕及质子晕核的基态组态,例如,23O,17,19C和23Al。研究发现,原子核不同组态的弹性磁形状因子彼此差别很大。其次,我们发展了相对论平均场框架下的弹性库伦电子散射方法,并用该方法研究了奇特核的电荷分布。研究发现,丰质子核中扩展的电荷密度分布可以通过库伦电子散射来测量。这种方法还被进一步推广用于计算弹性宇称不守恒电子散射,研究了一些典型原子核的中子密度分布,例如,Ca同位素链,N=50同中子素链以及N=Z的双幻核。结果表明,宇称不守恒非对称度的振幅主要由质子和中子形状因子极小值之间的距离决定。这些结果为下一代电子-核对撞机上的电子散射实验提供了有用的参考。     

锌对酒精性肝病小鼠的作用研究

为探究膳食补充锌是否改善肝再生,选用12周大的雄性C57BL/6小鼠40只,按随机数字表法分为4组:正常对照组、酒精中毒组、正常补锌组及酒精中毒补锌组,予不同的饮食喂养6个月后,通过增殖细胞核抗原(PCNA)阳性标记的肝细胞数目评价了肝细胞再生状况,并检测了超氧化物歧化酶(SOD)及丙二醛(MDA)含量评估肝损伤的氧化...