Efficiently enhanced energy storage performance of Ba2Bi4Ti5O18 film by co-doping Fe3+ and Ta5+ ion with larger radius

We present an efficient strategy, that is the co-substitution of Fe³⁺ and Ta⁵⁺ ions with large radius for Ti⁴⁺ ion, to enhance energy storage performance of Ba₂Bi₄Ti₅O₁₈ film. For the films co-doped with Fe³⁺ and Ta⁵⁺ ions, the maximum polarization under the same external electric field is improved because the radius of Fe³⁺ and Ta⁵⁺ ions is larger than that of Ti⁴⁺ ion. Moreover, due to the composition and chemical disorder, the relaxor properties are also slightly improved, which can not be achieved by the film doped with Fe³⁺ ions only. What is more, for the films doped with Fe³⁺ ion only, the leakage current density increases greatly due to the charge imbalance, resulting in a significant decrease in breakdown strength. It is worth mentioning that the breakdown strength of Fe³⁺ and Ta⁵⁺ ions co-doped film does not decrease due to the charge balance. Another important point is the recoverable energy storage density of the films co-doped with Fe³⁺ and Ta⁵⁺ ions has been greatly improved based on the fact that the maximum external electric field does not decrease and the maximum polarization under the same external electric field increases. On top of that, the hysteresis of the polarization has also been improved. Finally, the co-doped films with Fe³⁺ and Ta⁵⁺ ions have good frequency and temperature stability.     

Chromium(III)-Ettringite Formation and its Thermal Stability

Attempts have been made to replace aluminium(III) by chromium(III) in the ettringite structure because of practical importance of a waste treatment technology. The optimum conditions of Ca₆[Cr(OH)₆]₂(SO₄)₃⋅26H₂O formation and its thermal stability are reported. This revised version was published online in July 2006 with corrections to the Cover Date.     

A fixed point formula of Lefschetz type in Arakelov geometry I: statement and proof

We consider arithmetic varieties endowed with an action of the group scheme of n-th roots of unity and we define equivariant arithmetic K ₀-theory for these varieties. We use the equivariant analytic torsion to define direct image maps in this context and we prove a Riemann-Roch theorem for the natural transformation of equivariant arithmetic K ₀-theory induced by the restriction to the fixed point scheme; this theorem can be viewed as an analog, in the context of Arakelov geometry, of the regular case of the theorem proved by P. Baum, W. Fulton and G. Quart in [BaFQ]. We show that it implies an equivariant refinement of the arithmetic Riemann-Roch theorem, in a form conjectured by J.-M. Bismut (cf. [B2, Par. (l), p. 353] and also Ch. Soulé’s question in [SABK, 1.5, p. 162]). Oblatum 22-I-1999 & 20-II-2001?Published online: 4 May 2001     

On first order congruences of lines of ℙ4 with a fundamental curve

We discuss projective families of lines of ℙ ⁿ , and in particular congruences of order one. After giving general results, we obtain a complete classification of the case of ℙ⁴ in which there is a fundamental curve. Received: 2 August 2000 / Revised version: 11 July 2001     

Classification of incidence scrolls (I)

The aim of this paper is to obtain a classification of scrolls of genus 0 and 1, which are defined by a one-dimensional family of lines meeting a certain set of linear spaces in p ⁿ . These ruled surfaces will be called incidence scrolls and such a set will be the base of the incidence scroll. Unless otherwise stated, we assume that the base spaces are in general position. Received: 1 December 2000     

Convergence of Rational Interpolants with Preassigned Poles

Let Ω be a domain in the extended complex plane such that ∞∈Ω . Further, let K= C / Ω and, for each n , let Q _n be a monic polynomial of degree n with all its zeros in K . This paper is concerned with whether (Q _n ) can be chosen so that, if f is any holomorphic function on Ω and P _n is the polynomial part of the Laurent expansion of Q _n f at ∞ , then (P _n /Q _n ) converges to f locally uniformly on Ω . It is shown that such a sequence (Q _n ) can be chosen if and only if either K has zero logarithmic capacity or Ω is regular. January 21, 1999. Date accepted: August 17, 1999.     

Asymptotic Uniqueness of Best Rational Approximants of Given Degree to Markov Functions in L 2 of the Circle

We improve over a sufficient condition given in [8] for uniqueness of a nondegenerate critical point in best rational approximation of prescribed degree over the conjugate-symmetric Hardy space of the complement of the disk. The improved condition connects to error estimates in AAK approximation, and is necessary and sufficient when the function to be approximated is of Markov type. For Markov functions whose defining measure satisfies the Szego condition, we combine what precedes with sharp asymptotics in multipoint Padé approximation from [43], [40] in order to prove uniqueness of a critical point when the degree of the approximant goes large. This lends perspective to the uniqueness issue for more general classes of functions defined through Cauchy integrals.     

XPS and TDS study of CO interaction with Pd–AlOx systems

The metal–substrate and metal–metal interactions (MSI, MMI) represent important effects determining the properties of supported catalysts, gas sensors and gettering alloys. We investigated the MSI and MMI effects by the X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption (TPD) in the case of Pd films deposited on Al₂O₃ and Al substrates. The study shows that the particle-size dependent metal–substrate interaction plays an important role in CO–Pd chemisorption, namely, in the case of “aluminium rich” Pd–aluminium oxide interface. CO chemisorption exhibits a low-temperature desorption feature at 360 K characteristic for Pd–Al and very small Pd particles. The MSI is explained by the formation of a Pd–Al intermetallic interface exhibiting a strong bimetallic Pd–Al interaction.     

Ti—MCM—41的结构特征与芳烃羟化反应的化学亲和选择性

以不同硅源合成了Si/Ti比不同的Si-Ti－MCM－41,并在引入Ti的同时引入Al,合成了Si/Al比不同的Si-Ti-Al-MCM-41。XRD、TEM、低温N2吸附的表征结果说明,Ti-MCM-41具有长程有序一维孔道,且比表面积较高,FT－IR光谱表征说明,Ti对骨架Si的取代使MCM－41表面出现缺陷羟基。Al的引入有利于Ti-MCM-41有序结构的形成。且可调变Ti-MCM-41的表面性质。Ti-MCM-41在不同极性芳烃化合物的羟化过程中表现出化学亲和选择性,且调变Ti-MCM-41的表面性质可实现对化学亲和选择性的控制。