Using the recently suggested method of processing the data on external quantum efficiency as a function of output optical power, we have estimated the dependence of light extraction efficiency of high‐power light‐emitting diodes (LEDs) on their emission wavelength varied between 425 nm and 540 nm. The extraction efficiency is found to increase with the wavelength from ～80% to ～85% in this spectral range and to correlate with the wavelength dependence of reflectivity of the large‐area p‐electrode being the essential unit of the LED chip design. The correlation found identifies the incomplete reflection of emitted light from the electrode as the major mechanism eventually controlling the spectral dependence of the efficiency of light extraction from the LEDs.
The combination of a direct aqueous supercritical fluid extraction system interfaced to a fixed wavelength infrared detector; measuring CH2 (νasymmetric) absorbance at 2930 cm?1, has been successfully developed for the analysis of oil-in-water. Using an optional, in-line silica gel treatment procedure, method accuracy for determining Brent Delta crude oil in spiked 500 mL water samples was 92.0% to 94.5% with RSD 4.7% to 6.5%. The supercritical fluid extraction-infrared method enables a second analysis of the same water sample without silica gel treatment. For second sets of analyses without silica gel treatment, method accuracy for determining Brent Delta crude oil in spiked 500 mL water samples was 87% to 96.0% with RSD 7.5% to 9.5%. Results of this study indicate that the silica gel treatment procedure reduces the calculated level of Brent Delta crude oil-in-water by 6.6–12.4% relative to samples analysed without silica gel treatment. The results of a study involving Fourier transform infrared spectroscopy indicate a limit of detection for n-decane of approximately 0.5 mg L?1 by measuring CH2 (νasymmetric) absorbance using the supercritical fluid extraction-infrared method. Sample preparation using direct aqueous supercritical fluid carbon dioxide extraction provides an indefinite means for the use of infrared techniques to measure oil-in-water. 相似文献
We report high‐power frequency conversion of a Yb‐doped fiber laser using a double‐pass pumped external‐cavity diamond Raman oscillator. Pumping with circular polarization is shown to be efficient while facilitating high‐power optical isolation between the pump and Raman laser. We achieved continuous‐wave average power of 154 W with a conversion efficiency of 50.5% limited by backward‐amplified light in the fiber laser. In order to prove further scalability, we achieved a maximum steady‐state Raman‐shifted output of 381 W with 61% conversion efficiency and excellent beam quality using 10 ms pump pulses, approximately a thousand times longer than the transient thermal time‐constant. No power saturation or degradation in beam quality is observed. The results challenge the present understanding of heat deposition in Raman crystals and foreshadow prospects for reduced thermal effects in diamond than originally anticipated. We also report the first experimental evidence for stimulated Brillouin scattering in diamond.
Wide‐angle, polarization‐independent structural reflective colors from both directions based on a one‐dimensional photonic crystal are demonstrated. Our device produces a distinct and saturated color with high angular tolerant performance up to ±70° for any polarization state of an incident light wave, which is highly desirable for a broad range of research areas. Moreover, the purity of the color and luminous intensity of the proposed device are improved as compared to conventional colorant‐based color filters and colloidal glasses. The present approach may have the potential to replace existing color filters and pigments and pave the way for various applications, including color displays and image sensor technologies.
Periodic structures with a sub‐wavelength pitch have been known since Hertz conducted his first experiments on the polarization of electromagnetic waves. While the use of these structures in waveguide optics was proposed in the 1990s, it has been with the more recent developments of silicon photonics and high‐precision lithography techniques that sub‐wavelength structures have found widespread application in the field of photonics. This review first provides an introduction to the physics of sub‐wavelength structures. An overview of the applications of sub‐wavelength structures is then given including: anti‐reflective coatings, polarization rotators, high‐efficiency fiber–chip couplers, spectrometers, high‐reflectivity mirrors, athermal waveguides, multimode interference couplers, and dispersion engineered, ultra‐broadband waveguide couplers among others. Particular attention is paid to providing insight into the design strategies for these devices. The concluding remarks provide an outlook on the future development of sub‐wavelength structures and their impact in photonics.
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