火焰原子吸收光谱法间接测定钢中硼量

在弱酸介质中,硼、苯羟乙酸和[Fe(Phen)3]2+(phen:邻二氮菲)缔合生成具有较大疏水基团的化合物,用1,2-二氯乙烷萃取,再用去离子水反萃取,再用火焰原子吸收光谱法测定水相中铁,由此间接测定硼的含量.硼的质量浓度在0.05～3.24 mg·L-1范围内呈线性,方法检出限(3S/N)为0.036 mg·L-1.应用此方法测定了硼钢标准样品中硼含量,测得结果与已知值相符.     

X-Ray Emission from Zr, Mo, In and Pb Targets Bombarded by Slow Highly Charged Ar^q＋（q = 13, 14, 15, 16） Ions

We study the L x-ray emission from Zr, Mo and In targets and M x-ray emission from Pb target under bombardment of low energy Ar^q (q = 13, 14, 15, 16) ions. The relative x-ray yields were measured in the projectile kinetic energy range 210-360 keV. It is found that the relative x-ray yields from Zr, Mo and Pb targets increase with the increasing projectile kinetic energy for Ar^14 and Ar^16 projectiles and depend on the potential energy of the projectile remarkably.     

草酸铜原位催化高氯酸铵热分解的研究

通过TG-DTA-MS联用技术研究了草酸铜对高氯酸铵的催化过程。研究发现,草酸铜分解生成的氧化铜对高氯酸铵有较强的催化作用,添加2%的草酸铜使高氯酸铵的高温分解温度提前112℃。分解的气相产物主要有H2O,NH3,O2,HCl,Cl2,HNO,NO,N2O和NO2。在草酸铜原位分解生成的CuO表面吸附生成氧的过氧化离子(O2-)和氧离子(O-,O2-)是加速AP热分解反应的主要原因。     

Y2O3∶C陶瓷的发光性能

采用传统陶瓷制备工艺制备了C掺杂的Y₂O₃多晶陶瓷;研究了Y₂O₃∶C陶瓷的光谱性能,发现在403 nm有明显的发射峰。通过对其激发光谱的研究,表明它们是由F⁺和F色心造成的。本文还研究了Y₂O₃∶C陶瓷的热释光和光释光性能。用2个指数衰变函数拟合光衰变曲线得到的衰变时间常数τ₁=(4.66±0.27)s,τ₂=(23.31±1.03) s。     

一维链状锰配位聚合物[Mn(1,5-nds)(Him)_4]_n的合成、晶体结构及热稳定性研究(英文)

The synthesis,structural characterization and thermal behavior of a novel one-dimensional manganese (Ⅱ) complex of formula [Mn(1,5-nds)(Him)4]n [1,5-nds=naphthalene-1,5-disulfonate,Him=imidazole] is reported.The complex crystallizes in the triclinic system,space group P1,with a=0.835 42(13) nm,b=0.983 45(18) nm,c= 0.987 42(19) nm,α=60.523 0(10)°,β=97.748(2)°,γ=87.189(2)° and Z=2.The 1,5-nds ligand assumes the μ2 coordination mode and interlinks Mn(Ⅱ) ions into infinite one-dimensional chain structure along [111] direction,with the adjacent Mn…Mn distance being 1.144 99(12) nm.The chains are assembled into a three-dimensional supramolecular architecture via hydrogen bonds and C-H…π interactions.IR spectra and thermal analysis data are in agreement with the crystal structure.     

用于疾病诊断的Gd~Ⅲ/量子点多模态成像探针的构建

结合核磁共振成像(MRI)和荧光成像技术,以钆离子、近红外低毒量子点、二氧化硅和聚丙烯酸(PAA)等为原料,采用一系列纳米载体自组装技术,构建出MRI弛豫率/荧光效率高和生物相容性好的GdⅢ/量子点多模态纳米探针.结果表明,与未螯合GdⅢ的量子点纳米探针相比,GdⅢ/量子点多模态纳米探针具有更高的弛豫率;t1-加权MRI成像也证实了GdⅢ/量子点多模态纳米探针具有很好的阳性造影功效.     

Synthesis and Structure of a Cp^＊Ir Half-sandwich Complex Containing Azido and Bis（diphenylthiophosphoryl）amide Ligands

The title complex [CpIr{N(Ph2PS)2}(N3)](N(Ph2PS)2=bis(diphenylthiophosphoryl)amide,Cp=pentamethylcyclopentadienyl) has been prepared and characterized by X-ray diffraction analysis.It crystallizes in monoclinic,space group P21/n with a=11.6946(1),b=18.9273(2),c=15.7859(1),β=105.731(1)°,V=3363.29(5)3,Z=4,Mr=817.92,Dc=1.615g/cm3,μ(MoKα)=4.219 mm-1,F(000)=1624,S=1.028,the final R=0.0355 and wR=0.0848 for 5987 observed reflections with Ⅰ 2σ(Ⅰ) and 363 variables.The molecular structure of 1 consists of discrete monomeric molecule with a distorted octahedral configuration around the iridium atom,having a Cp ring at one face and bonded with a chelating bis(diphenylthiophosphoryl)amide group as well as a terminal azido ligand.The average Ir-S and Ir-N bond lengths are 2.416(1) and 2.121(5),respectively.     

巯基修饰单链DNA在纳米金薄膜电极上自组装、杂交和取向的电化学交流阻抗谱

利用电化学交流阻抗技术对SH-ssDNA在纳米金薄膜电极表面的自组装、杂交和取向进行了系统表征。 探讨了SH-ssDNA的组装时间、浓度和链长对其自组装的影响,自组装15 h时电荷传递电阻Rct最大,表面覆盖率最高;研究了SH-ssDNA的浓度、链长以及与互补DNA的杂交方式对杂交反应的影响。 结果发现,随着单链浓度的增加,杂交后R_ct的变化值逐渐降低,当SH-ssDNA为5 μmol/L时Rct值比杂交前增加了16%。 通过对阻抗谱数据模拟和分析,表明SH-ssDNA以垂直竖立取向在金电极表面形成均匀致密单分子层,杂交效率与SH-ssDNA的覆盖率密切相关。     

双波长高精度红外测温仪

利用双波长红外测温方法,通过黑体红外辐射曲线中双波长等比吸收的原理消除了由于辐射环境中水蒸气等外界吸收原因造成的单波长红外测温仪中的测量误差,实现更稳定的高精度红外测温.该方法绕开了传统红外测温方法中"辐射率修正困难"的问题.同时利用此红外测温仪器改进了金属钨电子逸出功测量实验.