纳米Al2O3掺杂对Ce0.8Y0.2O2-δ晶界离子电导的影响

纳米Al2O3掺杂对Ce0.8Y0.2O2-δ晶界离子电导的影响;固体电解质;晶界离子电导率     

电中性分子间相互作用分析的毛细管电泳方法研究

使用具有负有效淌度的十二烷基磺酸钠胶束赋予中性分子有效淌度,以中性主体分子18-冠-6和中性客体分子对-硝基苯胺形成中性超分子包结化合物为实例,建立了中性分子相互作用的毛细管电泳分析方法,发现对-硝基苯胺和18-冠-6与SDS的相互作用存在相当的差异.测得18-冠-6和对-硝基苯胺的lgK为4.14,18-冠-6与2-氨基吡啶、18-冠-6与SDS以及SDS与2-氨基吡啶的lgK分别为3.65,3.13和1.15.     

瑶药长柄瓜馥木的化学成分及抗痛风作用的网络药理学

对瑶药长柄瓜馥木Fissistigma oldhamii var.longistipitatum的化学成分进行分离鉴定，同时运用网络药理学研究其抗痛风的多成分、多靶标、多途径作用机制。采用硅胶、Sephadex LH-20、ODS等多种柱色谱以及制备型HPLC等现代分离技术对长柄瓜馥木化学成分进行分离纯化，根据其理化性质、NMR波谱技术进行结构鉴定；并对分离得到的化学成分进行生物信息学手段分析。从长柄瓜馥木中分离得到18个化合物，结构鉴定为：鹅掌楸碱(1)、氧代克列班宁(2),oxobuxifolina(3),观音莲明碱(4),O-甲基芒籽碱(5),芒籽香碱(6),4,5-Dioxodehydroasimilobine(7),缺碳金线吊乌龟二酮B(8),胡椒内酰胺A(9),胡椒内酰胺C(10),马兜铃内酰胺AIa(11),马兜铃内酰胺Allla(12),goniothalactam(13),goniopedaline(14),马兜铃内酰胺BⅢ(15),5,6,7,8-四甲氧基黄酮(16),5,8-二羟基-6,7-二甲氧基黄酮(17),Methylpedicin(18)。网络药理学研究分析发现长柄瓜馥木可能通过5,8-二羟基-6,7-二甲氧基黄酮、goniothalactam、5,6,7,8-四甲氧基黄酮、观音莲明碱等活性成分，作用于GAPDH、白介素-6(IL-6)、VEGFA、MAPK1、SRC等靶点，调节TNF通路、Toll样受体通路、PI3K-Akt通路等信号通路发挥抗痛风作用。     

三点弯曲试样幂硬化材料裂纹撕裂扩展的实验研究

本文应用三点弯曲试样和撕裂模量理论对弹塑性裂纹撕裂扩展的稳定性进行了实验研究,得出了适用于三点弯曲试样的施加撕裂模量T_(app)的计算公式。结果说明了材料硬化和系统柔度等因素对裂纹扩展稳定性的影响。实验中采用多层高柔度组合梁系统,得到了随加载系统柔度增加,裂纹扩展从慢稳定到失稳发展的过程。证明了撕裂模量理论的有效性。实验结果与理论预测相符。     

韧性材料J_R阻力曲线受试样尺寸因素影响的实验研究

本文应用不同尺寸的三点弯曲试样和带边侧槽试样,用实验方法研究了启裂J积分(J_(1C))和J_R阻力曲线的斜率(dJ/da)受试样尺寸的影响。结果表明,在满足GB2038-80所规定的试样尺寸要求的条件下,J_(1C)值受试样尺寸影响不大,但DJ/da值受试样尺寸影响较大。因此,在应用以J_R曲线理论为基础的裂纹扩展稳定性评定方法时,如撕裂模量理论及EPRI方法,要应用较大尺寸试样或带侧槽试样来测定J_R阻力曲线。     

Effect of f-c hybridization on the $\gamma\to \alpha$ phase transition of cerium studied by lanthanum doping

The hybridization between the localized 4f level (f) with conduction (c) electrons in $\gamma $-Ce upon cooling has been previously revealed in single crystalline thin films experimentally and theoretically, whereas its influence on the $\gamma \to \alpha $ phase transition was not explicitly verified, due to the fact that the phase transition happened in the bulk-layer, leaving the surface in the $\gamma $ phase. Here in our work, we circumvent this issue by investigating the effect of alloying addition of La on Ce, by means of crystal structure, electronic transport and angle resolved photoemission spectroscopy measurements, together with a phenomenological periodic Anderson model and a modified Anderson impurity model. Our current researches indicate that the weakening of f-c hybridization is the major factor in the suppression of $\gamma \to \alpha $ phase transition by La doping. The consistency of our results with the effects of other rare earth and actinide alloying additions on the $\gamma \to \alpha $ phase transition of Ce is also discussed. Our work demonstrates the importance of the interaction between f and c electrons in understanding the unconventional phase transition in Ce, which is intuitive for further researches on other rare earth and actinide metals and alloys with similar phase transition behaviors.     

层叠Blumlein纳秒脉冲形成线设计与实验

研究了一种结构紧凑型的多级层叠Blumlein纳秒脉冲形成线,从理论上分析了放电时回路各分布参数对层叠Blumlein脉冲形成线输出电压的影响,并利用PSpice模拟验证了各分布参数对层叠Blumlein脉冲形成线输出结果的影响,发现开关的导通电阻是制约输出电压幅值的主要因素,开关的分布电感对输出波形的影响大于负载分布电感的影响,基于时域有限差分法原理,利用XFDTD软件模拟了两级层叠Blumlein线的电磁耦合效应。开展了多级层叠Blumlein脉冲形成线实验,结果表明,基于陶瓷固态传输线和GaAs光导开关的层叠Blumlein脉冲形成线能够实现输出电压叠加,可用于产生ns量级脉宽的脉冲高压。     

Chaos generation by a hybrid integrated chaotic semiconductor laser

We design a hybrid integrated chaotic semiconductor laser with short-cavity optical feedback. It can be assembled in a commercial butterfly shell with just three micro-lenses. One of them is coated by a transflective film to provide the optical feedback for chaos generation while insuring regular laser transmission. We prove the feasibility of the chaos generation in this compact structure and provide critical external parameters for the fabrication by theoretical simulations. Rather than the usual changeless internal parameters used in previous simulation research, we extract the real parameters of the chip by experiment. Moreover, the maps of the largest Lyapunov exponent with varying bias current and feedback intensity K_(ap) demonstrate the dynamic characteristics under different external-cavity conditions. Each laser chip has its own optimal external cavity length(L) and feedback intensity(K_(ap)) to generate chaos because of the different internal parameters. We have acquired two ranges of optimal parameters(L = 4 mm, 0.12 K_(ap) 0.2 and L = 5 mm, 0.07 K_(ap) 0.12) for two different chips.     

激光触发能量对横向结构4H-SiC光导开关导通电阻的影响

采用钒掺杂半绝缘4H-SiC衬底,利用磁控溅射在硅衬底上制备了Ni/Au金属电极,并封装加工成同面型横向电极结构SiC光导开关,研究了不同激光触发能量对光导开关光电响应及导通电阻的影响。用波长532nm的激光作为触发源,当激光触发能量从26.7mJ增加到43.9mJ时,光导开关的导通电阻从295Ω降低到197Ω。利用复合理论推导出激光触发时导带中载流子浓度随时间的变化规律,并利用MATLAB模拟计算了不同触发能量下开关的导通电阻,得到了与实验较一致的结果。在此基础上,提出了降低开关导通电阻的两种途径。     

取向晶种法制备沸石分子筛膜研究进展

近年来沸石分子筛膜因在分离、 催化、 传感和防腐等研究领域具有重要的应用价值而引起广泛关注. 其中, 具有优先取向微观结构的沸石分子筛膜由于能够显著降低客体分子在膜内的扩散路径并减少膜内的晶间界缺陷密度, 成为膜分离学科的研究重点. 本文以b-轴取向MFI沸石分子筛膜为主线, 综述了国内外制备取向沸石分子筛膜的最新研究进展; 详细介绍了取向晶种法制膜工艺, 侧重总结了MFI沸石纳米片合成、 b-轴取向沸石晶种单层制备以及二次生长调控等方面的研究成果; 在深入探讨各类取向沸石分子筛膜制备策略的基础上, 分析探讨了其中存在的关键问题与解决措施, 最后对取向沸石分子筛膜的发展方向进行了展望.