Al2O3/SnO2 Co-Nanoparticle Modified Grafted Collagen for Improving Thermal Stability and Infrared Emissivity

Al2O3/SnO2 co-nanoparticles were prepared with a modified sol-gel technique followed by a thermal treatment process. With these co-nanoparticles the grafted collagen-Al2O3/SnO2 nanocomposites were obtained using a supersonic dispersion method. X-ray diffraction, FT-IR analysis, transmission electron microscopy, TGA/DTA and infrared emissivity test were performed to characterize the resulting nanoparticles and nanocomposites, respectively. The Al2O3/SnO2 co-nanoparticles showed a narrow distribution of size between 20-40 nm and could be uniformly absorbed on the tri-helix scaffolds of the grafted collagen without any aggregation. The nanocomposites possessed better thermal stability and substantially lower infrared emissivity than the grafted collagen and Al2O3/SnO2 co-nanoparticles with an increase of degradation temperature from 39 to 210 ℃ and a decrease of infrared emissivity from 0.850 of the grafted collagen and 0.708 of the Al2O3/SnO2 co-nanoparticles to 0.424, which provided a potential application of the nanocomposites to areas such as photoelectronics.     

Sn自溶剂含量对Al掺杂Ⅷ型Sn基单晶笼合物电传输特性的影响

通过Sn自熔剂法制备了Al掺杂Ⅷ型Sn基单晶笼合物Ba8Ga10Al6Snx(x=40,50,60;Sn40,Sn50,Sn60),并研究Ba8Ga10Al6Snx单晶笼合物的结构和电传输特性对自熔剂Sn初始含量的依赖性.结果表明,Al的实际含量随Sn自熔剂含量的增加而基本保持不变,说明Sn的起始含量对Al在该笼合物中固溶度的影响较小;室温下Sn60样品的载流子浓度较高,这可能是因Al在笼合物Ga8 Ga16Sn30中的占位不同而导致费米能级附近能带色散关系发生变化所引起;另一方面,在300～600 K的温度范围内,获得较高功率因子的是Sn初始含量为50的样品,在488 K处获得最大值1.82×10-3 W·m-1·K-2;获得较低功率因子的是Sn初始含量为40的样品,而功率因子较低主要是由于该样品电导率较低.     

差动光程差倍增法测量微小位移

基于差动光程差倍增法将微小位移转化为多倍光程差,通过电桥光电转换电路,得到干涉条纹数的变化.采用差动干涉方法,提高了光程改变量与位移量的比例,使微小位移的测量精度提高到亚微米量级.     

Structural and Thermodynamic Properties of M3W3N （M=Fe,Co, Ni）

Ternary transition metal nitrides, Fe3 W3N, Coa W3N, and Nia WaN~ are studied by the use of interatomic potentials acquired from lattice inversion. The study indicates that Fe3 WaN would be more stable than the other compounds in the family of intermetallic tungsten nitrides. The investigation of phonon density of states indi- cates that the lower frequency modes are mostly excited by the metal atoms, and the higher frequency modes are mostly excited by the nitrogen atoms. A qualitative analysis is carried out with the relevant potentials for the phase stability and vibrational modes.     

Monitoring of the ducting by a ground-based GPS receiver

In this paper, we describe the estimation of low-altitude refractivity structure from simulation and real ground-based GPS delays. The vertical structure of the refractive environment is modeled using three parameters, i.e., duct height, duct thickness, and duct slope. The refractivity model is implemented with a priori constraints on the duct height, thickness, and strength, which might be derived from soundings or numerical weather-prediction models. A ray propagation model maps the refractivity structure into a replica field. Replica fields are compared with the simulation observed data using a squared-error objective function. A global search for the three environmental parameters is performed using genetic algorithm. The inversion is assessed by comparing the refractivity profiles from the radiosondes to those estimated. This technique could provide near-real-time estimation of ducting effect. The results suggest that ground-based GPS provides significant atmospheric refractivity information, despite certain fundamental limitations of ground-based measurements. Radiosondes typically are launched just a few times daily. Consequently, estimates of temporally and spatially varying refractivity that assimilate GPS delays could substantially improve over-estimates using radiosonde data alone.     

Tuning of the periodicity of stable self-organized metallic templates

The atomic and electronic structures of Pb bilayer/Pt(111) are investigated with two theoretical calculations.We find that the stable (2 × 2)/(3 × 3) Pb/Pt(111) structure is a promising candidate for being used as a template with self-organized ordered Pb semi-cluster array on the first Pb monolayer.This stable structure can realize the ordered Au single-atom array around the Pb semi-clusters that can cause selective adsorption of noble atoms.The size of Pb magic number semi-cluster plays a more important role in determining the periodicity of the template than the lattice constant misfit between the substrate and the overlayer.This leads to quite a different periodicity between the two stable templates,which are (2 × 2)/(3 × 3) Pb/Pt(111) and Pb/Cu(111).Therefore,by considering the size of the stable semi-clusters and carefully selecting different substrate materials,we can tune the density of Pb semi-clusters as the nucleation points and then tune the periodicity of the stable template.     

基于流动损失权重分配的扩压叶栅弯叶片优化探究

本文采用经过实验校核过的数值模拟方法研究了CDA叶型的矩形扩压叶栅旋涡结构与流动损失之间的权重关系,并以此为指导进行叶片周向弯曲优化设计,改善叶栅气动性能.结果表明:原始叶栅中集中脱落涡所影响区域的总压损失权重占总损失的60%,并通过对该旋涡结构所对应的分离区域的拓扑分析确定了叶片周向弯曲的弯高、积叠线控制点和弯角数值.叶片周向弯曲的作用将该分离区从角区闭式分离转变为开式分离,同时降低叶片根部负荷,改变横向和径向压力梯度分布.优化叶栅降低了集中脱落涡所占的总压损失权重41.3%,最终降低了出口截面质量流量平均的总压损失系数2.55%。基于旋涡结构的流动损失分配权重分析方法有效地提升了叶栅气动性能,大大地缩短了叶栅流场优化设计周期,据有可观的工程应用前景。     

泡沫镍耦合金纳米结构增强拉曼散射

采用一种简易的化学置换反应方法在泡沫镍基底上生长花针状的金纳米结构,并将其作为表面增强拉曼散射（SERS）基底,主要研究置换时间对SERS基底性能的影响。采用COMSOL Multiphysics仿真软件对金纳米粒子高度分别为100,150,175,200 nm的基底进行电磁增强仿真,得到最大电场强度分别为20.112,29.060,24.766,21.382 V/m,计算得到增强因子分别为1.64×10⁵、7.13×10⁵、3.76×10⁵和2.09×10⁵。使用罗丹明6G（R6G）溶液作为探针分子,对不同置换时间下的泡沫镍镀金基底进行拉曼表征、检测极限测试以及拉曼mapping测试。测试结果表明,置换时间为10 min的基底增强效果是最佳的,对R6G分子的检测浓度可以达到10^-8 mol·L^-1,在613,774,1364 cm^-1这三个R6G分子的拉曼位移特征峰处的相对标准偏差值分别为11.3%、10.9%和11.9%,说明基底...     

轻质夹层材料的制备和振动声学性能

轻质夹层材料被广泛地用来制备动车组车体和飞机的机身,其结构设计面临着一系列挑战:即同时要求质量轻、力学强度高、散热性能好、动力学性能和隔声性能可调等多功能特性.针对动车组高速运行和飞机飞行过程中经常面临的振动及噪声问题,以及如何在现有的材料和结构基础上进一步减轻重量并获得更优良的综合性能是材料制备、固体力学、流体力学、声学、智能材料和结构、优化设计等诸多领域工作者面临的共同挑战.结合近年来围绕"超轻多孔结构创新构型的多功能化基础研究"国家基础研究计划项目所开展的一系列工作,综述了有关轻质三明治材料及结构振动和声学特性的国内外研究进展及现状,以及相应的主被动控制技术;针对目前存在的问题,讨论并展望了有关轻质材料和结构动力学性能及隔声性能的研究发展趋势.     

负载生物活性功能基聚醚氨酯的表面自由能与表面血液相容性研究

水相接触角;负载生物活性功能基聚醚氨酯的表面自由能与表面血液相容性研究