Electronic and optical properties of 3N-doped graphdiyne/MoS2 heterostructures tuned by biaxial strain and external electric field

The construction of van der Waals (vdW) heterostructures by stacking different two-dimensional layered materials have been recognised as an effective strategy to obtain the desired properties. The 3N-doped graphdiyne (N-GY) has been successfully synthesized in the laboratory. It could be assembled into a supercapacitor and can be used for tensile energy storage. However, the flat band and wide forbidden bands could hinder its application of N-GY layer in optoelectronic and nanoelectronic devices. In order to extend the application of N-GY layer in electronic devices, MoS₂ was selected to construct an N-GY/MoS₂ heterostructure due to its good electronic and optical properties. The N-GY/MoS₂ heterostructure has an optical absorption range from the visible to ultraviolet with a absorption coefficient of 10⁵ cm^-1. The N-GY/MoS₂ heterostructure exhibits a type-Ⅱ band alignment allows the electron-hole to be located on N-GY and MoS₂ respectively, which can further reduce the electron-hole complexation to increase exciton lifetime. The power conversion efficiency of N-GY/MoS₂ heterostructure is up to 17.77%, indicating it is a promising candidate material for solar cells. In addition, the external electric field and biaxial strain could effectively tune the electronic structure. Our results provide a theoretical support for the design and application of N-GY/MoS₂ vdW heterostructures in semiconductor sensors and photovoltaic devices.     

Reference-frame-independent quantum key distribution of wavelength division multiplexing with multiple quantum channels

Reference-frame-independent quantum key distribution (RFI-QKD) can allow a quantum key distribution system to obtain the ideal key rate and transmission distance without reference system calibration, which has attracted much attention. Here, we propose an RFI-QKD protocol based on wavelength division multiplexing (WDM) considering finite-key analysis and crosstalk. The finite-key bound for RFI-QKD with decoy states is derived under the crosstalk of WDM. The resulting secret key rate of RFI-QKD, which is more rigorous, is obtained. Simulation results reveal that the secret key rate of RFI-QKD based on WDM is affected by the multiplexing channel number, as well as crosstalk between adjacent channels.     

部分均匀荷载作用下圆板塑性极限统一解

本文采用俞茂宏双剪统一屈服准则求解部分均匀荷载下简支圆板的塑性极限，已有的最大主应力准则、Ｔｒｅｓｃａ准则，Ｍｉｓｅｓ准则的解答均是该解答的特例或线性逼近。该解答可以适合于多种工程材料，具有普遍性和适用性，从得出的解析解和图示中可得出一些新的有益的认识     

振动时效的动应力判据

采用多元非线性回归分析方法，求得振动时效试验中动应力σｄ，载荷次数ｎ和残余应力当量ｋ对消应力效果εｖ的经验方程。从而实现用动应力现场速测来定量评定振动时效工艺效果。本文主要介绍动应力判据方程的建立方法及其应用。     

压电液相免疫传感信号放大技术研究进展

本文简要介绍了压电液相生物传感器的理论基础,并对近年来压电液相免疫传感技术中所采用的质量效应信号放大技术和非质量效应信号放大技术的研究进展作系统综合评述。引用文献46篇。     

天然黄酮类化合物清除羟基自由基的活性研究

采用分光光度法测定了黑沙蒿中黄酮类化合物清除羟基自由基的能力,以IC50值作为评价指标,初步探讨了黄酮类化合物清除羟基自由基的活性与结构之间的关系,为开发利用黑沙蒿提供了科学依据.     

酚醛树脂层压基板真空热裂解产物分析表征

利用程序升温的热解炉反应器对酚醛树脂层压基板进行真空热裂解,通过元素分析、傅里叶红外(FT-IR)分析和气相色谱-质谱(GC-MS)分析,对原料及产物油成分进行了表征。研究表明,热解油上层清液主要是一些较易溶于水的物质,如苯酚、甲酚、二甲酚、糖类、乙内酰脲类、吗啉类、吡喃酮类和吡啶类化合物等;而下层沉淀则主要为不溶或难溶于水的物质,如大取代基酚类(取代基碳原子数≥2)、磷酸三芳基酯类、脂肪酸酯类和腈类化合物等。其中,三聚氰胺在上层清液和下层沉淀中都有较高的含量。     

红外光谱结合线阵列检测技术研究聚合物分散液晶膜分子取向

采用偏振红外光谱和变温红外光谱研究聚合物分散液晶膜中液晶分子取向随外加电场及温度的变化.利用线阵列检测技术表征了聚合物与液晶界面处的成分分布.结果表明,线阵列检测技术能够快速而直观地给出成分分布图,通过该成分分布图可以解释PDLC在温度场作用下分子取向的变化.     

真空蒸馏预富集-电感耦合等离子体发射光谱法测定铂

建立了真空蒸馏预富集-电感耦合等离子体发射光谱法测定铅试样中微量铂的方法.在真空条件下,利用Pb和Pt在较高温度下蒸汽压的差别进行分离,富集后的铂溶解制成溶液后进行电感耦合等离子体发射光谱检测,实现了真空密闭回收铅.针对试样的特点,对真空蒸馏方法理论上的可行性进行研究.结果表明:在蒸馏温度为1250 K,真空度为30 Pa,蒸馏时间为3 h条件下,铂的富集分离效果最好,可富集至99.01%以上.线性范围为0.023～20 mg/L,检出限(3σ)为0.0069 mg/L,对样品测定的相对标准偏差为1.7%(n=6).用本方法对样品中加入的铂标准溶液进行了测定,回收率为99.8%～103.0%.本方法简便快速、无污染,已应用于废电路板贵金属冶余物料中铂的测定.     

基于多种小波分解方法综合判决的低误报率分布式光纤围栏入侵监测系统

针对相位敏感光时域反射计型分布式光纤围栏入侵监测系统对外界干扰敏感、误报率高的问题进行了深入研究,比较了多种小波提取入侵信号突变特征方法,并提出一种基于多个小波分解结果进行综合判决来降低分布式光纤围栏误报率的方法.实验结果表明,多种小波分解可以分别提取不同层次的突变细节信息,为综合决策提供更完备的信息和条件,比单一判决...