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81.
Alexander Čeklovský Juraj Bujdák Adriana Czímerová Nobuo Iyi 《Central European Journal of Physics》2007,5(2):236-243
Tetracationic porphyrin dyes TMPyP and ZnPyP were intercalated into hydrophobized layered silicate films of three smectites.
The smectites represented the layered silicate specimens of high (Fluorohectorite, Corning; FHT), medium (Kunipia F montmorillonite;
KF) and low layer charge (Laponite, Laporte; LAP). The molecular orientations of the dye cations were studied by means of
linearly-polarized ultraviolet-visible (UV-VIS) spectroscopy. The spectral analysis and consequent calculations of tilting
angles of the transition moments at the wavelengths of Soret band transitions were in the range of 25°-35°. The determined
angles indicated molecular orientation of the dye cations being almost parallel to the surface of the silicates. Slightly
higher values (above 35°), determined for a FHT film, indicated either a slightly tilted orientation of the dye cations or
the change of molecular comformation after the intercalation of the dye.
Presented at 5-th International Conference Solid State Surfaces and Interfaces, November 19–24, 2006, Smolenice Castle, Slovakia 相似文献
82.
V. Banerjee 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,60(4):493-498
This paper addresses the issues of scaling and self-similarity in typical
nanoparticle films. The role played by microscopic processes contributing to
growth on these issues is probed. While we perform this investigation for a
specific system viz., Pb1-xFexS nanoparticle films for clarity of the
procedures, the analysis is general and can be applied to a variety of systems
obtained using different deposition techniques. 相似文献
83.
The watermiscible room temperature ionic liquid 1butyl3methylimidazolium tetrafluorob orate ([bmim] [BF4]) is a model system for studying the interactions between ionic liquid and water molecules. In this work the orientational structure of the low concentrated aqueous solution of [bmim] [BF4] at the air/liquid interface was investigated by sum frequency gener ation vibrational spectroscopy. It has been found that at very low concentrations, the butyl chain exhibited a significant gauche defect, indicating a disordered conformation; and the cation ring oriented with a fairly small tilting angle at the surface. When the concentration increased, the cation ring tended to lie flat at the surface, and the gauche defects of the butyl chain decreased due to the intermolecular chainchain interactions and the consequent more ordered interfacial molecular arrangement. Additionally, the antisymmetric stretching mode in the PPP and SPS spectra exhibited a peak shift, showing that there exists more than one kind of orientation or chemical environment for the butyl CH3 group. These results may shed new light on understanding the surface behavior of watermiscible ionic liquids as well as the imidazolium based surfactants. 相似文献
84.
Alexander Ryabchun Alexey Bobrovsky Alexey Medvedev Valery Shibaev 《Journal of polymer science. Part A, Polymer chemistry》2011,49(3):625-633
A series of novel crown ether‐containing photochromic comb‐shaped liquid crystalline polyacrylates with different macromolecular structure of side groups were synthesized and investigated. Phase behavior, optical and photo‐optical properties of thin spin‐coated films of these polymers were studied. A special attention was paid to a comparative study of the photo‐orientation phenomena occurring in the polymer films under a polarized light action. It was shown that complex formation with the potassium ions results in the decrease in degree of the photoinduced order that can be used for the creation of new materials for sensor devices. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
85.
Matt Mackey Lionel Flandin Anne Hiltner Eric Baer 《Journal of Polymer Science.Polymer Physics》2011,49(24):1750-1761
Layer‐multiplying coextrusion was used in conjunction with isothermal recrystallization to study the confined crystallization of polyvinylidene fluoride (PVDF) and polyvinylidene fluoride‐tetrafluoroethylene (PVDF‐TFE) using polycarbonate (PC) and polysulfone (PSF) as confining materials. Three layered systems were produced (PC/PVDF, PSF/PVDF, and PC/PVDF‐TFE) with layer thicknesses ranging from 525 to 28 nm. The crystal morphology was affected by both layer thickness and recrystallization temperature. Specifically, increased recrystallization temperature and decreased layer thickness facilitated the formation of high aspect ratio in‐plane crystals in both PVDF based polymers. On the other side of the spectrum, thicker layers and lower recrystallization temperatures produced on‐edge PVDF crystals and isotropic PVDF‐TFE crystals. The morphology was correlated with oxygen permeability, which decreased by almost two orders of magnitude compared with the bulk. A variety of crystal structures were obtained and explained with nucleation and diffusion theory. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
86.
Ferroelectric SrBi2Ta2O9 film was prepared using the sol-gel technique. The sol-gel precursor resulted in good ferroelectric performance at annealing temperatures as low as 700°C. The baking profiles changed the orientation and the grain size in the film. The finer grain size and the higher switching charge were consistent under the slower baking profile. 相似文献
87.
Both TEM and SEM/EBSD orientation measurements are carried out on a Eurofer97 martensitic steel. The influence of the prior austenitic grain size is studied using dedicated heat treatments. The intra laths misorientation is estimated by TEM. SEM/EBSD orientation mapping enable to study the actual orientation relationship (OR) between the parent austenitic phase and the martensitic phase. Neither the Nishiyama–Wasserman nor the Kurdjumov–Sachs OR is able to account for both the misorientation angle distributions, the pole figure and the misorientation axes measured. The mixed OR recently proposed by Gourgues et al. (Electron backscattering diffraction study of acicular ferrite, bainite, and martensite steel microstructures, Mater. Sci. Tech. 16 (2000), pp. 26–40.) and Sonderegger et al. (Martensite laths in creep resistant martensitic 9–12%Cr steels – Calculation and measurement of misorientations, Mater. Characterization (2006), in Press.) seems to be able to account for most of these results. Based on this OR, a new angular criterion is proposed to detect blocks of laths. 相似文献
88.
采用速凝成晶技术,制备了具有<112>和<110>择优取向的Tb0.27Dy0.73Fe1.95速凝片.研究发现,速凝片的择优取向和显微组织与冷却速度密切相关.随着冷却速度的增加,其择优取向从<112>向<110>变化,显微组织由枝状晶向胞枝晶转变.研究了由速凝片制备的稀土粘结磁致伸缩样品的性能.结果表明,当粉末粒度≤(100~150)μm时材料性能较好,具有<112择优取向的样品性能高于<110>择优取向的样品,磁场取向成型有利于材料性能的改善.获得了性能良好的粘结磁致伸缩材料,在238.8 kA·m-1时磁致伸缩系数达到740×10-6. 相似文献
89.
Trinh An Huy Rameshwar Adhikari Thomas Lüpke Sven Henning Goerg H. Michler 《Journal of Polymer Science.Polymer Physics》2004,42(24):4478-4488
The orientation behavior of isotactic polypropylene (iPP) in α‐ and β‐crystal form was investigated by rheo‐optical Fourier transformed infrared (FTIR) spectroscopy. This method enabled quantification of the degree of orientation as a feature of structural changes during uniaxial elongation in not only the crystalline phase but also the amorphous one. Molecular orientation mechanisms can be successfully derived from experimental results. Generally, three mechanisms were detected for iPP: (1) interlamellar separation in the amorphous phase, (2) interlamellar slip and lamellar twisting at small elongations, and (3) intralamellar slip at high elongations. The third mechanism was favored by α‐PP, whereas β‐PP favored the second mechanism, which, in fact, was responsible for the different mechanical properties of both materials at the macroscopic level. On the other hand, crystallization conditions may have significantly affected the amorphous orientation. Nevertheless, for both iPP types the chains in the amorphous phase always oriented less than did those in the crystalline phase. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4478–4488, 2004 相似文献
90.