电磁驱动45钢准等熵压缩的实验研究

在已有的众多准等熵加载技术中,磁驱动准等熵加载技术具有准等熵程度高、压力范围大、实验材料种类多、效费比高等特点。利用中物院流体物理研究所建成的磁驱动准等熵压缩和高速飞片实验装置CQ-1.5(最高加载压力为50GPa),成功开展了45钢的准等熵压缩实验,对装置的主要参数进行了介绍;利用激光干涉测试系统DPS获得了45钢飞片的自由面速度历史,通过反积分处理给出了材料准等熵压缩的p-V关系。通过分析实验数据,获得了45钢3种形式的等熵方程的参数。实验获得的最高等熵压力为47.5GPa。     

MAGNETO-HYDRODYNAMICS MODELING OF CONFIGURATIONS IN MAGNETICALLY DRIVEN ISENTROPIC COMPRESSION EXPERIMENTS

在一维弹塑性反应流体力学拉格朗日编码SSS 的基础上扩充编制成功的一维磁流体力学计算编码SSS/MHD,可以计算模拟磁驱动等熵压缩（ICE） 实验中多介质、多空腔的不同厚度平行样品构形（台阶靶） 运动,并且把磁流体计算与模拟脉冲功率驱动源的集中参数外电路方程组直接耦合,不依赖于实验当时测量的驱动电流（电压） 数据,直接根据原始数据对实验样品的力学和电磁学运动过程和各种参数剖面进行数值模拟. 介绍了对于纯铝、钽和塑料粘结炸药等3 种性能不同材料的台阶靶样品ICE 实验的计算模拟,得到了与激光速度干涉测量的不同厚度样品后自由面（或光学窗口界面） 速度历史十分符合的结果,对于实验结果的分析和实验设计的改进具有重要意义. 旨在为磁驱动实验系统的校核、设计和实验构形改进提供有一定预测能力、功能比较完善的计算模拟研究手段.     

Photophysics of Schiff Bases: Theoretical Study of Salicylidene Methylamine

The proton‐transfer reaction in a model aromatic Schiff base, salicylidene methylamine (SMA), in the ground and in the lowest electronically‐excited singlet states, is theoretically analyzed with the aid of second‐order approximate coupled‐cluster model CC2, time‐dependent density functional theory (TD‐DFT) using the Becke, three‐parameter Lee–Yang–Parr (B3LYP) functional, and complete active space perturbation theory CASPT2 electronic structure methods. Computed vertical‐absorption spectra for the stable ground‐state isomers of SMA fully confirm the photochromism of SMA. The potential‐energy profiles of the ground and the lowest excited singlet state are calculated and four photophysically relevant isomeric forms of SMA; α, β, γ, and δ are discussed. The calculations indicate two S₁/S₀ conical intersections which provide non‐adiabatic gates for a radiationless decay to the ground state. The photophysical scheme which emerges from the theoretical study is related to recent experimental results obtained for SMA and its derivatives in the low‐temperature argon matrices (J. Grzegorzek, A. Filarowski, Z. Mielke, Phys. Chem. Chem. Phys. 2011 , 13, 16596–16605). Our results suggest that aromatic Schiff bases are potential candidates for optically driven molecular switches.     

Single Chain Folding of Synthetic Polymers by Covalent and Non‐Covalent Interactions: Current Status and Future Perspectives

The present feature article highlights the preparation of polymeric nanoparticles and initial attempts towards mimicking the structure of natural biomacromolecules by single chain folding of well‐defined linear polymers through covalent and non‐covalent interactions. Initially, the discussion focuses on the synthesis and characterization of single chain self‐folded structures by non‐covalent interactions. The second part of the article summarizes the folding of single chain polymers by means of covalent interactions into nanoparticle systems. The current state of the art in the field of single chain folding indicates that covalent‐bond‐driven nanoparticle preparation is well advanced, while the first encouraging steps towards building reversible single chain folding systems by the use of mutually orthogonal hydrogen‐bonding motifs have been made.     

对称性自发破缺所诱发的种子平行雷诺胁强

根据第二类气球模理论,在托卡马克中诸如不稳定漂移波类的环形局部模将在径向呈现源于环形性的对称性自发破缺。以流体离子温度梯度模模型方程为例,解出在准环坐标系中由对称性自发破缺产生的二维局部模本征模式。在略去边带效应后,它成为具有径向位移修正的平板模式。由位移修正离子温度梯度模式导出了种子平行雷诺胁强,而它在传统的(无位移修正的)平板模式下被证明为零。     

格子Boltzmann方法中的曲边界处理

研究了格子Boltzmann方法中实现曲边界条件的3种格式,对它们的精度和稳定性进行了分析和比较.通过二维Poiseuille流和等边三角域上空腔流的模拟,讨论了这3种格式的数值精度和稳定性.     

核电站乏燃料对生物圈的影响及ADS 对策

介绍了核电发展状况和核电产生的乏燃料中的锕系及长寿命裂变产物核素, 在毒性方面评述了这些核素对生物圈的影响, 最后提出用加速器驱动的次临界系统嬗变核废物的对策, 以减轻或消除核废物对生物圈的影响。 The current status of nuclear power development and the actinides and some Long Lived Fission Products (LLFPs) in nuclear power spent fuel have been introduced. The radiation effect of spent fuel on biological circle in the viewpoint of Biological Hazard Potential (BHP) and Annual Limit of Intake were evaluated. The Accelerator Driven Sub critical System （ADS） as a strategy to transmute Minor Actinides (MAs) and LLFPs was recommended in order to reduce or eliminate the radiation effect of spent fuel on biological circle.     

高度分散的Pt/TiO2的制备及光催化活性

用柠檬酸作为空穴捕获剂和分散剂,在温和条件下用光催化还原法将3nm金属铂沉积在7nm的锐钛矿相及介孔二氧化钛纳米晶表面,TEM观察显示铂的负载量为w=1．0％时,多数二氧化钛纳米晶表面沉积了岛状的铂团簇,XPS和电子衍射结果表明铂以游离态存在．负载w=1．0％～2．0％铂的TiO2在苯酚光氧化反应中活性显著提高,Pt/TiO2在氨气中经550℃氮化,可制得氮掺杂的Pt／TiO2可见光光催化剂,氮化过程中铂团簇没有烧结和显著长大。     

New studying of Lattice Boltzmann method for two-phase driven in porous media

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中空等离子体通道中强激光脉冲对电子的加速

分析了中空等离子体通道内传播的强激光脉冲电磁场中注入电子的运动,发现当激光脉冲强度超过某个阈值时,电子能获得有效的纵向加速并自动与脉冲分离.所得结果为实验提供了参考和依据.