One-dimensional Coordination Polymers of rctt-1,3-Diphenyl-2,4-bis [2-（5-phenyl）- oxazolyl]cyclobutane with CuCI2 and COCl2

The Cu（Ⅱ） and Co（Ⅱ） supramolecular coordination polymers, [CuCl2（DPO）- （CH3CN）0.5（CH2Cl2）0.5]n （CuDPO, DPO = rctt-1,3-diphenyl-2,4-bis[2-（5-phenyl）oxazolyl]cyclo- butane） and [CoCl2（DPO）]n （CoDPO）, were synthesized and characterized by single-crystal X-ray diffraction method. CuDPO crystallizes in monoclinic, space group P21/n, with a = 11.243（5）, b = 16.070（8）, c = 19.872（9） A, β = 95.678（10）°, Z = 4, V= 3573（3） A3, C35.50H28.50Cl3CuN2.50O2, Mr = 692.00, Dc = 1.287 g/cm3, p = 0.868 mm^-1, F（000） = 1420, S = 1.089, （△/σ）max = 0.069, the final R = 0.0682 and wR = 0.1749. CoDPO is of monoclinie, space group P21/n, with a = 11.396（4）, b = 15.151（5）, c = 17.673（6） A, β = 90.528（6）°, Z = 4, V = 3051.4（17） A3, C34H26Cl2CoN2O2, Mr = 624.40, Dc = 1.359 g/cm3, μ = 0.770 mm^-1, F（000） = 1284, S = 0.981, （△/σ）max = 0.001, the final R = 0.0471 and wR = 0.0961. In each case, the metal cation is coordinated by two C1 anions and two N atoms from oxazole ring of the ligands, which leads to the formation of a one-dimensional polymeric structure. It is found that the cyclobutane ring of coordinated DPO adopts a distorted conformation in the crystal, which is attributed to the increased steric effect between adjacent aryl substituents for the coordination of oxazole ring to metal cation. Thermal gravimetric analysis of the two complexes was also observed.     

一维纳米材料的拉曼光谱学研究

本文将报告对硅纳米线、多孔硅、Si C纳米棒和碳纳米管等一维纳米体系的本征拉曼光谱及其特征的研究结果 ,并讨论拉曼光谱在上述材料的几何和物理特性研究中的应用。     

STEADY-STATE SOLUTIONS FOR A ONE-DIMENSIONAL NONISENTROPIC HYDRODYNAMIC MODEL WITH NON-CONSTANT LATTICE TEMPERATURE

A one-dimensional stationary nonisentropic hydrodynamic model for semiconductor devices with non-constant lattice temperature is studied. This model consists of the equations for the electron density, the electron current density and electron temperature, coupled with the Poisson equation of the electrostatic potential in a bounded interval supplemented with proper boundary conditions. The existence and uniqueness of a strong subsonic steady-state solution with positive particle density and positive temperature is established. The proof is based on the fixed-point arguments, the Stampacchia truncation methods, and the basic energy estimates.     

一类p-Laplace方程边值问题解的存在性

主要讨论一维p-Laplace方程在Neumann边值条件u(0)=0,u(1)=0下,对应的边值问题解的存在性.通过使用度理论,在适当的条件下,建立了对于p-Laplace方程在Neumann条件下解的存在性的充分条件.     

Electromagnetic Bloch oscillation in one-dimensional multiple microcavities composed of metamaterials

We propose a photonic structure stacked sequentially by one-dimensional photonic crystals and cavities. The whole structure is composed of single-negative and double-negative materials. The optical Wannier-Stark ladder （WSL） can be obtained in a low frequency region by modulating the widths of the cavities in order. We simulate the dynamical behavior of the electromagnetic wave passing through the proposed photonic structure. Due to the dispersive characteristics of the metamaterials, a very narrow WSL can be obtained. The long-period electromagnetic Bloch oscillation is demonstrated theoretically to have a period on a microsecond time scale.     

SHPB测试中的均匀性问题及恒应变率

利用一维应力波理论对霍普金森压杆(SHPB)测试中的均匀性问题作了较为详尽的讨论,对测试中各种加载波形的优缺点及各参数对均匀性的影响进行了分析与评估。给出了测试脆性材料时实现恒应变率加载的加载条件。对在满足应力均匀性要求下SHPB的可测应变率范围作了讨论并修正了前人不完善的结论。讨论了考虑均匀性时应采用的测试数据处理方法。利用图解的方法对弹塑性材料测试时的均匀性问题及相应加载要求作了定性分析,指出对弹塑性材料,测试中的应变不均匀也应予以考虑。     

SHPB数据处理中的二波法与三波法

分析了传统的分离式霍普金森压杆测试数据处理方法(二波法)及其他被提出的改进方法的误差及优缺点,给出了传统二波处理方法在不同被测材料情况下所带来的误差。分析结果表明,基于绝对时间下的试件应力及应变计算的三波处理法具有最好的可信度且能最大程度地避免数据处理过程中的人为因素。传统二波法在不同测试情况下均不是优选的方法。对于三波测试无法进行的情况,也提出了一种简化三波处理方法。     

硅基薄膜太阳电池一维光子晶体背反射器的模拟设计与制备

从模拟和实验两个方面研究了一种适用于硅基薄膜太阳电池的一维光子晶体新型背反射器.首先采用时域有限差分方法,模拟研究了组成一维光子晶体的两种介质的折射率比、厚度比以及周期厚度对光子禁带的影响.基于模拟结果,制备出一种由低折射率SiOx层与高折射率非晶硅a-Si层周期性交叠构成的禁带可调式一维光子晶体背反射器.通过改变a-Si层的厚度,使得禁带范围由500—750 nm波长范围红移至650—1100 nm,反射率分别达到96.4%和99%.将上述结构的一维光子晶体作为背反射器分别应用于非晶硅单结太阳电池和非晶硅/微晶硅双结叠层太阳电池,与没有背反射结构电池相比,短路电流密度分别提升了18.3%和15.2%.同时模拟研究了在不同入射角度下自然光、TE波和TM波对光子晶体反射特性的影响.研究结果表明,在太阳电池中,光线倾斜入射对一维光子晶体反射率的影响有限.     

含双周期裂纹的一维六方准晶电弹性全平面应变基本问题

针对电极化方向沿准周期方向的情况,讨论了周期平面内含双周期裂纹的一维六方准晶的电弹性全平面应变第一基本问题和第二基本问题。根据力的叠加原理,将三维的应力系统分解为线性独立的两组二维应力状态;运用复应力函数方法将弹性平衡状态的求解归结为求解正则型积分方程,并证明了其唯一可解性。结果表明:一维六方准晶双周期断裂问题在广义双周期边界条件下的力学解是存在并且唯一的。此结果为运用各种方法研究该基本问题的正确性和一致性提供了理论保证。