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91.
一维链状有机锡配位聚合物[(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n的合成及晶体结构 总被引:7,自引:0,他引:7
[(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n was synthesized by the reaction of 4-pyridine car-boxylic acid with the tribenzyltin oxide and was characterized by IR,1H NMR and MS.Its crystal structure was determined by X-ray single crystal diffraction.The crystal belongs to monoclinic.The space group P21/c with unit cell parameters a=1.2241(8)nm,b=0.9660(6)nm,c=2.3708(15)nm,β=102.722(12)°,V=2.734(3)nm3,Z =4,Dc=1.298g·cm-3.In crystal,the tin atom rendered five-coordinate in a trigo nal bipyramidal structure which is bridged by 4-pyridine carboxy-late into one-dimensional chain polymers. 相似文献
92.
一维链状配位聚合物[Co(imbz)2(H2O)2]n[imbz=4′-(1-咪唑基亚甲基)苯甲酸根]的合成及晶体结构 总被引:1,自引:0,他引:1
A new coordination polyme[Co (imbz)2(H2O)2]n[imbz =4'-(imidazol-1-ylmethyl)benzoate anion]was synthesized and characterized by x-ray crystallography.The title complex crystallizes in monoclinic,space group P21/c,a=10.910(2),b=8.8720(18),c=11.252(2)Å,β=92.20(3)°,V=1088.3(4)Å3,Z =2,Dc=1.518g·cm-3,μ=0.836cm-1,F(000)=514,R=0.0679,wR=0.1710.Each Co(Ⅱ)atom has a distorted octahedral coordination geometry and is six-coord-inated by two water molecules and fou rimbz ligands.Each imbz ligand connects two Co(Ⅱ) to gen-erate an infinite 1Dtwisted chain structure. 相似文献
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This paper is concerned with developing accurate and efficient numerical methods for one-dimensional fully nonlinear second order elliptic and parabolic partial differential equations (PDEs). In the paper we present a general framework for constructing high order interior penalty discontinuous Galerkin (IP-DG) methods for approximating viscosity solutions of these fully nonlinear PDEs. In order to capture discontinuities of the second order derivative uxx of the solution u, three independent functions p1,p2 and p3 are introduced to represent numerical derivatives using various one-sided limits. The proposed DG frame- work, which is based on a nonstandard mixed formulation of the underlying PDE, embeds a nonlinear problem into a mostly linear system of equations where the nonlinearity has been modified to include multiple values of the second order derivative uxz. The proposed framework extends a companion finite difference framework developed by the authors in [9] and allows for the approximation of fully nonlinear PDEs using high order polynomials and non-uniform meshes. In addition to the nonstandard mixed formulation setting, another main idea is to replace the fully nonlinear differential operator by a numerical operator which is consistent with the differential operator and satisfies certain monotonicity (called g-monotonicity) properties. To ensure such a g-monotonicity, the crux of the construction is to introduce the numerical moment, which plays a critical role in the proposed DG frame- work. The g-monotonicity gives the DG methods the ability to select the mathematically "correct" solution (i.e., the viscosity solution) among all possible solutions. Moreover, the g-monotonicity allows for the possible development of more efficient nonlinear solvers as the special nonlinearity of the algebraic systems can be explored to decouple the equations. This paper also presents and analyzes numerical results for several numerical test problems which are used to guage the accuracy and efficiency of the proposed DG methods. 相似文献
96.
本文利用多种液体核磁共振(NMR)技术,综合分析了在三个不同反应条件下蒽催化加氢反应获得的产物混合物.利用二维扩散排序谱(DOSY)和一维选择性激发谱(selTOCSY)确定了产物中含有的二氢蒽、四氢蒽、对称八氢蒽和非对称八氢蒽;利用1H NMR、13C NMR、DEPT135、1H-1H COSY、1H-13C HSQC实验对二氢蒽、四氢蒽和对称八氢蒽的1H和13C NMR信号进行了详细归属;利用定量核磁共振氢谱(QNMR)计算得到了蒽的转化率和产物的选择性.本研究可用于指导优化催化反应条件,提高产物对称八氢蒽的选择性,同时为稠环类芳烃催化加氢产物的分析提供系统的NMR技术方案. 相似文献
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1引言
ITER实验包层模块(Test Blanket Modules,TBM)是验证未来聚变反应堆能否实现氚自持、高热量提取的重要实验平台,也是将来发展DEMO聚变堆包层技术而进行电磁性能测试、热工水力学测试、氚增殖实验的重要工具。由于ITER对自身安全的严格要求和对TBM安全性的要求限制,TBM内部能量产生的多少和最大功率密度及其分布等参数都非常重要。同时,产氚实验也是TBM重要的目的之一,它关系到热核聚变堆氚燃料的供给。因此,提高TBM的氚增殖性能的优化设计同样具有十分重要的意义。 相似文献
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