原子吸收光谱法测定皖景天吸收镉和锌的研究

通过原子吸收光谱法研究了皖景天对镉和锌的吸收特性,结果表明:皖景天对镉和锌的吸收量随时间的延长而增加,皖景天对镉吸收速率随时间的延长而降低,皖景天对锌吸收速率随时间的延长呈现先下降后上升的趋势。     

圆柱形通道结构橡胶声障板

本文介绍了具有圆柱通道的橡胶水声反声障板的机理，通过静态近似得到此种橡胶声学参数的计算公式，测试了相关材料的动态力学性能，并对障板的声学特性进行了理论计算和分析，给出了不同频率下的反声性能随材料损耗因子、剪切模量及厚度的变化规律，并对模型进行了试验验证。     

A new dimeric iridal triterpenoid from Belamcanda chinensis with significant molluscicide activity

An unprecedented dimeric triterpenoid, designated dibelamcandal A, with a six-membered ring linking two iridal type triterpenoid nuclei, was isolated from the rhizome of Belamcanda chinensis. Its structure was determined by extensive spectroscopic measurements, including IR, ESI-MS, HR-ESI-MS, and 1D and 2D NMR. It demonstrated significant molluscicide activity against Pomacea canaliculata.     

硅胶柱层析-电喷雾多级质谱快速分析两头尖中的三萜皂苷类成分

建立了电喷雾多级质谱结合硅胶柱层析快速、全面分析中药两头尖中三萜皂苷成分的方法.取两头尖粉末30 g,在60℃下以300 mL 70%甲醇溶液提取6次,合并提取液,减压浓缩得提取物3.3 g,提取物悬浮于20mL,水中,先用乙酸乙酯(20 mL×3)萃取除脂,再用正丁醇(20 mL×6)萃取.取正丁醇萃取物1.5 g进...     

光源参数及大气湍流对电磁光束传输偏振特性的影响

根据光束扩展理论,以部分相干的电磁高斯-谢尔光束为研究对象,分析了电磁光束传输时其偏振特性的变化机理.结果表明,光源参数和大气湍流对电磁光束分量扩展的影响是导致传输过程中电磁光束偏振特性变化的原因.在真空中传输时,电磁光束两分量的相干性存在差异,导致传输时电磁光束两分量扩展快慢不同,从而引起传输路径上光束谱偏振度的变化.在大气湍流中,电磁光束两分量扩展的快慢与光源参数和大气湍流强度均有关,当传输路径较短时,电磁光束偏振变化主要与光源参数有关,变化特性与在真空中传输时的情况类似,而传输距离较远时,电磁光束偏振变化受大气湍流的影响明显,变化特性与在真空中传输时的情形存在不同.     

色氨酸-镝(Ⅲ)配合物与鲱鱼精DNA的作用方式

采用UV光谱法、荧光光谱法,在pH=7.40的缓冲溶液中确定了镝(Ⅲ)与色氨酸的结合比n_Dy(Ⅲ)∶n_Trp=1∶3,Dy(Ⅲ)(Trp)₃配合物与鲱鱼精DNA的结合比n_{Dy(Ⅲ)(Trp)3}∶n_DNA=2∶1。用双倒数法确定了结合常数K_25℃=5.75×10⁴ L·mol^-1和K_37℃=3.27×10⁴ L·mol^-1。化学热力学研究显示配合物Dy(Ⅲ)(Trp)₃与hsDNA的结合为熵和焓共同驱动。结合Scatchard法和粘度法,确定了配合物Dy(Ⅲ)(Trp)₃与hsDNA之间主要为静电作用和嵌插作用。     

固体中圆柱形空腔上爬波的光弹法实验研究

本文用光弹法在玻璃内直接看到了弹性波爬波现象,当超声垂直轴向投射于固体内的圆柱形空腔时,在声的几何阴影区会激发出一种沿空腔界面爬行的表面波,它边爬边辐射体波,从而在几阴影区产生超声的散射波。我们观察了纵波入射和横波入射两种情况,分别测量了爬波的脉冲速度。实验表明,纵波入射时,固体中情况和流体中情况大体一样,但横波入射时,固体中情况要复杂得多。 此外,还附带观察了超声波从圆弧一侧投射到玻璃内半圆柱形空腔时的爬波行为。     

Demonstration of a phosphazirconocene as a catalyst for the ring opening of epoxides with TMSCl

[reaction: see text] In this study, it was demonstrated for the first time that a phosphazirconocene catalyzes the ring opening of epoxides with TMSCl. This reactivity leads to a facile preparation of chlorohydrins. The late transition metal Fe analogue was found to catalyze the reaction at rates and stereoselectivity comparable to those of the Zr complex.     

Thermal Degradation of Linalool-Chemotype Cinnamomum osmophloeum Leaf Essential Oil and Its Stabilization by Microencapsulation with β-Cyclodextrin

The thermal degradation of linalool-chemotype Cinnamomum osmophloeum leaf essential oil and the stability effect of microencapsulation of leaf essential oil with β-cyclodextrin were studied. After thermal degradation of linalool-chemotype leaf essential oil, degraded compounds including β-myrcene, cis-ocimene and trans-ocimene, were formed through the dehydroxylation of linalool; and ene cyclization also occurs to linalool and its dehydroxylated products to form the compounds such as limonene, terpinolene and α-terpinene. The optimal microencapsulation conditions of leaf essential oil microcapsules were at a leaf essential oil to the β-cyclodextrin ratio of 15:85 and with a solvent ratio (ethanol to water) of 1:5. The maximum yield of leaf essential oil microencapsulated with β-cyclodextrin was 96.5%. According to results from the accelerated dry-heat aging test, β-cyclodextrin was fairly stable at 105 °C, and microencapsulation with β-cyclodextrin can efficiently slow down the emission of linalool-chemotype C. osmophloeum leaf essential oil.     

A quasi-layer structure of trinuclear molybdenum(IV) cluster, [Mo3S7(S2CNEt2)3]I·S8

The title compound, [Mo₃(₃-S)(-S₂)₃(S₂CNEt₂)₃]I·S₈, was obtained by solid state reaction of (NH₄)₂MoS₄, Et₂NCS₂Na, and Et₄NI at low heating temperature and crystallizes in space group P with a = 13.572(3), b = 13.813(4), c = 13.239(3) Å, = 92.63(3), = 100.15(3), = 117.89(2)°, V = 2136(2) ų, and D _calc. = 2.08 g/cm³ for Z = 2. The structure reveals that it consists of a trinuclear Mo cluster molecule, [Mo₃S₇(S₂CNEt₂)₃]I, and one S₈, which are connected to form a quasi-layer structure by the interaction between S₈ and the S atoms of the cluster molecule.