Sm3+掺杂棒状BiPO4微晶的制备及其光催化活性增强机理

以Sm(NO3)3、NH4H2PO4和Bi(NO3)3为原料,采用水热法合成了Sm3+掺杂棒状BiPO4光催化剂.采用XRD、SEM、UV-Vis吸收光谱、BET比表面积测试等手段对其组成、晶型、粒径、形貌及比表面积等进行了表征,并以金卤灯模拟可见光,以甲基橙和邻硝基苯酚为模型污染物,对其光催化性能进行了评价和分析.XRD和SEM分析表明,Sm3+掺杂进入BiPO4的晶格,导致其晶胞参数发生变化,但对其物相结构和形貌的影响不明显;UV-Vis吸收光谱测试表明,Sm3+掺杂使BiPO4在紫外光区的吸收减弱,可见光区略有增强.光催化实验表明,Sm3+掺杂后BiPO4的光催化活性与掺杂量密切相关,当Sm3掺杂量为0.75at;时光催化活性提高较显著.根据实验结果和文献报道,论文对Sm3+掺杂后BiPO4活性提高机理进行了探讨,认为Sm3+掺杂后BiPO4光生电子-空穴分离效率提高是影响其活性的主要因素.     

Random-fuzzy model for the ductile/brittle transition

IntroductionTheductile brittletransition (DBT )ofsteelalloysisinfluencedbythematerialmicrostructureandtestingtemperature[1].Availablereferencesrangingfromanalyticalapproachtoempiricaltestsaretoonumeroustolist.Mostofthesemodesaredeterministic ,whichdidnottaketherandomnessoftheparametersandman_madeerrorintoconsideration .Thebasicproposesofthispaperistounderstandthetransitionbyanewrandom_fuzzymodel.Theductile brittletransitioninvolvestheductilefracture ,brittlefractureandthetransition .Inacerta…     

CONDITIONAL SIMILARITY REDUCTION APPROACH: JIMBO－MIWA EQUATION

The direct method developed by Clarkson and Kruskal (1989 J. Math. Phys. 30 2201) for finding the symmetry reductions of a nonlinear system is extended to find the conditional similarity solutions. Using the method of the Jimbo－Miwa (JM) equation, we find that three well-known (2+1)-dimensional models－the asymmetric Nizhnik--Novikov－Veselov equation, the breaking soliton equation and the Kadomtsev-Petviashvili equation－can all be obtained as the conditional similarity reductions of the JM equation.     

不同形状压头作用下的压痕蠕变数值研究

采用有限元方法分析了圆锥压头、球形压头和圆柱形平压头作用下铝合金(2A12)的压痕蠕变行为,给出了三种压头作用下的等效蠕变应变、压痕深度-时间曲线和硬度-时间曲线.对于给定尺寸的三种压头,在相同载荷作用下,圆锥压头作用下的最大等效蠕变应变最大,圆柱形平压头作用下的最大等效蠕变应变最小;不同形状压头的压痕深度-时间曲线相似,由"瞬态蠕变"和"稳态蠕变"两段组成;而硬度随时间和压痕深度均呈现递减的趋势,不存在稳态数值.结果表明,在研究高温压痕蠕变现象、确定材料蠕变参数方面,平压头具有相当的优势:压头下方的应力场相对稳定,可不考虑摩擦和堆积的影响,计算简便准确.     

复合材料螺栓连接性能的分散性和可靠性分析

本文通过对35个复合材料层合板螺栓连接试验件进行钉孔挤压试验,得到各个试件的挤压强度,然后采用统计分析的方法,研究复合材料层合板螺栓连接挤压强度的分散性规律。研究表明,复合材料层合板螺栓连接挤压强度的分散性模型可以用正态分布、对数正态分布以及威布尔分布三种模型模拟,其中以威布尔分布拟合效果最好,其次是正态分布。另外,本文采用极大似然估计方法给出了三个模型的分布参数。最后,利用蒙特卡洛法和雷-菲法计算了三种分布模型下的失效概率。结果表明,威布尔分布的失效概率最大,而对数正态分布的失效概率最小。     

基于主动轮廓模型的EAST等离子体边界重建

通过分析等离子体边界的等磁通特性,利用主动轮廓模型进行边界重建,给出了主动轮廓的能量计算方法、重建算法、边界磁通和初始轮廓的确定方法。利用EAST实验数据对边界的重建测试表明,该算法具有良好的准确性和实时性。     

STRESS ANALYSIS IN CUBIC BORON NITRIDE FILMS BY X-RAY DIFFRACTION USING sin2 ψ METHOD

The boron nitride (BN) films containing cubic boron nitride (c-BN) and hexagonal boron nitride (h-BN) were prepared by radio frequency a ssisted thermal filament chemical vapor deposition. The stress and strain in BN films were investigated by X-ray diffraction analysis using the sin² ψ method. The results showed that both c-BN and h-BN in the same film have similar values of elastic strain, however, the compressive stress in c-BN is much greater than that in h-BN for the same film. Both stress and strain gradually decre ased with the increase of substrate temperature (T_s). The effective stress in the films calculated by the effective stress model increased with the increase of T_s. Furthermore, the dependence of effective stress in the films on T_s was also investigated.     

三维SPH程序及其在斜高速碰撞问题的应用

叙述了平滑粒子流体动力学(简称SPH)的基本概念,重新推导了所用的基本方程。介绍了具体计算格式、算法以及策略等。对所编制的程序作了一定的检验。对SPH方法中的人为粘性和人为热流的作用作了数值考查。还提供了一个三维高速碰撞现象的算例。最后指出尚存在的若干问题。     

Simulation of coupled flowing-reaction-deformation with mass transfer in heap leaching processes

Governing equations for a fully coupled flowing-reaction-deformation behavior with mass transfer in heap leaching are developed. The model equations are solved using an explicit finite difference method under the conditions of invariable application rate and constant hydraulic head. The distribution of the degree of the saturation, as well as the distributions of the concentration of the reagent and the solute is given. A cubic relationship between the mineral recovery and the leaching duration is obtained based on the numerical results. The relationship can be used to predict the recovery percentage of the valuable metal.     

机械可靠性分析的高精度响应面法

通过对已有可靠性分析中的响应面法的研究,提出了一种高精度的响应面法,该方法通过迭代线性插值的策略,来保证确定响应面的抽样点比经典的响应面法更接近真实的极限状态方程,并且该方法通过序列线性插值的方法来控制抽样点与插值中心点的距离,保证随着插值中心点收敛于真实设计点,抽样点提供更多的关于设计点附近真实极限状态方程的信息,进而保证了收敛的响应面能够在设计点附近更好地拟合真实的极限状态方程,并得到高精度的失效概率计算结果．算例充分说明了所提方法的合理性与适用性．