浅海宽带简正模相干/非相干能量比值特征匹配的源深估计

无源声源深度估计一直是水声领域的一个难题。针对浅海波导中低频宽带脉冲声源深度估计问题,提出了利用单水听器接收信号中多阶简正模相干项能量与非相干项能量比值的特征匹配处理方法,不仅消除了声源未知激发谱的影响,而且由于在预先估计声源距离基础上实现对声源深度的独立估计,运算量小。同时,由于利用了实测数据与拷贝声场中具有相同简正模贡献的相干能量特征进行匹配,参数估计具有较高的稳健性。首先通过向量线性相关数学理论,在理想波导条件下讨论了简正模数目与源深估计单值性的关系,证明了仅利用两阶简正模时源深估计具有多值性,而声场含有三阶以上简正模时源深估计存在唯一解。进一步的仿真分析表明,当信噪比高于0 dB时源深估计结果的平均误差整体上在5 m之内。分析了水文参数、沉积层声学参数及声源距离失配时方法的鲁棒性。最后,利用浅海垂直阵采集的低频宽带脉冲实验数据对方法进行验证,声源深度估计结果绝对误差小于5 m的概率在79.1%以上。方法可推广应用于浅海水平或垂直基阵对低频宽带声源的深度估计。      

Sr-doping effects on conductivity,charge transport,and ferroelectricity of Ba0.7La0.3TiO3 epitaxial thin films

Sr-doped Ba_0.7La_0.3TiO₃(BSLTO)thin films are deposited by pulsed laser deposition,and their microstructure,conductivity,carrier transport mechanism,and ferroelectricity are systematically investigated.The x-ray diffraction measurements demonstrate that Sr-doping reduces the lattice constant of BSLTO thin films,resulting in the enhanced phonon energy in the films as evidenced by the Raman measurements.Resistivity-temperature and Hall effect measurements demonstrate that Sr can gradually reduce electrical resistivity while the electron concentration remains almost unchanged at high temperatures.For the films with semiconducting behavior,the charge transport model transforms from variable range hopping to small polaron hopping as the measurement temperature increases.The metalic conductive behaviors in the films with Sr=0.30,0.40 conform to thermal phonon scattering mode.The difference in charge transport behavior dependent on the A-site cation doping,is clarified.It is revealed that the increasing of phonon energy by Sr doping is responsible for lower activation energy of small polaron hopping,higher carrier mobility,and lower electrical resistivity.Interestingly,the piezoelectric force microscopy(PFM)results demonstrate that all the BSLTO films can exhibit ferroelectricity,especially for the room temperature metallic conduction film with Sr=0.40.These results imply that Sr-doping could be a potential way to explore ferroelectric metal materials for other perovskite oxides.     

多层自组装硫脲和纳米金电流型萘免疫传感器的研究

建立了基于硫脲和纳米金层层自组装技术的无标记、高灵敏电流型免疫传感器,用于萘的检测。利用循环伏安法研究了修饰电极表面的电化学特性以及测试溶液的pH值、孵育时间和温度对免疫传感器性能的影响。实验表明,此免疫传感器在含不同浓度萘抗原的PBS溶液(pH7.4)中37℃下孵育30 min后,在pH7.4的测试底液中测定,响应电流与萘浓度在0.5～100μg/L范围内有良好的线性关系,r=0.9986,检出限为0.08μg/L。此传感器制备简单,灵敏度高,稳定性好,可以重复使用。应用于实际水样中萘的测定,回收率为94.3%～107.0%。     

Influence of Substrate on the Transportation Properties of Co/Alq3 Granular Films on a Si Wafer

A series of Co0.48 （Alq3）0.52 granular films were deposited on silicon substrates using the co-evaporating technique. A crossover of magnetoresistance （MR） from negative to positive was observed in the samples, due to conducting channel switching. The transport properties of samples are greatly influenced by hydrofluoric acid pretreatment, as a result, positive MR decreases drastically and the temperature dependence of resistance changes a lot near room temperature. The result indicates that the native oxide layer plays an important role in the transport mechanism. Moreover, different resistivities of Si substrates influence the current distribution of conducting channels, leading to different transport behaviors accordingly.     

多孔芳香骨架吸附剂-固相萃取-高效液相色谱法同时测定辣椒粉中4种偶氮类染料

建立了固相萃取-高效液相色谱同时测定辣椒粉中对位红、酸性橙Ⅱ、苏丹红Ⅰ和苏丹红Ⅱ 4种偶氮染料的方法。以多孔芳香骨架-6（PAF-6）材料作为固相萃取吸附剂，考察并获得了影响自制固相萃取柱的萃取效率和吸附容量等主要因素。在优化条件下，4种目标分析物的检出限（LOD）为1.5~7.0 μg/L（信噪比S/N=3），定量限（LOQ）为5.0~22.1 μg/L（S/N=10），加标回收率为76.5%~89.8%，相对标准偏差（RSD）均不大于5.3%（n=6）。此外，基于量子化学计算，考察了PAF-6与目标分析物之间的相互作用机制，结果表明，目标分析物可以稳定地吸附在PAF-6分子上。该方法准确可靠，具有良好的回收率和较高的灵敏度，可用于辣椒粉中4种偶氮类染料的检测。     

Resonance Absorption of Metallic Plate with Subwavelength Hole Array

The optical reflectance by a metallic plate arranged with array consisting of subwavelength periodic square hole is investigated by using the three-dimensional finite-difference time-domain method （3D-FDTD）. There are dips in the reflectivity spectra, which indicate the absorption peaks. The absorption peaks behave differently according to the ratio of hole width and the period of the hole array. Combined with the near fields of the absorption peaks, it is found that the surface plasmon （SP） resonance on the surface of plate and localized SP in the hole play a major role for the two absorptions.     

丝氨酰组氨酰赖氨酸三肽的合成

利用液相合成法,丝氨酸、组氨酸、赖氨酸经活化后缩合合成了具有细胞生长因子功能的丝氨酰组氨酰赖氨酸三肽,其结构经1H NMR,GC-MS和IR确证。     

浅谈军校大学物理分层教学法

本文针对士官学员基础较差、层次参差不齐等特点,在其大学物理的教学中实施了分层教学法.分层教学法主要包括教学对象分层、教学目标分层、教学过程分层和考核评价分层四个环节.教学实践表明,该种教学方法能够激发学员的学习热情和潜能,同时有利于提高学员的综合素质.     

聚吖啶橙修饰电极上对苯二酚的电催化及分析应用

将吖啶橙修饰到玻碳电极表面,并研究了此电极上对苯二酚的电化学行为及其检测,发现聚吖啶橙修饰电极对对苯二酚有明显的电催化作用,使其氧化电位降低,峰电流增大。在优化的测试条件下,氧化峰电流与对苯二酚浓度在6.8×10-7~9.6×10-5mol.L-1和3.5×10-4~2.1×10-3mol.L-1范围内呈线性关系。在零电位处闭路富集130 s,测得其检出限为3×10-7mol.L-1,用于模拟废水样的分析,测得对苯二酚的回收率在97.3%~103.0%之间。     

基于网络环境的大学物理实验教学改革研究与实践

本文结合我校大学物理实验课程改革的具体实际, 介绍了课程教学的设计理念和课程教学的组织模 式, 通过课程改革的运行, 总结出大学物理实验课程改革对人才培养发挥的作用, 指出了课程改革存在的问题, 以 及解决问题的方法