压电热弹性体的变分原理及正则方程和齐次方程

结合对偶变量理论,为压电热弹性体混合层合板问题推导了齐次的控制方程和Hamilton等参元列式．首先根据广义的Hamilton变分原理推导了压电热弹性体非齐次的Hamilton正则方程．然后进一步考虑了热平衡方程与导热方程中变量的对偶关系,通过增加正则方程的维数,成功地将非齐次的正则方程转化为能独立求解压电热弹性体耦合问题的齐次控制方程．为了推导四节点Hamilton等参元列式的方便,可将温度梯度关系类比成本构关系并构建新的变分原理．齐次方程大大简化了人们在分析压电热弹性体耦合问题时,通常要求解非齐次方程和关于平衡方程和导热方程的二阶微分方程的繁琐方法,同时也减少了数值计算工作量．     

Hamiltonian parametric element and semi-analytical solution for smart laminated plates

Based on the Hellinger-Reissner (H-R) mixed variational principle for piezoelectric material, a unified 4-node Hamiltonian isoparametric element of anisotropy piezoelectric material is established. A new semi-analytical solution for the natural vibration of smart laminated plates and the transient response of the laminated cantilever with piezoelectric patch is presented. The major steps of mathematical model are as follows: the piezoelectric layer and host layer of laminated plate are considered as unattached three-dimensional bodies and discretized by the Hamiltonian isoparametric elements. The control equation of whole structure is derived by considering the compatibility of generalized displacements and generalized stresses on the interface between layers. There is no restriction for the side-face geometrical boundaries, the thickness and the number of layers of plate by the use of the present isoparametric element. Present method has wide application area.     

Surface properties of diamond-like carbon films prepared by CVD and PVD methods

Diamond-like carbon (DLC) films have been deposited using three different techniques: (a) electron cyclotron resonance---plasma source ion implantation, (b) low-pressure dielectric barrier discharge, (c) filtered---pulsed cathodic arc discharge. The surface and mechanical properties of these films are compared using atomic force microscope-based tests. The experimental results show that hydrogenated DLC films are covered with soft surface layers enriched with hydrogen and sp$^{3}$ hybridized carbon while the soft surface layers of tetrahedral amorphous carbon (ta-C) films have graphite-like structure. The formation of soft surface layers can be associated with the surface diffusion and growth induced by the low-energy deposition process. For typical CVD methods, the atomic hydrogen in the plasmas can contribute to the formation of hydrogen and sp$^{3}$ hybridized carbon enriched surface layers. The high-energy ion implantation causes the rearrangement of atoms beneath the surface layer and leads to an increase in film density. The ta-C films can be deposited using the medium energy carbon ions in the highly-ionized plasma.     

光子石墨烯中赝磁场作用下的谷霍尔效应

将石墨烯中赝磁场的产生机理运用于光子石墨烯,通过在光子石墨烯中引入晶格有规律单轴形变的方式,理论分析得到了谷依赖的均匀赝磁场,并通过数值模拟的方法观察到明显的谷霍尔效应.这种谷霍尔效应的显著程度随晶格形变度的增加而加强.在具有一定损耗的电介质材料构成的形变光子石墨烯中仍可观察到明显的谷霍尔效应.随着电介质材料损耗的增加,谷霍尔效应导致的波束转弯效果依然能够保持,只是强度逐渐变弱.类似于自旋电子学中的自旋霍尔效应,这种光子石墨烯中等效赝磁场作用下的谷霍尔效应在未来谷极化器件的设计和应用中具有重要意义.     

Theoretical analysis of ion kinetic energies and DLC film deposition by CH4＋ Ar （He） dielectric barrier discharge plasmas

The kinetic energy of ions in dielectric barrier discharge plasmas are analysed theoretically using the model of binary collisions between ions and gas molecules. Langevin equation for ions in other gases, Blanc law for ions in mixed gases, and the two-temperature model for ions at higher reduced field are used to determine the ion mobility. The kinetic energies of ions in CH4 ＋ Ar（He） dielectric barrier discharge plasma at a fixed total gas pressure and various Ar （He） concentrations are calculated. It is found that with increasing Ar （He） concentration in CH4 ＋ Ar （He） from 20% to 83%, the CH4＋ kinetic energy increases from 69.6 （43.9） to 92.1 （128.5）eV, while the Ar＋ （He＋） kinetic energy decreases from 97 （145.2） to 78.8 （75.5）eV. The increase of CH4＋ kinetic energy is responsible for the increase of hardness of diamond-like carbon films deposited by CH4 ＋ Ar （He） dielectric barrier discharge without bias voltage over substrates.     

一种双腙受体的合成及阴离子识别性能研究

设计合成了一种含双腙类阴离子受体1(5-甲基双水杨醛-2,4-二硝基苯腙)。用紫外-可见吸收光谱、荧光光谱考察了其与AcO-,H2PO4-,F-,Cl-,Br-和I-阴离子的作用。当加入AcO-、F-和H2PO4-时,受体分子1的吸收光谱发生明显的红移,与此同时溶液颜色由浅粉色变为紫色,而加入其他阴离子则无变化。通过在DMSO-d6核磁滴定实验进一步研究受体1和F-相互作用的本质。     

锌掺杂OV-β-Bi2O3可见光催化活性的提高:能带结构的调节和电荷分离的促进

采用溶胶-凝胶-原位碳热还原处理的方法,制备了一种含有氧空位（OV）的新型Zn掺杂β-Bi₂O₃纳米材料（OV-Zn：Bi₂O₃）,氧空位的浓度可以通过改变Zn²⁺的掺杂量进行调节。作为参照,只有氧空位没有Zn²⁺的新型β-Bi₂O₃（OV-β-Bi₂O₃）也通过类似的方法制得。通过紫外可见漫反射光谱、X射线光电子能谱、电子顺磁共振、光致发光光谱和光电化学测试,系统研究了氧空位和Zn²⁺掺杂对OV-Zn：Bi₂O₃降解亚甲基蓝（MB）和2,4,6-三氯苯酚（2,4,6-TCP）可见光催化活性的综合影响。结果表明,氧空位的引入不仅可以使光吸收向长波方向拓展,而且可以促进光生载流子的分离。因此,与传统的β-Bi₂O₃相比,OV-β-Bi₂O₃对亚甲基蓝（MB）和2,4,6-三氯苯酚（2,4,6-TCP）的降解活性显著增强。对于OV-Zn：Bi₂O₃催化剂,Zn²⁺掺杂可使光催化剂的价带边缘向下移动,增强了光激发空穴的氧化能力,并且适量的锌掺杂也能提高光生载流子的分离效率。因此,OV-Zn：Bi₂O₃的可见光活性优于OV-β-Bi₂O₃,而且当Zn与Bi物质的量之比为0.3时,OV-Zn：Bi₂O₃-0.3对MB和2,4,6-TCP的降解活性最高。     

双核铼配合物复合电纺纤维的制备和氧传感性能的研究

合成了亲脂性双核铼配合物fac-[{Re(CO)₃(d19 phen)}₂(4,4′ bipyridylacetylene)](OTf_⁾2^,将此配合物均匀地分散到聚苯乙烯(PS)和聚甲基丙烯酸甲酯(PMMA)中,通过电纺方法,得到复合材料纤维,并系统地研究了它们的氧传感性能。分别用线性Stern Volmer模型,Demas双格位模型以及Lehrer模型对所得到的Stern Volmer曲线进行了拟合,实验结果表明,这种复合纤维氧传感材料显示了短的响应时间,可逆的氧传感信号,而且由于含有亲脂性的长链烷烃配体的存在,使得铼配合物在聚合物中分散均匀,从而得到线性关系较好的Stern Volmer曲线。     

Rotational analysis and line intensities of the HCO B^2A＇-X^2A＇31^1 band at 296 K

This paper computes the rotational energy levels of the HCO B^2A＇-X^2A＇31^1 transition, especially, the higher values of the rotational quantum numbers NKa Kc and Ka, with the rotational constants which are obtained via B3LYP method with 6-311G basis set, and the results show that the calculated frequencies using the computed vibration-rotation energy levels are in reasonable agreement with the data from the experiment. Meanwhile, the line intensities of HCO are first reported, the results are of significance for the studying HCO.     

Structures and Dynamics of Two-Dimensional Dust Lattices with and without Coulomb Molecules in Plasmas

Structures and dynamics of two-dimensional dust lattices with and without Coulomb molecules in plasmas are investigated. The experimental results show that the lattices have the crystal-like hexagonal structures, i.e. most particles have six nearest-neighboring particles. However, the lattice points can be occupied by the individual particles or by a pair of particles called Coulomb molecules. The pair correlation function is used to compare the structures between the lattices with or without the Coulomb molecules. In the experiments, the Coulomb molecules can also decompose and recombine with another individual particle to form a new molecule.